用N—P—甲氧基苯基—2—呋喃基丙烯氧肟酸萃取分离...     

Abba.  SA 魏澎 《国外铀金地质》1990,(3):88-90

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新西兰奥塔戈东部马可罗斯地区石墨片岩中变质...     

Mcke.  SA 王文珍 《世界地质》1992,11(1):108-117

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The use of meiofauna as an indicator of benthic organic enrichment associated with salmonid aquaculture   总被引：4，自引：1，他引：3  

Sutherland TF  Levings CD  Petersen SA  Poon P  Piercey B 《Marine pollution bulletin》2007,54(8):1249-1261

Sediment chemistry and meiofaunal samples were collected in the Broughton Archipelago, British Columbia, to examine the relationship between sediment variables and meiofauna diversity across near- and far-field gradients surrounding several finfish aquaculture operations. The sediment variables examined consisted of free sulfide concentrations, redox potential (E(NHE)), organic content, and sediment grain size. A strong trend between sediment texture and organic content was observed across all sampling locations, which reflected a wide range of sediment types (sand-silt) that exist within the Broughton Archipelago. The abundance of certain meiofaunal groups (kinorhynchs, crustaceans, polychaetes) declined in an asymptotic fashion with increasing free sulfide concentrations, an indicator of benthic organic enrichment. Within these relationships, low meiofaunal abundances occurred in fine sediments associated with higher organic contents. Although other groups (nematodes, foraminifera) showed a slight decline in abundance with increasing organic enrichment, a high amount of variability in abundance was observed at high free sulfide concentrations, rendering these groups not suitable as indicators of organic enrichment. This study reports both horizontal and vertical trends in meiofaunal distributions relative to free sulfide concentrations. The abundance of nematode and crustacean taxa decreased with sediment depth as well as increasing sulfide concentration, while polycheate abundance increased with increasing free sulfide concentration. The ratio of nematodes to copepods was also shown to represent the degree of organic loading associated with aquaculture operations and its application as an indicator of benthic impact is discussed.  相似文献   

Development of a benthic index to assess sediment quality in the Tampa Bay Estuary   总被引：1，自引：0，他引：1  

Malloy KJ  Wade D  Janicki A  Grabe SA  Nijbroek R 《Marine pollution bulletin》2007,54(1):22-31

The identification, remedial treatment, and monitoring of contaminated sediments are among the priorities for managers of the Tampa Bay Estuary. Tampa Bay, as an urbanized estuary, is subject to the input of watershed sources of chemical contaminants, including metals, pesticides, and organic chemicals. Although the use of biological indicators and their incorporation into multi-metric indices is not new, the refinement and applications of such techniques for determining environmental condition still require further development and exploration. We present a single Tampa Bay Benthic Index (TBBI) that was developed specifically for Tampa Bay. Stepwise discriminant analysis was applied to a comprehensive list of potential benthic metrics. Results from the stepwise procedure identified the metrics that best discriminated between "healthy" and "degraded" conditions, as defined by sediment contaminant effect levels and dissolved oxygen. Discriminant analysis was then applied to the resultant three variables to determine the linear combination for the index.  相似文献   

Cytochrome P4501A biomarker indication of the timeline of chronic exposure of Barrow's goldeneyes to residual Exxon Valdez oil     

Esler D  Ballachey BE  Trust KA  Iverson SA  Reed JA  Miles AK  Henderson JD  Woodin BR  Stegeman JJ  McAdie M  Mulcahy DM  Wilson BW 《Marine pollution bulletin》2011,62(3):609-614

We examined hepatic EROD activity, as an indicator of CYP1A induction, in Barrow’s goldeneyes captured in areas oiled during the 1989 Exxon Valdez spill and those from nearby unoiled areas. We found that average EROD activity differed between areas during 2005, although the magnitude of the difference was reduced relative to a previous study from 1996/1997, and we found that areas did not differ by 2009. Similarly, we found that the proportion of individuals captured from oiled areas with elevated EROD activity (?2 times unoiled average) declined from 41% in winter 1996/1997 to 10% in 2005 and 15% in 2009. This work adds to a body of literature describing the timelines over which vertebrates were exposed to residual Exxon Valdez oil and indicates that, for Barrow’s goldeneyes in Prince William Sound, exposure persisted for many years with evidence of substantially reduced exposure by 2 decades after the spill.  相似文献   

