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In seismic retrofitting of concrete buildings, frame bays are converted into reinforced concrete (RC) walls by infilling the space between the frame members with RC of a thickness of not more than their width. The cyclic behavior of the resulting wall depends on the connection between the RC infill and the surrounding RC members. The paper uses the results from 56 cyclic tests on such composite walls to express their properties in terms of the geometry, the reinforcement and the connection. Properties addressed are: (a) the yield moment at the story base; (b) the secant-to-yield-point stiffness over the shear span of the wall in a story; (c) the deflection at flexural failure in cyclic loading; (d) the cyclic shear resistance, including a sliding shear failure mode. Separate models are given for squat walls failing in shear and for those where the top of the column shears-off. The proposals are modifications of models developed in the past for monolithic RC walls from several hundred cyclic tests; blind application of these latter models as though the walls were monolithic gives, in general, unsafe predictions. By contrast, the diagonal compression strut approach in ASCE41-06 is safe-sided, but gives unacceptably large prediction scatter.  相似文献   
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Hydrothermal experiments were conducted to evaluate the kinetics of H2(aq) oxidation in the homogeneous H2-O2-H2O system at conditions reflecting subsurface/near-seafloor hydrothermal environments (55-250 °C and 242-497 bar). The kinetics of the water-forming reaction that controls the fundamental equilibrium between dissolved H2(aq) and O2(aq), are expected to impose significant constraints on the redox gradients that develop when mixing occurs between oxygenated seawater and high-temperature anoxic vent fluid at near-seafloor conditions. Experimental data indicate that, indeed, the kinetics of H2(aq)-O2(aq) equilibrium become slower with decreasing temperature, allowing excess H2(aq) to remain in solution. Sluggish reaction rates of H2(aq) oxidation suggest that active microbial populations in near-seafloor and subsurface environments could potentially utilize both H2(aq) and O2(aq), even at temperatures lower than 40 °C due to H2(aq) persistence in the seawater/vent fluid mixtures. For these H2-O2 disequilibrium conditions, redox gradients along the seawater/hydrothermal fluid mixing interface are not sharp and microbially-mediated H2(aq) oxidation coupled with a lack of other electron acceptors (e.g. nitrate) could provide an important energy source available at low-temperature diffuse flow vent sites.More importantly, when H2(aq)-O2(aq) disequilibrium conditions apply, formation of metastable hydrogen peroxide is observed. The yield of H2O2(aq) synthesis appears to be enhanced under conditions of elevated H2(aq)/O2(aq) molar ratios that correspond to abundant H2(aq) concentrations. Formation of metastable H2O2 is expected to affect the distribution of dissolved organic carbon (DOC) owing to the existence of an additional strong oxidizing agent. Oxidation of magnetite and/or Fe++ by hydrogen peroxide could also induce formation of metastable hydroxyl radicals (•OH) through Fenton-type reactions, further broadening the implications of hydrogen peroxide in hydrothermal environments.  相似文献   
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Mechanics-based models are developed for the moment, the curvature and the chord rotation at yielding of circular concrete columns or piers, their secant stiffness to the yield point and the ultimate curvature and flexure-controlled ultimate chord rotation in cyclic loading. The strain criteria for yielding or ultimate are calibrated on the basis of over four hundred test results. Besides the model for the secant-to-yield-point stiffness which is in terms of the yield moment and chord rotation, an empirical one, independent of the vertical reinforcement, is fitted to the data. The ultimate chord rotation is obtained from a plastic hinge model employing a plastic hinge length, the yield and the ultimate curvatures of the end section and the fixed-end rotation due to slippage of bars from their anchorage zone beyond the column length. All models are extended to columns the vertical bars of which are lap-spliced within the plastic hinge and to columns with FRP wrapping and continuous or lap-spliced vertical bars. The comprehensive portfolio of expressions proposed for the deformation properties of circular columns is fully consistent across the various situations of continuous or lap-spliced bars, with or without FRP wrapping, and with models developed by the authors from much larger databases of rectangular columns in similar situations; the aspects specific to circular sections are limited to the mechanics-based section analysis for moment and curvature, a purely empirical coefficient for the secant-to-yield-point stiffness and the empirical plastic hinge length.  相似文献   
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The unloading parameters of hysteretic models for RC members are given in terms of their shear-span-to-depth ratio and the viscous damping used to model other energy dissipation sources. They reflect the energy dissipation in full post-yield load cycles in 534 tests of rectangular or circular members. Pre-yield hysteretic energy dissipation—ignored if the model is elastic till yielding—amounts in the tests to a mean viscous damping around 8.5% and can be considered in nonlinear response-history analysis through a new model which combines constant elastic stiffness in virgin loading with hysteretic energy dissipation both before and after yielding. Models with linear behavior till yielding and hysteretic energy dissipation only after it come closer to the results of the new model if viscous damping is 5%.  相似文献   
6.
