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1.
The distribution of the dissolved labile and of the particulate Fe and Cu together with dissolved oxygen, nutrients, chlorophyll a and total particulate matter was investigated in the surface waters of Terra Nova Bay polynya in mid-January 2003. The measurements were conducted within the framework of the Italian Climatic Long-term Interactions of the Mass balance in Antarctica (CLIMA) Project activities. The labile dissolved fraction was operationally defined by employing the chelating resin Chelex-100, which retains free and loosely bound trace metal species. The dissolved labile Fe ranges from below the detection limit (0.15 nM) to 3.71 nM, while the dissolved labile Cu from below the detection limit (0.10 nM) to 0.90 nM. The lowest concentrations for both metals were observed at 20 m depth (the shallowest depth for which metals were measured). The concentration of the particulate Fe was about 5 times higher than the dissolved Fe concentration, ranging from 0.56 to 24.83 nM with an average of 6.45 nM. The concentration of the particulate Cu ranged from 0.01 to 0.71 nM with an average of 0.17 nM. The values are in agreement with the previous data collected in the same area. We evaluated the role of the Fe and Cu as biolimiting metals. The N:dissolved labile Fe ratios (18,900–130,666) would or would not allow a complete nitrate removal, on the basis of the N:Fe requirement ratios that we calculated considering the N:P and the C:P ratios estimated for diatoms. This finding partially agrees with the Si:N ratio that we found (2.29). Moreover we considered a possible influence of the dissolved labile Cu on the Fe uptake process.  相似文献   
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A new method of searching for dark matter in the form of weakly interacting massive particles (WIMP) has been developed with the direct detection of the low energy nuclear recoils observed in a massive target (ultimately many tons) of ultra pure liquid argon at 87 K. A high selectivity for argon recoils is achieved by the simultaneous observation of both the VUV scintillation luminescence and of the electron signal surviving columnar recombination, extracted through the liquid–gas boundary by an electric field.

First physics results from this method are reported, based on a small 2.3 l test chamber filled with natural argon and an accumulated fiducial exposure of about 100 kg day, supporting the future validity of this method with isotopically purified 40Ar and for a much larger unit presently under construction with correspondingly increased sensitivities.  相似文献   

