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Coesite is one of the most common and abundant high‐pressure phases occurring in impactites. The mechanism of formation of coesite and its postshock evolution is revisited in this paper based on Raman microspectroscopy, and scanning and transmission electron microscopy of a coesite‐bearing suevite from the Ries impact structure. Our data indicate that coesite forms through a single process, i.e., by crystallization from high‐pressure silica melt, and that its formation is related to fluid inclusions in precursor quartz. During the postshock phase, coesite aggregates are partially modified by annealing and interactions with fluids. In an early stage of the postshock evolution, coesite is back‐transformed to quartz and the surrounding diaplectic glass devitrifies into β‐cristobalite, which transforms into α‐cristobalite and then into microcrystalline quartz during subsequent stages of the postshock evolution. Altogether these postshock modifications result in a significant volume loss and extensional fracturing. During a late postshock stage, the fractures are filled with clay minerals due to circulation of hydrothermal fluids.  相似文献   
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This paper deals with the derivation of the hydrological response of a hillslope on the assumption of quick runoff by surface runoff generation. By using the simple non‐linear storage based model, first proposed by Horton, an analytical solution of the overland flow equations over a plane hillslope was derived. This solution establishes a generalization for different flow regimes of Horton's original solution, which is valid for the transitional flow regime only. The solution proposed was compared successfully with that of Horton and, for the turbulent flow regime, to the one derived from kinematic wave theory. This solution can be applied easily to both stationary and non‐stationary rainfall excess events. An analytical solution for the instantaneous response function (IRF) was also derived. Finally, simple expressions to compute peak and time to peak of IRF are proposed. Copyright © 2001 John Wiley & Sons, Ltd.  相似文献   
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According to the European Water Framework Directive, the ecological status (ES) of a water body is determined by comparing observation data with undisturbed Reference Conditions (RCs). Defining RCs is crucial when evaluating the ES of a water body as it strongly affects the final outcome of any index application. Identifying RCs by observing real sites is not feasible in many marine environments, such as the Emilia-Romagna coast (Italy, N-Adriatic Sea). We used a statistical approach on a large dataset to derive RCs for the application of the benthic index M-AMBI in this area. We then applied M-AMBI to samples collected along a gradient of presumed environmental disturbance. The results put 14.8% of the Emilia-Romagna samples in “High” ES, 60.2% in “Good”, 23.0% in “Moderate” and 2.0% in “Poor”, showing a spatial gradient of improving quality. These results are in agreement with the extensive ecological knowledge available for this area.  相似文献   
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The sessile and mobile macrobenthos on artificial hard bottoms was studied in 12 stations of the Sacca di Goro lagoon, a brackish, highly stressed water basin in the delta of the river Po, open to the Northwestern Adriatic Sea. Three sampling surveys were carried out in June and September 2000 and June 2001 in order to make three types of temporal comparisons: (i) on a seasonal scale, before and after a summer dystrophic event; (ii) on an annual basis, before and after the works of excavation of a canal through the outer sand bank; (iii) on a multiannual scale, comparing the data with those of a survey carried out in 1988. The biocoenoses did not show large fluctuations after a moderately severe summer dystrophic crisis, while the digging of the canal caused clear changes in the macrobenthos community structure after one year. The long-term comparison showed a shift in the community patterns after a decade.  相似文献   
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We have investigated silicate emulsions in impact glasses and impact melt rocks from the Wabar (Saudi Arabia), Kamil (Egypt), Barringer (USA), and Tenoumer (Mauritania) impact structures, and in experimentally generated impact glasses and laser-generated glasses (MEMIN research unit) by scanning electron microscopy, electron microprobe analysis, and transmission electron microscopy. Textural evidence of silicate liquid immiscibility includes droplets of one glass disseminated in a chemically distinct glassy matrix; sharp phase boundaries (menisci) between the two glasses; deformation and coalescence of droplets; and occurrence of secondary, nanometer-sized quench droplets in Si-rich glasses. The compositions of the conjugate immiscible liquids (Si-rich and