Local meteoric water lines describe extratropical precipitation     

Devin F. Smith  Elsa Saelens  Deborah L. Leslie  Anne E. Carey 《水文研究》2021,35(2):e14059

Stable water isotopes δ¹⁸O and δ²H are used to investigate precipitation trends and storm dynamics to advance knowledge of precipitation patterns in a warming world. Herein, δ¹⁸O and δ²H were used to determine the relationship between extratropical cyclonic precipitation and local meteoric water lines (LMWLs) in the eastern Ohio Valley and the eastern United States. Precipitation volume weighted and unweighted central Ohio LMWLs, created with samples collected during 2012–2018, showed that temperature had the greatest effect on precipitation isotopic composition. HYSPLIT back trajectory modelling showed that precipitation was primarily derived from a mid-continental moisture source. Remnants of major hurricanes were collected as extratropical precipitation during the 2012–2018 sampling period in central Ohio. Extratropical precipitation samples were not significantly different from the samples that created the central Ohio LMWL. Six additional LMWLs were derived from United States Geological Survey (USGS) Atmospheric Integrated Research Monitoring Network (AIRMoN) samples collected in Pennsylvania, Delaware, Tennessee, Vermont, New Hampshire, and Oxford, Ohio. Meteoric water lines describing published samples from Superstorm Sandy, plotted with these AIRMoN LMWLs, showed isotopic composition of Superstorm Sandy precipitation was commonly more depleted than the average isotopic composition at the mid-latitude locations. Meteoric water lines describing the Superstorm Sandy precipitation were not significantly different in slope from LMWLs generated within 300 km of the USGS AIRMoN site. This finding, which was observed across the eastern Ohio Valley and eastern United States, demonstrated a consistent precipitation δ²H–δ¹⁸O relationship for extratropical cyclonic and non-cyclonic events. This work also facilitates the analysis of storm development based on the relationship between extratropical event signature and the LMWL. Analysis of extratropical precipitation in relation to LMWLs along storm tracks allows for stronger development of precipitation models and understanding of which climatic and atmospheric factors determine the isotopic composition of precipitation.  相似文献   

Spatial Patterns in Water Quality Associated with Submersed Plant Beds     

Renee K. Gruber  Deborah C. Hinkle  W. Michael Kemp 《Estuaries and Coasts》2011,34(5):961-972

This study describes the influence of submersed plant beds on spatial distributions of key water quality variables. An on-board flow-through water sampling system was used to investigate patterns in turbidity, chlorophyll-a, temperature, dissolved oxygen, and pH across a robust stand of the submersed plant Stuckenia pectinata. Spatially interpolated maps show that water quality conditions were significantly altered within this plant bed, especially during months of peak biomass, and that reduction of suspended particles focused at the bed’s edge. Comparison with a suite of submersed plant beds indicated that patterns were related to canopy height, shoot density, and cross-shore bed width. Wide and dense stands with tall canopies showed reduced turbidity and increased light penetration, while smaller sparser beds often showed elevated within-bed turbidity. These results suggest that bed effects on water quality conditions vary seasonally with plant canopy architecture and bed size, providing tentative guidelines for restoring self-sustaining beds.  相似文献   

Uranium and Thorium Concentration and Isotopic Composition in Five Glass (BHVO‐2G,BCR‐2G,NKT‐1G,T1‐G,ATHO‐G) and Two Powder (BHVO‐2, BCR‐2) Reference Materials     

Kathryn A. Matthews  Michael T. Murrell  Steven J. Goldstein  Andrew J. Nunn  Deborah E. Norman 《Geostandards and Geoanalytical Research》2011,35(2):227-234

Here we report uranium and thorium isotopic ratios and elemental concentrations measured in solid reference materials from the USGS (BHVO‐2G, BCR‐2G, NKT‐1G), as well as those from the MPI‐DING series (T1‐G, ATHO‐G). Specifically created for microanalysis, these naturally‐sourced glasses were fused from rock powders. They cover a range of compositions, elemental concentrations and expected isotopic ratios. The U‐Th isotopic ratios of two powdered source materials (BCR‐2, BHVO‐2) were also characterised. These new measurements via multi‐collector thermal ionisation mass spectrometry and multi‐collector inductively coupled plasma‐mass spectrometry can now be used to assess the relative performance of techniques and facilitate comparison of U‐Th data amongst laboratories in the geoscience community for in situ and bulk analyses.  相似文献   

