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1.
Chemical compositions of materials used for new sample holders (vertically aligned carbon nanotubes [VACNTs] and polyimide film), which were developed for the analysis of Hayabusa2‐return samples, were determined by instrumental neutron activation analysis and/or instrumental photon activation analysis, to estimate contamination effects from the sample holders. The synthetic quartz plate used for the sample holders was also analyzed. Ten elements (Na, Al, Cr, Mn, Fe, Ni, Eu, W, Au, and Th) and 14 elements (Na, Al, K, Sc, Ti, Cr, Zn, Ga, Br, Sb, La, Eu, Ir, and Au) could be detected in the VACNTs and polyimide film, respectively. The VACNT data show that contamination by this material with respect to the Murchison meteorite is negligible in terms of the elemental ratios (e.g., Fe/Mn, Na/Al, and Mn/Cr) used for the classification of meteorites due to the extremely low density of VACNTs. However, for the Au/Cr ratio, even small degrees (1.7 wt%) of contamination by VACNTs will change the Au/Cr ratio. Elemental ratios used for the classification of meteorites are only influenced by large amounts of contamination (>60 wt%) of polyimide film, which is unlikely to occur. In contrast, detectable effects on Ti isotopic compositions are caused by >0.1 and >0.3 wt% contamination by VACNTs and polyimide film, respectively, and Hf isotopic changes are caused by >0.1 wt% contamination by VACNTs. The new sample holders (VACNTs and polyimide film) are suitable for chemical classification of Hayabusa2‐return samples, because of their ease of use, applicability to multiple analytical instruments, and low contamination levels for most elements.  相似文献   
2.
Takahashi  Naoya  Hayasaka  Tadahiro  Qiu  Bo  Yamaguchi  Ryohei 《Climate Dynamics》2021,56(11):3511-3526

Active roles of both sea surface temperature (SST) and its frontal characteristics to the atmosphere in the mid-latitudes have been investigated around the western boundary current regions, and most studies have focused on winter season. The present study investigated the influence of the variation of the summertime Oyashio extension SST front (SSTF) in modulating low-level cloud properties (i.e., low-level cloud cover [LCC], cloud optical thickness [COT], and shortwave cloud radiative effect [SWCRE]) on inter-annual timescales, based on available satellite and Argo float datasets during 2003–2016. First, we examined the mechanism of summertime SSTF variability itself. The strength of the SSTF (SSSTF), defined as the maximum horizontal gradient of SST, has clear inter-annual variations. Frontogenesis equation analysis and regression analysis for subsurface temperature indicated that the inter-annual variations of the summertime SSSTF in the western North Pacific are closely related to the variations of not surface heat flux, but western boundary currents, particularly the Oyashio Extensions. The response of low-level cloud to intensified SSSTF is that negative SWCRE with positive COT anomaly in the northern flank of the SSTF can be induced by cold SST anomalies. The spatial scale of the low-level cloud response was larger than the SST frontal scale, and the spatial distribution of the response was mainly constrained by the pathways of Kuroshio and Oyashio Extensions. Multi-linear regression analysis revealed that the local SST anomaly played largest role in modulating the SWCRE and COT anomalies among the cloud controlling factors (e.g., estimated inversion strength, air-temperature advection) accounting for more than 50% of the variation. This study provides an observational evidence of the active role of local SST anomalies in summertime associated with the western boundary currents to the oceanic low-level cloud.

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3.
Nondimensionalization of variables enables us to treat experiment data much more simply and efficiently by decreasing the number of variables. In some cases, trivial conclusions (which Kenney, 1982, called spurious self-correlation) result from a formal application of dimensional analyses. In contrast, in some cases fully significant conclusions can be derived. We first discuss how to construct nondimensional variables retaining the physical meanings of variables. We then propose simple and efficient methods, especially the use of “spurious triangle (SpT)”, to discriminate between significant conclusions and spurious self-correlations in the analysis of nondimensionalized variables.  相似文献   
4.