Local hydraulic gradient estimator analysis of long-term monitoring networks   总被引：1，自引：0，他引：1  

McKenna SA  Wahi A 《Ground water》2006,44(5):723-731

Three measurements of head at unique locations form a three-point estimator of the local magnitude and orientation of the hydraulic gradient. The relative head measurement error (RHME) is defined here as the measurement error normalized by the head drop across the three-point estimator. Monte Carlo simulation results show that estimators with base to height ratios between 0.5 and 5.0 and that are large enough to keep the RHME below 0.05 create the most accurate gradient estimates and provide criteria for identifying good estimators. These criteria are applied to an example ground water monitoring network design problem in the Culebra dolomite near the Waste Isolation Pilot Plant repository to both analyze temporal changes and modify and expand the current monitoring network. Limiting the three-point estimators to those that meet the shape and RHME criteria reduces the number of possible estimators by >50% and leads to approximately 1 order of magnitude decrease in the average estimated magnitude of the gradient relative to using all estimators. Application of these criteria also reduces the variability in estimated gradient magnitude and orientation between the two time periods of measurements. Redundant wells in the network are identified by removing each existing well in turn and determining which removals yield the smallest decrease in the number of acceptable estimators. Optimal new well locations are identified by mapping the increase in total number of acceptable estimators for a single new well placed in the study domain.  相似文献   

Electrical resistance sensors record spring flow timing, Grand Canyon, Arizona     

Adams EA  Monroe SA  Springer AE  Blasch KW  Bills DJ 《Ground water》2006,44(5):630-641

Springs along the south rim of the Grand Canyon, Arizona, are important ecological and cultural resources in Grand Canyon National Park and are discharge points for regional and local aquifers of the Coconino Plateau. This study evaluated the applicability of electrical resistance (ER) sensors for measuring diffuse, low-stage (<1.0 cm) intermittent and ephemeral flow in the steep, rocky spring-fed tributaries of the south rim. ER sensors were used to conduct a baseline survey of spring flow timing at eight sites in three spring-fed tributaries in Grand Canyon. Sensors were attached to a nearly vertical rock wall at a spring outlet and were installed in alluvial and bedrock channels. Spring flow timing data inferred by the ER sensors were consistent with observations during site visits, with flow events recorded with collocated streamflow gauging stations and with local precipitation gauges. ER sensors were able to distinguish the presence of flow along nearly vertical rock surfaces with flow depths between 0.3 and 1.0 cm. Laboratory experiments confirmed the ability of the sensors to monitor the timing of diffuse flow on impervious surfaces. A comparison of flow patterns along the stream reaches and at springs identified the timing and location of perennial and intermittent flow, and periods of increased evapotranspiration.  相似文献   

Determination of HBCD, PBDEs and MeO-BDEs in California sea lions (Zalophus californianus) stranded between 1993 and 2003   总被引：1，自引：0，他引：1  

Stapleton HM  Dodder NG  Kucklick JR  Reddy CM  Schantz MM  Becker PR  Gulland F  Porter BJ  Wise SA 《Marine pollution bulletin》2006,52(5):522-531

Blubber samples from male California sea lions (Zalphophus californianus) stranded between 1993 and 2003 were analyzed for 27 polybrominated diphenyl ether (PBDE) congeners, three isomers of hexabromocyclododecane (HBCD) and 14 methoxylated polybrominated diphenyl ether (MeO-BDE) congeners. Total PBDEs ranged from 450 ng/g to 4740 ng/g wet mass and total HBCD ranged from < 0.3 ng/g to 12 ng/g wet mass. The concentration of HBCD increased from 0.7 ng/g to12.0 ng/g wet mass in sea lion blubber between 1993 and 2003. However, no significant temporal trend was observed for any of the other brominated compounds over this 10 year period. Only one of the 14 MeO-BDE congeners was detected in the blubber samples, 6-methoxy-2,2',4,4'-tetrabromodiphenyl ether (6-MeO-BDE 47), and concentrations ranged from < 0.2 ng/g to 12 ng/g wet mass. A bromo-, chloro-heterocyclic compound, 1,1'-dimethyl-tetrabromo-dichloro-2,2'-bipyrrole (DBP-Br4Cl2), previously reported in marine species along the Pacific coast, was also identified in the sea lion blubber. DBP-Br4Cl2 ranged from 44 ng/g wet mass to 660 ng/g wet mass and was present at concentrations rivaling the dominant PBDE congener, BDE 47 (2,2',4,4'-tetrabromodiphenyl ether). Concentrations of DBP-Br4Cl2 were positively correlated with 6-MeO-BDE 47 (r = 0.7; p < 0.05). Both of these compounds have been identified in marine algae and sponges, and studies suggest they are both produced from natural sources. This study demonstrates that brominated compounds from both anthropogenic and biogenic sources can accumulate to similar levels in marine mammals. In addition, HBCD concentrations appear to be increasing in California sea lion populations, whereas PBDE concentrations, between 1993 and 2003, were highly variable.  相似文献   