On the use of IPCC-class models to assess the impact of climate on Living Marine Resources     

Charles A. Stock  Michael A. Alexander  Nicholas A. Bond  Keith M. Brander  William W.L. Cheung  Enrique N. Curchitser  Thomas L. Delworth  John P. Dunne  Stephen M. Griffies  Melissa A. Haltuch  Jonathan A. Hare  Anne B. Hollowed  Patrick Lehodey  Simon A. Levin  Jason S. Link  Kenneth A. Rose  Ryan R. Rykaczewski  Jorge L. Sarmiento  Ronald J. Stouffer  Franklin B. Schwing  Francisco E. Werner 《Progress in Oceanography》2011,88(1-4):1-27

The study of climate impacts on Living Marine Resources (LMRs) has increased rapidly in recent years with the availability of climate model simulations contributed to the assessment reports of the Intergovernmental Panel on Climate Change (IPCC). Collaboration between climate and LMR scientists and shared understanding of critical challenges for such applications are essential for developing robust projections of climate impacts on LMRs. This paper assesses present approaches for generating projections of climate impacts on LMRs using IPCC-class climate models, recommends practices that should be followed for these applications, and identifies priority developments that could improve current projections. Understanding of the climate system and its representation within climate models has progressed to a point where many climate model outputs can now be used effectively to make LMR projections. However, uncertainty in climate model projections (particularly biases and inter-model spread at regional to local scales), coarse climate model resolution, and the uncertainty and potential complexity of the mechanisms underlying the response of LMRs to climate limit the robustness and precision of LMR projections. A variety of techniques including the analysis of multi-model ensembles, bias corrections, and statistical and dynamical downscaling can ameliorate some limitations, though the assumptions underlying these approaches and the sensitivity of results to their application must be assessed for each application. Developments in LMR science that could improve current projections of climate impacts on LMRs include improved understanding of the multi-scale mechanisms that link climate and LMRs and better representations of these mechanisms within more holistic LMR models. These developments require a strong baseline of field and laboratory observations including long time series and measurements over the broad range of spatial and temporal scales over which LMRs and climate interact. Priority developments for IPCC-class climate models include improved model accuracy (particularly at regional and local scales), inter-annual to decadal-scale predictions, and the continued development of earth system models capable of simulating the evolution of both the physical climate system and biosphere. Efforts to address these issues should occur in parallel and be informed by the continued application of existing climate and LMR models.  相似文献   

Evidence of microbially mediated arsenic mobilization from sediments of the Aquia aquifer, Maryland, USA     

Christine A. PearcyDarren A. Chevis  T. Jade HaugHolly A. Jeffries  Ningfang YangJianwu Tang  Deborah A. GrimmKaren H. Johannesson 《Applied Geochemistry》2011,26(4):575-586

Sediments from the Aquia aquifer in coastal Maryland were collected as part of a larger study of As in the Aquia groundwater flow system where As concentration are reported to reach levels as high as 1072 nmol kg⁻¹, (i.e., ∼80 μg/L). To test whether As release is microbially mediated by reductive dissolution of Fe(III) oxides/oxyhydroxides within the aquifer sediments, the Aquia aquifer sediment samples were employed in a series of microcosm experiments. The microcosm experiments consisted of sterilized serum bottles prepared with aquifer sediments and sterilized (i.e., autoclaved), artificial groundwater using four experimental conditions and one control condition. The four experimental conditions included the following scenarios: (1) aerobic; (2) anaerobic; (3) anaerobic + acetate; and (4) anaerobic + acetate + AQDS (anthraquinone-2,6-disulfonic acid). AQDS acts as an electron shuttle. The control condition contained sterilized aquifer sediments kept under anaerobic conditions with an addition of AQDS. Over the course of the 27 day microcosm experiments, dissolved As in the unamended (aerobic and anaerobic) microcosms remained constant at around ∼28 nmol kg⁻¹ (2 μg/L). With the addition of acetate, the amount of As released to the solution approximately doubled reaching ∼51 nmol kg⁻¹ (3.8 μg/L). For microcosm experiments amended with acetate and AQDS, the dissolved As concentrations exceeded 75 nmol kg⁻¹ (5.6 μg/L). The As concentrations in the acetate and acetate + AQDS amended microcosms are of similar orders of magnitude to As concentrations in groundwaters from the aquifer sediment sampling site (127-170 nmol kg⁻¹). Arsenic concentrations in the sterilized control experiments were generally less than 15 nmol kg⁻¹ (1.1 μg/L), which is interpreted to be the amount of As released from Aquia aquifer sediments owing to abiotic, surface exchange processes. Iron concentrations released to solution in each of the microcosm experiments were higher and more variable than the As concentrations, but generally exhibited similar trends to the As concentrations. Specifically, the acetate and acetate + AQDS amended microcosm typically exhibited the highest Fe concentrations (up to 1725 and 6566 nmol kg⁻¹, respectively). The increase in both As and Fe in the artificial groundwater solutions in these amended microcosm experiments strongly suggests that microbes within the Aquia aquifer sediments mobilize As from the sediment substrate to the groundwaters via Fe(III) reduction.  相似文献   