Abstract– Different oxygen isotopic reservoirs have been recognized in the early solar system. Fluffy type A Ca‐Al‐rich inclusions (CAIs) are believed to be direct condensates from a solar nebular gas, and therefore, have acquired oxygen from the solar nebula. Oxygen isotopic and chemical compositions of melilite crystals in a type A CAI from Efremovka CV3 chondrite were measured to reveal the temporal variation in oxygen isotopic composition of surrounding nebular gas during CAI formation. The CAI is constructed of two domains, each of which has a core‐mantle structure. Reversely zoned melilite crystals were observed in both domains. Melilite crystals in one domain have a homogeneous 16O‐poor composition on the carbonaceous chondrite anhydrous mineral (CCAM) line of δ18O = 5–10‰, which suggests that the domain was formed in a 16O‐poor oxygen isotope reservoir of the solar nebula. In contrast, melilite crystals in the other domain have continuous variations in oxygen isotopic composition from 16O‐rich (δ18O = ?40‰) to 16O‐poor (δ18O = 0‰) along the CCAM line. The oxygen isotopic composition tends to be more 16O‐rich toward the domain rim, which suggests that the domain was formed in a variable oxygen isotope reservoir of the solar nebula. Each domain of the type A CAI has grown in distinct oxygen isotope reservoir of the solar nebula. After the domain formation, domains were accumulated together in the solar nebula to form a type A CAI.  相似文献   
5.
We report the mineral compositions and micro-texture of the isotopically anomalous (δ17,18OSMOW ∼ +180‰) Fe-S-Ni-O material recently discovered in matrix of the primitive carbonaceous chondrite Acfer 094 [Sakamoto N., Seto Y., Itoh S., Kuramoto K., Fujino K., Nagashima K., Krot A. N. and Yurimoto H. (2007) Oxygen isotope evidence for remnants of the early solar system primordial water. Science317, 231-233]. Synchrotron radiation X-ray diffraction and transmission electron microscopy studies indicate that this material consists of the symplectitically intergrown magnetite (Fe3O4) and pentlandite (Fe5.7Ni3.3S8) with magnetite/pentlandite volume ratio of ∼2.3. Magnetite forms column-shaped grains (10-30 nm in diameter and 100-200 nm in length); pentlandite occurs as worm-shaped grains or aggregates of grains 100-300 nm in size between magnetite crystals. Although both the X-ray diffraction and electron energy loss spectra support identification of iron oxide as magnetite, the electron diffraction patterns show that magnetite has a weak 3-fold superstructure, possibly due to ordering of vacancies. We infer that the isotopically anomalous symplectite formed by sulfurization and oxidization of metal grains either in the solar nebula or on an icy planetesimal. The intersite cation distribution of pentlandite suggests that timescale of oxidation was no longer than 1000 years.  相似文献   
6.
Abstract— Crystallization of parent melts for nakhlites was experimentally studied under QFM ± 2 at one bar. Isothermal experiments suggest that melts having parent magma composition for nakhlites crystallize both augites and titanomagnetites at liquidus temperatures of 1144–1154 °C. Compositions of the augites are identical to those of phenocrystic core augites (En36–38Fs22–25Wo39–40) in nakhlites. No olivines crystallize from the isothermal runs, and solidus temperature is about 1000 °C. Linear‐cooling experiments were carried out at various cooling rates (1–17 °C/h) ranging from liquidus to solidus temperatures under similar pressure conditions to the isothermal runs. Augites, titanomagnetites, and fayalites crystallized in the cooling runs, but magnesian olivines never crystallized there. Magnesian core augite in the cooling runs has the same composition as those of nakhlites. Rims of augite crystals from the cooling runs of 1–4 °C/h consist of two layers, ferroan augite inner rim and hedenbergite outer rim, which are very similar to those in the Miller Range (MIL) 03346 nakhlite. Small amounts of pyroxferroite crystallized in mesostasis and augite rims from two cooling runs. Titanomagnetites from cooling runs never accompany ilmenite lamellae as seen in nakhlites, suggesting that the subsolidus cooling rate of the cooling runs was much more rapid than those of nakhlite intercumulus melts. The cooling experiments reproduce the crystallization processes of pyroxenes and the compositional change of residual melt for a rapidly cooled magma such as MIL 03346.  相似文献   
7.
