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This study concentrates on the petrological and geochemical investigation of mafic rocks embedded within the voluminous Triassic June Complex of the central Sanandaj–Sirjan zone (Iran), which are crucial to reconstruct the geodynamics of the Neotethyan passive margin. The Triassic mafic rocks are alkaline to sub-alkaline basalts, containing 43.36–49.09 wt% SiO2, 5.19–20.61 wt% MgO and 0.66–4.59 wt% total alkalis. Based on MgO concentrations, the mafic rocks fall into two groups: cumulates (Mg# = 51.61–58.94) and isotropic basaltic liquids (Mg# = 24.54–42.66). In all samples, the chondrite-normalized REE patterns show enrichment of light REEs with variable (La/Yb)N ratios ranging from 2.48 to 9.00, which confirm their amalgamated OIB-like and E-MORB-like signatures. Enrichment in large-ion lithophile elements and depletion in high field strength elements (HFSE) relative to the primitive mantle further support this interpretation. No samples point to crustal contamination, all having undergone fractionation of olivine + clinopyroxene + plagioclase. Nevertheless, elemental data suggest that the substantial variations in (La/Sm)PM and Zr/Nb ratios can be explained by variable degrees of partial melting rather than fractional crystallization from a common parental magma. The high (Nb/Yb)PM ratio in the alkaline mafic rocks points to the mixing of magmas from enriched and depleted mantle sources. Abundant OIB alkaline basalts and rare E-MORB appear to be linked to the drifting stage on the northern passive margin of the Neotethys Ocean.  相似文献   
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The Upper Jurassic Sargelu and the Cretaceous Garau formations are important source rocks in the Lurestan basin, southwest Iran. In this study, the maturity evolution and burial history of these source rocks are investigated using 1D modeling in 15 wells within the Lurestan basin. These models are calibrated using temperature and vitrinite reflectance readings at well locations. Results indicate that thermal maturity of studied source rocks increases towards the northwest of the Lurestan basin and is the lowest over the Anaran High. The present-day level of maturity suggests that these formations are suitable candidates for shale gas resources in the Lurestan basin.  相似文献   
4.
Human‐induced land use/land cover (LULC) changes are among the most important processes that shape the dynamics of the earth’s surface. This phenomenon, which is occurring at an astonishing rate, and its consequential environmental impacts have become an important area of research for scientists.Therefore, a wide range of methods and models have been developed to detect and predict these alterations, among which cellular automata (CA) models such as the CA‐Markov model, due to their affinity to geographic information system (GIS) and remote sensing (RS), are appropriate for detailed resolution modelling and simulating dynamic spatial processes. In Iran, the district of Ravansar has undergone severe LULC changes recently, thus to take the necessary precautions, decision‐makers need to predict and determine the extent of these changes. In this study, using spatial analysis methods the LULC changes in Ravansar were investigated from 1992 to 2015. Subsequently, the CA‐Markov model was applied to simulate the spatial pattern changes of LULC until 2030. Our results indicated that from 1992 to 2015, this region has witnessed a noticeable increase in the areas of the built‐up and agricultural lands (both aquatic and non‐aquatic), resulting in the decrease of the gardens, range, and bare lands. The simulated LULC map showed that this trend will continue due to more urbanization and development of agricultural areas.  相似文献   
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Understanding the impacts of land‐use changes on hydrology at the watershed scale can facilitate development of sustainable water resource strategies. This paper investigates the hydrological effects of land‐use change in Zanjanrood basin, Iran. The water balance was simulated using the Soil and Water Assessment Tool (AVSWAT2000). Model calibration and uncertainty analysis were performed with sequential uncertainty fitting (SUFI‐2). Simulation results from January 1998 to December 2002 were used for parameter calibration, and then the model was validated for the period of January 2003 to December 2004. The predicted monthly streamflow matched the observed values: during calibration the correlation coefficient was 0·86 and the Nash–Sutcliffe coefficient 0·79, compared with 0·80 and 0·79, respectively, during validation. The model was used to simulate the main components of the hydrological cycle, in order to study the effects of land‐use changes in 1967, 1994 and 2007. The study reveals that during 1967 a 34·5% decrease of grassland with concurrent increases of shrubland (13·9%), rain‐fed agriculture (12·1%), bare ground (5·5%) irrigated agriculture (2·2%), and urban area (0·7%) led to a 33% increase in the amount of surface runoff and a 22% decrease in the groundwater recharge. Furthermore, the area of sub‐basins that was influenced by high runoff (14–28 mm) increased. The results indicate that the hydrological response to overgrazing and the replacing of rangelands (grassland and shrubland) with rain‐fed agriculture and bare ground (badlands) is nonlinear and exhibits a threshold effect. The runoff rises dramatically when more than 60% of the rangeland is removed. For groundwater this threshold lies at an 80% decrease in rangeland. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   
6.
