Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff          下载免费PDF全文

Chuan‐An Xia  Juxiu Tong  Bill X. Hu  Xiujie Wu  Alberto Guadagnini 《水文研究》2018,32(20):3140-3157

We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AIC_C] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.  相似文献   

The Cabo Frio upwelling overrides geographical patterns in the population dynamics of the shrimp Artemesia longinaris Spence Bate, 1888 (Decapoda: Penaeidae)     

Abner Carvalho‐Batista  Joo Alberto Farinelli Pantaleo  Antonio Leo Castilho  Rogrio Caetano da Costa 《Marine Ecology》2019,40(2)

Upwelling areas are among the most productive ecosystems on the planet, influencing the biology of marine organisms. This study investigated the population dynamics of the shrimp Artemesia longinaris in two regions in southeastern Brazil, one inside (Macaé—Rio de Janeiro State) and one outside (Ubatuba—State of São Paulo) the Cabo Frio upwelling area. The aim was to verify the influence of the upwelling phenomenon on the abundance, growth, longevity, size of sexual maturity, and reproductive period of the species. In total, 188,902 individuals were captured at Macaé and 3,461 at Ubatuba. Individuals captured at Macaé showed larger maximum size, higher longevity, and slower growth rate, besides reaching sexual maturity at larger sizes than at Ubatuba. Continuous reproduction was observed in both regions, with juvenile recruitment peaks in spring and summer. Local conditions observed at Macaé were influenced by the Cabo Frio upwelling zone, characterized by productive and cooler waters that are around 20°C during most of the year. The upwelling phenomenon is probably the main factor influencing the population parameters studied here, changing the geographic patterns previously observed for the variation of these parameters in A. longinaris.  相似文献   

A depth average SPH model including μ(I) rheology and crushing for rock avalanches     

Alberto Longo  Manuel Pastor  Lorenzo Sanavia  Diego Manzanal  Miguel Martin Stickle  Chuan Lin  Angel Yague  Saeid Moussavi Tayyebi 《国际地质力学数值与分析法杂志》2019,43(5):833-857

Classical depth-integrated smoothed particle hydrodynamics (SPH) models for avalanches are extended in the present work to include a μ(I)− rheological model enriched with a fragmentation law. With this improvement, the basal friction becomes grain distribution dependent. Rock avalanches, where grain distribution tends to change with time while propagating, are the appropriate type of landslide to apply the new numerical proposal. The μ(I)− rheological models considered in the present work are those of Hatano and Gray, combined with two different fragmentation laws, a hyperbolic and a fractal-based law. As an application, Frank avalanche, which took place in Canada in 1903, is analyzed under the scope of the present approach, focusing in the influence of the rheological and fragmentation laws in the evolution of the avalanche.  相似文献   

Contextual factors influencing sustainable fisheries in Mexico     

Alejandro Espinoza-Tenorio  Ileana Espejel  Matthias Wolff  José Alberto Zepeda-Domínguez 《Marine Policy》2011

Sustainable fisheries take into consideration that managed fisheries ecosystems shift over time in response to evolving environmental as well as market and political factors. These contextual forces are especially valuable in understanding developing countries such as Mexico, where the unconsolidated fisheries administration faces productive marine ecosystems but unsustainable fisheries. To recognize the issues that have inhibited the consolidation of a regulatory system for sustainable fisheries, a contextual factor analysis was applied to the co-development of two current policies in the Mexican fishery regime: fisheries and environmental policies. Six historical phases have been identified in which there are few long periods of stability and frequent short periods of radical change that alternate between stable and adverse contextual situations. These short and contrasting contextual situations cause a kind of tug-of-war in Mexican fisheries policy-making. On the one hand, domestic economic, scientific, and technological forces seem to slowly lead toward the consolidation of sustainable fisheries; on the other hand, domestic policies drift from one position to another at other timing than the international fisheries and environmental policies. Although recent crises seem to highlight new periods of radical change in Mexico, they also provide an opportunity to adopt new structural plans to consolidate domestic forces as a basis for long-term strategies.  相似文献   