Evolution of anthropogenic and biomass burning emissions of air pollutants at global and regional scales during the 1980�C2010 period     

Claire Granier  Bertrand Bessagnet  Tami Bond  Ariela D��Angiola  Hugo Denier van der Gon  Gregory J. Frost  Angelika Heil  Johannes W. Kaiser  Stefan Kinne  Zbigniew Klimont  Silvia Kloster  Jean-Fran?ois Lamarque  Catherine Liousse  Toshihiko Masui  Frederik Meleux  Aude Mieville  Toshimasa Ohara  Jean-Christophe Raut  Keywan Riahi  Martin G. Schultz  Steven J. Smith  Allison Thompson  John van Aardenne  Guido R. van der Werf  Detlef P. van Vuuren 《Climatic change》2011,109(1-2):163-190

Several different inventories of global and regional anthropogenic and biomass burning emissions are assessed for the 1980?C2010 period. The species considered in this study are carbon monoxide, nitrogen oxides, sulfur dioxide and black carbon. The inventories considered include the ACCMIP historical emissions developed in support of the simulations for the IPCC AR5 assessment. Emissions for 2005 and 2010 from the Representative Concentration Pathways (RCPs) are also included. Large discrepancies between the global and regional emissions are identified, which shows that there is still no consensus on the best estimates for surface emissions of atmospheric compounds. At the global scale, anthropogenic emissions of CO, NO_x and SO₂ show the best agreement for most years, although agreement does not necessarily mean that uncertainty is low. The agreement is low for BC emissions, particularly in the period prior to 2000. The best consensus is for NO_x emissions for all periods and all regions, except for China, where emissions in 1980 and 1990 need to be better defined. Emissions of CO need better quantification in the USA and India for all periods; in Central Europe, the evolution of emissions during the past two decades needs to be better determined. The agreement between the different SO₂ emissions datasets is rather good for the USA, but better quantification is needed elsewhere, particularly for Central Europe, India and China. The comparisons performed in this study show that the use of RCP8.5 for the extension of the ACCMIP inventory beyond 2000 is reasonable, until more global or regional estimates become available. Concerning biomass burning emissions, most inventories agree within 50?C80%, depending on the year and season. The large differences between biomass burning inventories are due to differences in the estimates of burned areas from the different available products, as well as in the amount of biomass burned.  相似文献   

Effects of deglaciation on the petrology and eruptive history of the Western Volcanic Zone,Iceland     

Deborah E. Eason  John M. Sinton  Karl Grönvold  Mark D. Kurz 《Bulletin of Volcanology》2015,77(6):1-27

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Stratigraphy of Pleistocene glaciations in the St Elias Mountains,southwest Yukon,Canada          下载免费PDF全文

Derek G. Turner  Brent C. Ward  Duane G. Froese  Michel Lamothe  Jeffrey D. Bond  Nancy H. Bigelow 《Boreas: An International Journal of Quaternary Research》2016,45(3):521-536

