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At Tylicz, near Krynica Spa (Polish Carpathians), spelean deposits fill fissures and caverns in Eocene flysch rocks. They occur as: (1) clastic cave sediments transformed into hard crusts due to cementation by finely crystalline low-Mg calcite, (2) drusy calcite that covers crust surfaces and fills voids in the crust and (3) colloform calcite. Two varieties of drusy calcite are distinguished: acicular and columnar. The acicular calcite is built up of crystallites forming spherulitic fans or cones. In places it is syntaxially covered with colloform calcite. The drusy calcite is low-Mg ferroan calcite with non-ferroan subzones, whereas the colloform calcite is a low-Mg non-ferroan variety. The columnar calcite crystals form fan-like bundles. Cross-sections cut perpendicular to the c-axes of columnar crystals are equilateral triangular in shape, although some have slightly curved edges. The columnar crystals have steep rhombic terminations and most have curved triangular faces, i.e. gothic-arch calcite. Saddle crystals have also been observed. The columnar crystals are composed of radially orientated crystallites whose long dimension is parallel to the c-axis. The curved crystal faces of such polycrystals are interpreted as a result of differential growth rates of the crystallites. The spelean calcites precipitated from CO2-saturated water. The high rate of CaCO3 precipitation is thought to be responsible for the formation of radial structures. Finely crystalline calcite formed within pore spaces of clastic sediments close to the water-air interface, drusy calcite crystallized beneath the water-air interface, and colloform calcite precipitated from thin films of water.  相似文献   
2.
Slovenia is required to reduce its greenhouse gas emissions to an average of 8% below the base year 1986 in the period 2008–2012, due to the ratification of the Kyoto Protocol in 2002. It was the first of the transition countries to implement a CO2 tax in 1997. At the beginning of 2005, Slovenia joined other EU Member States by implementing the Emissions Trading Scheme. In contrast with other new EU Member States, Slovenia will be a net buyer of allowances. Therefore future movements on the emissions market will play an important role in the compliance costs of achieving the Kyoto target. The main purpose of this article is to present the establishment and characteristics of the first national allocation plan (NAP1) and to describe the main elements of the second national allocation plan (NAP2) for Slovenia within the EU Emissions Trading Scheme, the expected movements on the emissions allowances market in Slovenia, the expected compliance cost of achieving the Kyoto target and to present the main characteristics and efficiency of the CO2 tax in Slovenia.  相似文献   
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What potential effect do flexible mechanisms under the Kyoto Protocol have on energy efficiency, fuel switching and the development of renewable energy sources for the eight post-communist EU Member States that accessed in 2004? These countries are chief candidates for hosting Joint Implementation (JI) projects and for participating in international emission trading, which may assist the implementation and financing of projects in these target areas. The potentials and barriers to Joint Implementation are reviewed, as well as the conditions under which international emission trading can influence the energy use of the selling country. Different strategies adopted by the host countries towards the application of these instruments, and their impact on sustainable energy development, are examined. The article concludes that the Kyoto flexibility mechanisms may play a positive, but rather limited, role in the sustainable energy development of the region, but the barriers to Joint Implementation may shift the emphasis towards transactions under the framework of international emission trading. If innovative mechanisms are tied to sustainable development goals, this may mobilize the energyefficiency potentials of these countries. An attractive opportunity exists to achieve energy efficiency and emission reductions, utilizing the revenues from allowance sales through ‘green investment’ schemes.  相似文献   
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