Structural-stratigraphic control on the Umitaka Spur gas hydrates of Joetsu Basin in the eastern margin of Japan Sea   总被引：1，自引：0，他引：1  

Antonio Fernando Menezes Freire  Ryo Matsumoto  Luiz Alberto Santos 《Marine and Petroleum Geology》2011,28(10):1967-1978

Integrated geological, geochemical, and geophysical exploration since 2004 has identified massive accumulation of gas hydrate associated with active methane seeps on the Umitaka Spur, located in the Joetsu Basin on the eastern margin of Japan Sea. Umitaka Spur is an asymmetric anticline formed along an incipient subduction zone that extends throughout the western side of the Japanese island-arc system. Seismic surveys recognized chimney structures that seem strongly controlled by a complex anticlinal axial fault system, and exhibit high seismic amplitudes with apparent pull-up structures, probably due to massive and dense accumulation of gas hydrate. Bottom simulating reflectors are widely developed, in particular within gas chimneys and in the gently dipping eastern flank of the anticline, where debris can store gas hydrates that may represent a potential natural gas resource. The axial fault system, the shape of the anticline, and the carrier beds induce thermogenic gas migration to the top of the structure, and supply gas to the gas hydrate stability zone. Gas reaching the seafloor produces strong seepages and giant plumes in the sea water column.  相似文献   

The 29 September 2009 Samoa Islands Tsunami: Simulations Based on the First Focal Mechanism Solutions and Implications on Tsunami Early Warning Strategies     

Roberto Tonini  Alberto Armigliato  Stefano Tinti 《Pure and Applied Geophysics》2011,168(6-7):1113-1123

The tsunamigenic earthquake (Mw?=?8.1) that occurred on 29 September 2009 at 17:48 UTC offshore of the Samoa archipelago east of the Tonga trench represents an example of the so-called ??outer-rise?? earthquakes. The areas most affected were the south coasts of Western and American Samoa, where almost 200 people were killed and run-up heights were measured in excess of 5?m at several locations along the coast. Moreover, tide gauge records showed a maximum peak-to-peak height of about 3.5?m near Pago Pago (American Samoa) and of 1.5?m offshore of Apia (Western Samoa). In this work, different fault models based on the focal mechanism solutions proposed by Global CMT and by USGS immediately after the 2009 Samoan earthquake are tested by comparing the near-field recorded signals (three offshore DART buoys and two coastal tide gauges) and the synthetic signals provided by the numerical simulations. The analysis points out that there are lights and shadows, in the sense that none of the computed tsunamis agrees satisfactorily with all the considered signals, although some of them reproduce some of the records quite well. This ??partial agreement?? and ??partial disagreement?? are analysed in the perspective of tsunami forecast and of Tsunami Early Warning System strategy.  相似文献   

SLA–chlorophyll-a variability and covariability in the Algero-Provençal Basin (1997–2007) through combined use of EOF and wavelet analysis of satellite data     

Antonio Olita  Alberto Ribotti  Roberto Sorgente  Leopoldo Fazioli  Angelo Perilli 《Ocean Dynamics》2011,61(1):89-102

Data reduction and signal decomposition techniques have been applied to a large bio-physical remotely sensed dataset covering the decade 1997–2007. The aim was the estimation of the spatial (basin and sub-basin scales) and temporal (seasonal and interannual) variability of sea level anomalies and chlorophyll-a concentration in the Algero-Provençal Basin, as well as the study of their covariability. Empirical orthogonal functions, wavelet analysis, singular value decomposition and correlation maps have been successfully used to individuate the patterns of (co)variability of the investigated fields. The seasonal variability of the phytoplanktonic biomass is divided in two distinct modes, timewise and spacewise separated. Positive interannual events are related to anomalies in 1999 and 2005, while the main (negative) anomaly is that of summer 2003, associated to the European 2003 heatwave. The analysis of the sea level anomalies shows a minimum in the formation of anticyclonic Algerian eddies during that period. The largest anticorrelation between sea level anomalies and phytoplanktonic biomass is found in the central zone of the basin, suggesting a clear biological response to the shoaling/deepening of the isopycnae and so to the nutrient injection into the euphotic layer. The analysis suggests that the driver of the variability of the nutricline depth in this central area is the displacement (seasonal) of the North Balearic Front and the formation/action of the frontal eddies.  相似文献   