Hydrologic balance in high‐altitude, mid‐latitude mountain areas is important in terms of the water resources available to associated lowlands. This study examined how current and historical shifts in precipitation (P) patterns and concurrent increases in temperature (T) affected runoff (Q) and other hydrologic components in a mid‐latitude mountain catchment of central Japan, using a combination of long‐term data and a simplified hydrologic model, along with their stochastic treatment. The availability of intensive meteorological and hydrological data from the period 1997–2001 allowed the derivation of key relationships for the current climate that tie the forcing term to the parameters or state variables. By using the data recorded in the period 1965–2001, the force for driving the historical simulation was generated. Based on this model and historical shifts in P and T, the probability density functions of Q (pdf(Q)) was computed. A main novelty in this study is that such a stochastic representation, which is useful for considering the influence of projected shifts in environmental factors on the hydrologic budget, was provided. Despite the large increase in the rate of T in winter and spring, pdf(Q) in spring and summer varied appreciably during the time studied mainly because of an increase in snowmelt. An interannual change in whole‐year Q was robust to shifts in T because while Q in spring increased, in summer it decreased, implying a crucial effect of global warming on mountain hydrologic regimes is change in the timing of Q. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   
8.
In both 2009 and 2010, massive Chattonella blooms occurred in Tachibana Bay. Observation results show that high cell densities of Chattonella were distributed in the central area of Tachibana Bay with low salinity water. Model results indicate that the low salinity water originated from the Ariake Sea and intruded into Tachibana Bay during the northerly or weak winds. It is suggested that low salinity water was mainly discharged from the northern area of the Ariake Sea. Northerly wind enhanced the horizontal advection of the low salinity water intruding into Tachibana Bay originating from the northern area of the Ariake Sea.  相似文献   
9.
We have determined the density evolution of the sound velocity of dhcp-FeHx (x  1) up to 70 GPa at room temperature, by inelastic X-ray scattering and by X-ray diffraction. We find that the variation of VP with density is different for the ferromagnetic and nonmagnetic dhcp-FeHx, and that only nonmagnetic dhcp-FeHx follows Birch's law. Combining our results with Birch's law for iron and assuming an ideal two-component mixing model, we obtain an upper bound of the hydrogen content in the Earth's inner core, 0.23(6) wt.% H, corresponding to FeH0.13(3). The iron alloy with 0.23(6) wt.% H can satisfy the density, and compressional and shear sound velocities of the PREM inner core, assuming that there are no other light elements in the inner core.  相似文献   
10.
Using an X‐ray diffractometer, powder‐like diffraction patterns were acquired from in‐plane rotation of polished thin sections (PTSs) of 60 ordinary chondrites (23 H, 21 L, and 16 LL), in order to explore the thermal and shock metamorphism and its modifications of primordial features. The olivine (Ol) 130 peak position shown as Bragg indices clearly correlates with the chemical group for equilibrated ordinary chondrites (EOCs), while the peak is split or broad for unequilibrated ordinary chondrites (UOCs). The intensity ratio of kamacite may be useful for distinguishing the chemical group between H and L‐LL, but it is not definite because of heterogeneous terrestrial weathering of kamacite, especially in H chondrites. The summed intensities of the orthoenstatite (Oen) 511 and 421 peaks positively correlates with the metamorphic sequence from 3 to 6, while that of clinoenstatite (Cen) 22 is inversely correlated. The shock stage positively correlates with the summed full width of half maximum values of the Oen 511 and 421 peaks and the FWHM of Ol 130 peak for each class. Significant amount of Oen (Pbca) transformed through Cen (C2/c) finally to Cen (P21/c) is stable at high pressure for shock stage S6 (Tenham and NWA 4719). The shock melted LL chondrite is characterized by the occurrence of Cen and abundant homogeneous olivine. The effects of both thermal and shock metamorphism are thus incorporated into the bulk X‐ray diffraction (XRD) data. The bulk XRD method is useful for determining the bulk mineralogy, resulting in the classification of ordinary chondrites. The method is also applicable to samples other than PTS.  相似文献   
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