Fe-rich) are consistent with phase separation in two-liquid fields in the general system Fe2SiO4–KAlSi3O8–SiO2–CaO–MgO–TiO2–P2O5. Major-element partition coefficients are well correlated with the degree of polymerization (NBO/T) of the Si-rich melt: Fe, Ca, Mg, and Ti are concentrated in the poorly polymerized, Fe-rich melt, whereas K, Na, and Si prefer the highly polymerized, Si-rich melt. Partitioning of Al is less pronounced and depends on bulk melt composition. Thus, major element partitioning between the conjugate liquids closely follows trends known from tholeiitic basalts, lunar basalts, and experimental analogs. The characteristics of impact melt inhomogeneity produced by melt unmixing in a miscibility gap are then compared to impact melt inhomogeneity caused by incomplete homogenization of different (miscible or immiscible) impact melts that result from shock melting of different target lithologies from the crater's melt zone, which do not fully homogenize and equilibrate due to rapid quenching. By taking previous reports on silicate emulsions in impact glasses into account, it follows that silicate impact melts of variable composition, cooling rate, and crystallization history might readily unmix during cooling, thereby rendering silicate liquid immiscibility a much more common process in the evolution of impact melts than previously recognized.  相似文献   
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We report on the microscopic impactor debris around Kamil crater (45 m in diameter, Egypt) collected during our 2010 geophysical expedition. The hypervelocity impact of Gebel Kamil (Ni‐rich ataxite) on a sandstone target produced a downrange ejecta curtain of microscopic impactor debris due SE–SW of the crater (extending ~300,000 m2, up to ~400 m from the crater), in agreement with previous determination of the impactor trajectory. The microscopic impactor debris include vesicular masses, spherules, and coatings of dark impact melt glass which is a mixture of impactor and target materials (Si‐, Fe‐, and Al‐rich glass), plus Fe‐Ni oxide spherules and mini shrapnel, documenting that these products can be found in craters as small as few tens of meters in diameter. The estimated mass of the microscopic impactor debris (<290 kg) derived from Ni concentrations in the soil is a small fraction of the total impactor mass (~10 t) in the form of macroscopic shrapnel. That Kamil crater was generated by a relatively small impactor is consistent with literature estimates of its pre‐atmospheric mass (>20 t, likely 50–60 t).  相似文献   
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Kamil is a 45 m diameter impact crater identified in 2008 in southern Egypt. It was generated by the hypervelocity impact of the Gebel Kamil iron meteorite on a sedimentary target, namely layered sandstones with subhorizontal bedding. We have carried out a petrographic study of samples from the crater wall and ejecta deposits collected during our first geophysical campaign (February 2010) in order to investigate shock effects recorded in these rocks. Ejecta samples reveal a wide range of shock features common in quartz‐rich target rocks. They have been divided into two categories, as a function of their abundance at thin section scale: (1) pervasive shock features (the most abundant), including fracturing, planar deformation features, and impact melt lapilli and bombs, and (2) localized shock features (the least abundant) including high‐pressure phases and localized impact melting in the form of intergranular melt, melt veins, and melt films in shatter cones. In particular, Kamil crater is the smallest impact crater where shatter cones, coesite, stishovite, diamond, and melt veins have been reported. Based on experimental calibrations reported in the literature, pervasive shock features suggest that the maximum shock pressure was between 30 and 60 GPa. Using the planar impact approximation, we calculate a vertical component of the impact velocity of at least 3.5 km s?1. The wide range of shock features and their freshness make Kamil a natural laboratory for studying impact cratering and shock deformation processes in small impact structures.  相似文献   
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The paper deals with the theoretical prediction of the at-rest earth pressure coefficient for normally consolidated soils (k0(NC)) using simple elasto-plastic constitutive models. In the first part of the work, the k0(NC) expressions derived from critical state soil mechanics models are critically discussed. It is shown that, adopting typical values of the models parameters, the experimental k0(NC) values are usually over-predicted. In the second part, a possible modification of the critical state model formulation, which allows to predict lower k0(NC) values for a fixed angle of shearing resistance, is considered. Finally, a discussion of the results and some brief conclusions are proposed.  相似文献   
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