Low temperature vent fluids (<91 °C) issuing from the ultramafic-hosted hydrothermal system at Lost City, 30°N Mid-Atlantic Ridge, are enriched in dissolved volatiles (H2,CH4) while attaining elevated pH values, indicative of the serpentization processes that govern water/rock interactions deep in the oceanic crust. Here, we present a series of theoretical models to evaluate the extent of hydrothermal alteration and assess the effect of cooling on the systematics of pH-controlled B aqueous species. Peridotite-seawater equilibria calculations indicate that the mineral assemblage composed of diopside, brucite and chrysotile likely dictates fluid pH at moderate temperature serpentinization processes (<300 °C), by imposing constraints on the aCa++/a2H+ ratios and the activity of dissolved SiO2. Based on Sr abundances and the 87Sr/86Sr isotope ratios of vent fluids reported from Lost City, estimated water/rock mass ratios (w/r = 2-4) are consistent with published models involving dissolved CO2 and alkane concentrations. Combining the reported δ18O values of vent fluids (0.7‰) with such w/r mass ratios, allows us to bracket subseafloor reaction temperatures in the vicinity of 250 °C. These estimates are in agreement with previous theoretical studies supporting extensive conductive heat loss within the upflow zones. Experimental studies on peridotite-seawater alteration suggest that fluid pH increases during cooling which then rapidly enhances boron removal from solution and incorporation into secondary phases, providing an explanation for the highly depleted dissolved boron concentrations measured in the low temperature but alkaline Lost City vent fluids. Finally, to account for the depleted 11B composition (δ11B ∼25-30‰) of vent fluids relative to seawater, isotopic fractionation between tetrahedrally coordinated aqueous boron species with BO3-bearing mineral sites (e.g. in calcite, brucite) is proposed.  相似文献   
7.
Cyclic tests of single concrete columns with smooth (plain) bars are not representative of building columns with lap splices at floor levels and story-long starter bars. Column specimens with fixity at top and bottom resemble building columns best, but few of those tested so far had smooth bars and even then without bar lap-splicing at floor level or FRP jackets at column ends. Empirical models based on single-column tests, especially the numerous ones with cantilever-type specimens, cannot be readily extended to columns with smooth bars in real-life buildings. Physical models of the Strut-and-Tie type are developed and are validated or calibrated through comparisons with laboratory tests. Their scope includes anchorage and splicing of bars with either 180° hooks or straight ends. Once validated, they are adapted to real-life multistory rectangular RC columns with smooth bars, in order to obtain the column properties of interest: the chord rotation at yielding and the cyclic ultimate chord rotation, with or without FRP jacketing. Different expressions apply to the top and bottom end of a column in a story, but a single one is used to estimate the column’s effective stiffness. Empirical alternatives fitted to the single-element test results have slightly less scatter than physical models, but caution is needed for their application to columns of real buildings. Simulations of the 3D seismic response of a plan wise asymmetric full size building, tested pseudo-dynamically before or after retrofitting all columns with FRPs or just two of them with RC jackets, provide certain confidence in the extension of the physical models for the estimation of the stiffness and ultimate deformation of columns with smooth bars in real-life buildings.  相似文献   
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