At least five Middle to Late Pleistocene advances of the northern Cordilleran Ice Sheet are preserved at Silver Creek, on the northeastern edge of the St Elias Mountains in southwest Yukon, Canada. Silver Creek is located 100 km up‐ice of the Marine Isotope Stage (MIS) 2 McConnell glacial limit of the St Elias lobe. This site contains ~3 km of nearly continuous lateral exposure of glacial and non‐glacial sediments, including multiple tills separated by thick gravel, loess and tilted lake beds. Infrared‐stimulated luminescence (IRSL) and AMS radiocarbon dating constrain the glacial deposits to MIS 2, 4, either MIS 6 or mid‐MIS 7, and two older Middle Pleistocene advances. This chronology and the tilt of the lake beds suggest Pleistocene uplift rates of up to 1.9 mm a^?1 along the Denali Fault since MIS 7. The non‐glacial sediment consists of sand, gravel, loess and organic beds from MIS 7, MIS 3 and the early Holocene. The MIS 3 deposits date to between 30–36 ¹⁴C ka BP, making Silver Creek one of the few well‐constrained MIS 3‐aged sites in Yukon. This confirms that ice receded close to modern limits in MIS 3. Pollen and macrofossil analyses show that a meadow‐tundra to steppe‐tundra mosaic with abundant herbs and forbs and few shrubs or trees, dominated the environment at this time. The stratigraphy at Silver Creek provides a palaeoclimatic record since at least MIS 8 and comprises the oldest direct record of Pleistocene glaciation in southwest Yukon.  相似文献   

Constitutive and numerical framework for modeling joints and faults in rock          下载免费PDF全文

Howard Schreyer  Deborah Sulsky 《国际地质力学数值与分析法杂志》2016,40(9):1253-1283

A three‐dimensional constitutive model for joints is described that incorporates nonlinear elasticity based on volumetric elastic strain, and plasticity for both compaction and shear with emphasis on compaction. The formulation is general in the sense that alternative specific functional forms and evolution equations can be easily incorporated. A corresponding numerical structure based on finite elements is provided so that a joint width can vary from a fraction of an element size to a width that occupies several elements. The latter case is particularly appropriate for modeling a fault, which is considered simply to be a joint with large width. For small joint widths, the requisite equilibrium and kinematic requirements within an element are satisfied numerically. The result is that if the constitutive equation for either the joint or the rock is changed, the numerical framework remains unchanged. A unique aspect of the general formulation is the capability to handle either pre‐existing gaps or the formation of gaps. Representative stress–strain plots are given to illustrate both the features of the model and the effects of changes in values of material parameters. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

Guiding ecological principles for marine spatial planning     

Melissa M. Foley  Benjamin S. Halpern  Fiorenza Micheli  Matthew H. Armsby  Margaret R. Caldwell  Caitlin M. Crain  Erin Prahler  Nicole Rohr  Deborah Sivas  Michael W. Beck  Mark H. Carr  Larry B. Crowder  J. Emmett Duffy  Sally D. Hacker  Karen L. McLeod  Stephen R. Palumbi  Charles H. Peterson  Helen M. Regan  Mary H. Ruckelshaus  Paul A. Sandifer  Robert S. Steneck 《Marine Policy》2010

The declining health of marine ecosystems around the world is evidence that current piecemeal governance is inadequate to successfully support healthy coastal and ocean ecosystems and sustain human uses of the ocean. One proposed solution to this problem is ecosystem-based marine spatial planning (MSP), which is a process that informs the spatial distribution of activities in the ocean so that existing and emerging uses can be maintained, use conflicts reduced, and ecosystem health and services protected and sustained for future generations. Because a key goal of ecosystem-based MSP is to maintain the delivery of ecosystem services that humans want and need, it must be based on ecological principles that articulate the scientifically recognized attributes of healthy, functioning ecosystems. These principles should be incorporated into a decision-making framework with clearly defined targets for these ecological attributes. This paper identifies ecological principles for MSP based on a synthesis of previously suggested and/or operationalized principles, along with recommendations generated by a group of twenty ecologists and marine scientists with diverse backgrounds and perspectives on MSP. The proposed four main ecological principles to guide MSP—maintaining or restoring: native species diversity, habitat diversity and heterogeneity, key species, and connectivity—and two additional guidelines, the need to account for context and uncertainty, must be explicitly taken into account in the planning process. When applied in concert with social, economic, and governance principles, these ecological principles can inform the designation and siting of ocean uses and the management of activities in the ocean to maintain or restore healthy ecosystems, allow delivery of marine ecosystem services, and ensure sustainable economic and social benefits.  相似文献