Ambient response measurements were made on an eighteen-storey building at three different stages of construction to detect any changes in the frequencies, mode shapes and stiffness with construction. The first nine frequencies and corresponding mode shapes for each stage of construction are found. A comparison is made among these mode shapes and frequencies and with the mode shapes and frequencies of an analytical model incorporating beams, columns, shear walls, panels and diagonal elements. The added effects, on frequencies and mode shapes, of non-structural elements such as stairs, elevators, claddings and partition walls are studied. Using Improved Statistical Structural Identification, an attempt is made to study the stiffening effect of non-structural elements by updating the stiffness matrix of the building.  相似文献   
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A new organic/inorganic composite based on polyacrylonitrile and stannic molybdophosphate (PAN–SMP) as an adsorbent was synthesized under various conditions. The physicochemical properties of this material were specified by elemental analysis, scanning electron microscopy, infrared spectroscopy and thermogravimetry studies. The synthesized material was found to be stable in demineralized water, in dilute acids, under gamma radiation up to the total radiated of 100 kGy doses and in high temperature up to 500 °C. Ion exchange capacity of the synthesized composite and its distribution coefficient (K d) for several metal ions were determined. The results showed that PAN–SMP has a great affinity toward some metal ions such as Tl+, Sr2+, Ba2+, UO2 2+ and La4+. Based on the determined K d values, two binary quantitative separations of metal ions (Cr6+ from Cu2+ and Pb2+ from Cu2+) have been achieved on columns of this ion exchanger. The ability of PAN–SMP to decontaminate low-level liquid waste was also investigated.  相似文献   
9.
The cross-validation technique is a popular method to assess and improve the quality of prediction by least squares collocation (LSC). We present a formula for direct estimation of the vector of cross-validation errors (CVEs) in LSC which is much faster than element-wise CVE computation. We show that a quadratic form of CVEs follows Chi-squared distribution. Furthermore, a posteriori noise variance factor is derived by the quadratic form of CVEs. In order to detect blunders in the observations, estimated standardized CVE is proposed as the test statistic which can be applied when noise variances are known or unknown. We use LSC together with the methods proposed in this research for interpolation of crustal subsidence in the northern coast of the Gulf of Mexico. The results show that after detection and removing outliers, the root mean square (RMS) of CVEs and estimated noise standard deviation are reduced about 51 and 59%, respectively. In addition, RMS of LSC prediction error at data points and RMS of estimated noise of observations are decreased by 39 and 67%, respectively. However, RMS of LSC prediction error on a regular grid of interpolation points covering the area is only reduced about 4% which is a consequence of sparse distribution of data points for this case study. The influence of gross errors on LSC prediction results is also investigated by lower cutoff CVEs. It is indicated that after elimination of outliers, RMS of this type of errors is also reduced by 19.5% for a 5 km radius of vicinity. We propose a method using standardized CVEs for classification of dataset into three groups with presumed different noise variances. The noise variance components for each of the groups are estimated using restricted maximum-likelihood method via Fisher scoring technique. Finally, LSC assessment measures were computed for the estimated heterogeneous noise variance model and compared with those of the homogeneous model. The advantage of the proposed method is the reduction in estimated noise levels for those groups with the fewer number of noisy data points.  相似文献   
10.
Tertiary volcanic rocks in northwestern Firoozeh, Iran (the Meshkan triangular structural unit), constitute vast outcrops (up to 250 km2) of high-Mg basaltic andesites to dacites that are associated with high-Nb hawaiites and mugearites. Whole-rock 40Ar/39Ar ages show a restricted range of 24.1 ± 0.4–22.9 ± 0.5 Ma for the volcanic rocks. The initial ratios of 87Sr/86Sr and 143Nd/144Nd vary from 0.703800 to 0.704256 and 0.512681 to 0.512877, respectively, in the high-Mg basaltic andesites–dacites. High-Th contents (up to 11 ppm) and Sr/Y values (27–100) and the isotopic composition of the subalkaline high-Mg basaltic andesites–dacites indicate derivation from a mantle modified by slab and sediment partial melts. Evidence such as reverse zoning and resorbed textures and high Ni and Cr contents in the evolved samples indicate that magma mixing with mafic melts and concurrent fractional crystallization lead to the compositional evolution of this series. The high-Nb hawaiites and mugearites, by contrast, have a sodic alkaline affinity and are silica undersaturated; they are also enriched in Nb (up to 47 ppm) and a wide range of incompatible trace elements, including LILE, LREE, and HFSE. Geochemistry and Sr–Nd isotopic compositions of the high-Nb hawaiites and mugearites suggest derivation from a mantle source affected by lower degrees of slab melts. Post-orogenic slab break-off is suggested to have prompted the asthenospheric upwelling that triggered partial melting in mantle metasomatized by slab-derived melts.  相似文献   
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