An overview of toxicant identification in sediments and dredged materials   总被引：1，自引：0，他引：1  

Ho KT  Burgess RM  Pelletier MC  Serbst JR  Ryba SA  Cantwell MG  Kuhn A  Raczelowski P 《Marine pollution bulletin》2002,44(4):286-293

The identification of toxicants affecting aquatic benthic systems is critical to sound assessment and management of our nation's waterways. Identification of toxicants can be useful in designing effective sediment remediation plans and reasonable options for sediment disposal. Knowledge of which contaminants affect benthic systems allows managers to link pollution to specific dischargers and prevent further release of toxicant(s). In addition, identification of major causes of toxicity in sediments may guide programs such as those developing environmental sediment guidelines and registering pesticides, while knowledge of the causes of toxicity which drive ecological changes such as shifts in benthic community structure would be useful in performing ecological risk assessments. To this end, the US Environmental Protection Agency has developed tools (toxicity identification and evaluation (TIE) methods) that allow investigators to characterize and identify chemicals causing acute toxicity in sediments and dredged materials. To date, most sediment TIEs have been performed on interstitial waters. Preliminary evidence from the use of interstitial water TIEs reveals certain patterns in causes of sediment toxicity. First, among all sediments tested, there is no one predominant cause of toxicity; metals, organics, and ammonia play approximately equal roles in causing toxicity. Second, within a single sediment there are multiple causes of toxicity detected; not just one chemical class is active. Third, the role of ammonia is very prominent in these interstitial waters. Finally, if sediments are divided into marine or freshwater, TIEs perforMed on interstitial waters from freshwater sediments indicate a variety of toxicants in fairly equal proportions, while TIEs performed on interstitial waters from marine sediments have identified only ammonia and organics as toxicants, with metals playing a minor role. Preliminary evidence from whole sediment TIEs indicates that organic compounds play a major role in the toxicity of marine sediments, with almost no evidence for either metal or ammonia toxicity. However, interpretation of these results may be skewed because only a small number of interstitial water (n = 13) and whole sediment (n = 5) TIEs have been completed. These trends may change as more data are collected.  相似文献   

Levels of organochlorine pesticide residues in some organs of the Ganges perch, Lates calcarifer, from the Ganges-Brahmaputra-Meghna Estuary, Bangladesh     

Jabber SA  Khan YS  Rahman MS 《Marine pollution bulletin》2001,42(12):1291-1296

Levels of organochlorine pesticide residues (p,p′ DDT, DDD, DDE, Aldrin, Dieldrin, Lindane, Heptachlor and BHC) were analysed in the dry and wet seasons in four organs (muscle, liver, gut and egg samples) of Ganges Perch, Lates calcarifer, collected during October–November–December, 1996 and May–June–July, 1997 from the Ganges–Brahmaputtra–Meghna estuary. The residues were analysed by using gas-chromatography (GC) in electron capture detector (ECD) mode and were verified by thin layer chromatography (TLC). Among the four organs analysed, the residues were found in the order egg > gut > muscle > liver. The pesticide residues were found in the order ∑DDT > Heptachlor >Dieldrin > Aldrin. Higher levels of residues were found during the dry season due to high lipid content in fishes. A positive correlation was observed between the pesticide residues (∑DDT and ∑OCs) and lipid contents of fish, and the correlation was found to be linear. The concentrations of pesticide residues in muscle, liver and gut were below the FAO/WHO (1993) recommended permissible limit except in eggs.  相似文献