An overview of seismic testing needs in Europe: towards a new advanced experimental facility     

Francesco Marazzi  Ioannis Politopoulos  Alberto Pavese 《Bulletin of Earthquake Engineering》2011,9(2):623-640

This paper presents a synthesis of the activities carried out in the framework of the European project EFAST (design study of a European Facility for Advanced Seismic Testing) to determine the general characteristics of a new European world-class facility for earthquake testing of structures. To this end the demands for the necessary testing to support the modern seismic engineering research have been investigated and compared to the actual capabilities of European laboratories. The outcome is the determination of performance objectives and requirements in the gross. On the basis of the needs assessment carried out during the first phase of the project and taking into account the technological advances in both experimental techniques and equipment (hardware and software) for seismic testing, a modern facility for experimental seismic research should be composed, mainly, of a high performance shaking tables array and a large reaction structure where both traditional (pseudo-static/dynamic) and innovative testing techniques (e.g. real time hybrid testing) can be applied and combined. A tentative layout of the facility is also proposed and issues related to the best utilization of such a laboratory are discussed.  相似文献   

Cotton Fiber/ZrO2, A New Material for Adsorption of Cr(VI) Ions in Water     

Alfredo Alberto Muxel  Sonia Maria Nobre Gimenez  Flaveli Aparecida de Souza Almeida  Rení Ventura da Silva Alfaya  Antonio Alberto da Silva Alfaya 《洁净——土壤、空气、水》2011,39(3):289-295

The natural cotton fiber was used to synthesize an anion exchange, containing ZrO₂ film on its surface, NCFZC (natural cotton fiber/ZrO₂ composite). This anion exchanger was produced by the reaction of the zirconium oxychloride and hydroxyl groups on surface of the natural cotton fiber. The material was used for Cr(VI) ions adsorption studies. Adsorption equilibrium time and optimum pH for Cr(VI) adsorption were found to be 6 h and 4.0, respectively. The Langmuir and Temkin isotherms were used to models adsorption equilibrium data. The adsorption capacity of NCFZC was found to be 1.33 mmol/g. Kinetic studies showed that the rate of adsorption of Cr(VI) on NCFZC obeyed a pseudo‐second‐order kinetic model.  相似文献   

Terrestrial laser scanning to estimate plot-level forest canopy fuel properties     

Mariano García  F. Mark Danson  David Riaño  Emilio Chuvieco  F. Alberto Ramirez  Vishal Bandugula 《International Journal of Applied Earth Observation and Geoinformation》2011

This paper evaluates the potential of a terrestrial laser scanner (TLS) to characterize forest canopy fuel characteristics at plot level. Several canopy properties, namely canopy height, canopy cover, canopy base height and fuel strata gap were estimated. Different approaches were tested to avoid the effect of canopy shadowing on canopy height estimation caused by deployment of the TLS below the canopy. Estimation of canopy height using a grid approach provided a coefficient of determination of R² = 0.81 and an RMSE of 2.47 m. A similar RMSE was obtained using the 99th percentile of the height distribution of the highest points, representing the 1% of the data, although the coefficient of determination was lower (R² = 0.70). Canopy cover (CC) was estimated as a function of the occupied cells of a grid superimposed upon the TLS point clouds. It was found that CC estimates were dependent on the cell size selected, with 3 cm being the optimum resolution for this study. The effect of the zenith view angle on CC estimates was also analyzed. A simple method was developed to estimate canopy base height from the vegetation vertical profiles derived from an occupied/non-occupied voxels approach. Canopy base height was estimated with an RMSE of 3.09 m and an R² = 0.86. Terrestrial laser scanning also provides a unique opportunity to estimate the fuel strata gap (FSG), which has not been previously derived from remotely sensed data. The FSG was also derived from the vegetation vertical profile with an RMSE of 1.53 m and an R² = 0.87.  相似文献