4.
Abstract. During the austral summer 1997–98, within the framework of the activities of the Climatic Long-term Interaction for the Massbalance in Antarctica (CLIMA) Project of the Italian National Program for Antarctic Research (PNRA) in the Ross Sea, measurements were conducted to focus on the role of dissolved iron, copper and manganese as micronutrients, and on their distribution in suspended particulate matter in different water masses. Sampling was carried out in two selected shelf areas, both important for formation and mixing processes of the water bodies.
Metal data were evaluated together with physical measurements and classical chemical parameters such as oxygen and nutrients.
In both the studied areas, the distribution of dissolved metals along the waste column confirmed their micronutrient behaviour, showing depletion where phytoplanktonic activities occurred.
The trend of particulate metals underlined the scavenging phenomena along the water column and presented an interesting correlation at intermediate depths with the amount and origin of suspended matter.  相似文献   
5.
Intense blooms of the benthic dinoflagellate Ostreopsis cf. ovata have occurred in the northern Adriatic Sea since 2006. These blooms are associated with noxious effects on human health and with the mortality of benthic organisms because of the production of palytoxin-like compounds. The O. cf. ovata bloom and its relationships with nutrient concentrations at two stations on the Conero Riviera (northern Adriatic Sea) were investigated in the summer of 2009. O. cf. ovata developed from August to November, with the highest abundances in September (1.3 × 106 cells g−1 fw corresponding to 63.8 × 103 cells cm−2). The presence of the single O. cf. ovata genotype was confirmed by a PCR assay. Bloom developed when the seawater temperature was decreasing. Nutrient concentrations did not seem to affect bloom dynamics. Toxin analysis performed by high resolution liquid chromatography-mass spectrometry revealed a high total toxin content (up to 75 pg cell−1), including putative palytoxin and all the ovatoxins known so far.  相似文献   
6.
This article analyzes the geochemical and mineralogical composition of the roofing slate deposits of the Iberian Peninsula. Most roofing slate deposits are found on Middle and Upper Ordovician terrains, although there are also deposits in the Ediacaran, Cambrian and Devonian terrains. Samples of slate were taken in most of the active quarries of the Iberian Peninsula, and being analyzed by X-ray Diffraction and Fluorescence. Each lithotect or slate productive formation has its own specific proportions of major and trace elements, being able to differentiate between them by using these relationships. This fact is particularly interesting in geological exploration and prospecting, as it allows knowing exactly the slate lithotect, and also for restoration work in the architectural heritage, due to the ability of identifying the source of the original slate tiles.  相似文献   
7.
Peridotite xenoliths entrained in Plio-Pleistocene alkali basalts from Sardinia represent fragments of the uppermost lithospheric mantle, and are characterised by an anhydrous four-phase mineral assemblage. They range in bulk rock composition from fertile spinel-lherzolites to residual spinel-harzburgites. The Sr-Nd isotope and trace element composition of clinopyroxene mineral separates varies between LREE-depleted samples with 87Sr/86Sr as low as 0.70262 and 143Nd/144Nd up to 0.51323 and LREE-enriched samples with 87Sr/86Sr up to 0.70461 and 143Nd/144Nd down to 0.51252. The available data suggest that all the studied peridotite samples suffered variable degrees of partial melting during Pre-Mesozoic times (based on Nd model ages relative to CHUR and DMM). The overprinted enrichment is related to a subsequent metasomatism, induced by fluids rising through the lithosphere that preferentially percolated the originally most depleted domains. Despite the occurrence of orogenic volcanism in the area, preferential enrichment in elements typically associated with slab derived fluids/melts (K, Rb, Sr, Th) relative to LREE has not been detected, and metasomatism seems to be more likely related to the infiltration of highly alkaline basic melts characterised by an EM-like Sr-Nd isotopic composition. Similar 87Sr/86Sr-143Nd/144Nd compositions, characterised by an EM signature, are observed in anorogenic mafic lavas and peridotite xenoliths from widespread localities within the "European" plate, whereas they have not previously been recorded in peridotite xenoliths and associated alkaline mafic lavas from the stable "African" lithospheric domain.  相似文献   
8.
A comprehensive volcanological study of the Albano multiple maar (Alban Hills, Italy) using (i) 40Ar/39Ar geochronology of the most complete stratigraphic section and other proximal and distal outcrops and (ii) petrographic observations, phase analyses of major and trace elements, and Sr and O isotopic analyses of the pyroclastic deposits shows that volcanic activity at Albano was strongly discontinuous, with a first eruptive cycle at 69±1 ka producing at least two eruptions, and a second cycle with two peaks at 39±1 and 36±1 ka producing at least four eruptions. Contrary to previous studies, we did not find evidence of magmatic or hydromagmatic eruptions younger than 36±1 ka. The activity of Albano was fed by a new batch of primary magma compositionally different from that of the older activity of the Alban Hills; moreover, the REE and 87Sr/86Sr data indicate that the Albano magma originated from an enriched metasomatized mantle. According to the modeled liquid line of descent, this magma differentiated under the influence of magma/limestone wall rock interaction. Our detailed eruptive and petrologic reconstruction of the Albano Maar evolution substantiates the dormant state of the Alban Hills Volcanic District. Electronic Supplementary Material Supplementary material is available for this article at Editorial responsibility: J. Donnelly-Nolan An erratum to this article can be found at  相似文献   
9.
Crystal-poor, differentiated magmas are commonly erupted from shallow, thermally zoned magma chambers. In order to constrain the origin of these magmas, we have experimentally investigated crystallization, differentiation and crystal-melt separation in presence of a thermal gradient. Experiments have been designed taking advantage of the innate temperature gradient of the piston cylinder apparatus and carried out on a phonolitic system at 0.3 GPa and temperature ranging from 1,050 to 800°C. Crystallization degree and melt composition in experimental products vary as a function of the temperature gradient. In particular, melt composition differentiates from tephri-phonolite (starting material) to phonolite moving from the hotter, glassy zone (T ≤ 1,050°C) towards the cooler, heterogeneously crystallized zone (T ≤ 900°C) of the charge. The heterogeneously crystallized zone is made up of: (1) a crystal-rich, mushy region (crystallinity >30 vol%), (2) a rigid crystal framework (crystallinity ≤80 vol%) and (3) glassy belts of phonolitic glass at the top. Thermal gradient experiments picture crystallization, differentiation and crystal-melt separation processes occurring in a thermally zoned environment and reveal that relatively large volumes of crystal-poor melt (glassy belts) can originate as a consequence of the instability and collapse of the rigid crystal framework. Analogously, in thermally zoned magma chambers, the development and collapse of a solidification front may represent the controlling mechanism originating large volumes of crystal-poor, differentiated magmas.  相似文献   
10.

Phosphorus (P) is an essential nutrient required for plant growth and at the same time a costly pollutant, which can cause eutrophication of water bodies. Modern agriculture relies heavily on mineral fertilisers, which contain phosphorus derived from phosphate rock, because, without regular applications, crop yields would be limited. Since phosphate rock is a non-renewable resource, there are growing concerns regarding future phosphorus scarcity and the sustainability of modern agriculture. For many farmers, animal manure was once a means of maintaining soil fertility, but now it presents a major operational problem. This study evaluated the possibility of recycling phosphorus on a national and regional scale in Italy, using major sources of manure and wastewater. These results were successively compared with an estimate of the agricultural demand for phosphorus. Considering the quantity of phosphorus fertilizer that was applied to the soil–plant system, for the years 2001–2010, the annual phosphorus requirement of Italian crops was about 101,000 t of P. Therefore, the phosphorus source comprising animal manure and civil/industrial waste (117,500 t of P and 40,000 t of P, respectively) could potentially satisfy the average annual agronomic phosphorus demand. Regarding the geographical distribution of phosphorus supply and demand on a regional scale, areas with a large deficit of phosphorus included Calabria, Puglia and Marche. However, when only livestock waste was considered, Sicily, Umbria and Friuli could also be considered to be regions experiencing a phosphorus deficit.

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