Low‐P and high‐T metamorphism of basalts: Insights from the Sudbury impact melt sheet aureole and thermodynamic modelling     

Taus R. C. Jrgensen  Douglas K. Tinkham  C. Michael Lesher 《Journal of Metamorphic Geology》2019,37(2):271-313

Low‐pressure and high‐temperature (LP–HT) metamorphism of basaltic rocks, which occurs globally and throughout geological time, is rarely constrained by forward phase equilibrium modelling, yet such calculations provide valuable supplementary thermometric information and constraints on anatexis that are not possible to obtain from conventional thermometry. Metabasalts along the southern margin of the Sudbury Igneous Complex (SIC) record evidence of high‐grade contact metamorphism involving partial melting and melt segregation. Peak metamorphic temperatures reached at least ~925°C at ~1–3 kbar near the SIC contact. Preservation of the peak mineral assemblage indicates that most of the generated melt escaped from these rocks leaving a residuum characterized by a plagioclase–orthopyroxene–clinopyroxene–ilmenite‐magnetite±melt assemblage. Peak temperatures reached ~875°C up to 500 m from the SIC lower contact, which marks the transition to metabasalts that only experienced incipient partial melting without melt loss. Metabasalts ~500 to 750 m from the SIC contact are characterized by a similar two‐pyroxene mineral assemblage, but typically contain abundant hornblende that overgrew clino‐ and orthopyroxene along an isobaric cooling path. Metabasalts ~750 to 1,000 m from the SIC contact are characterized by a hornblende–plagioclase–quartz–ilmenite assemblage indicating temperatures up to ~680°C. Mass balance and phase equilibria calculations indicate that anatexis resulted in 10–20% melt generation in the inner ~500 m of the aureole, with even higher degrees of melting towards the contact. Comparison of multiple models, experiments, and natural samples indicates that modelling in the Na₂O–CaO–FeO–MgO–Al₂O₃–SiO₂–H₂O–TiO₂–O₂ (NCFMASHTO) system results in the most reliable predictions for the temperature of the solidus. Incorporation of K₂O in the most recent amphibole solution model now successfully predicts dehydration melting by the coexistence of high‐Ca amphibole and silicate melt at relatively low pressures (~1.5 kbar). However, inclusion of K₂O as a system component results in prediction of the solidus at too low a temperature. Although there are discrepancies between modelling predictions and experimental results, this study demonstrates that the pseudosection approach to mafic rocks is an invaluable tool to constrain metamorphic processes at LP–HT conditions.  相似文献   

Sediment routing in the Zagros foreland basin: Drainage reorganization and a shift from axial to transverse sediment dispersal in the Kurdistan region of Iraq     

Renas I. Koshnaw  Brian K. Horton  Daniel F. Stockli  Douglas E. Barber  Mazin Y. Tamar-Agha 《Basin Research》2020,32(4):688-715

In the northwestern sector of the Zagros foreland basin, axial fluvial systems initially delivered fine-grained sediments from northwestern source regions into a contiguous basin, and later transverse fluvial systems delivered coarse-grained sediments from northeastern sources into a structurally partitioned basin by fold-thrust deformation. Here we integrate sedimentologic, stratigraphic, palaeomagnetic and geochronologic data from the northwestern Zagros foreland basin to define the Neogene history of deposition and sediment routing in response to progressive advance of the Zagros fold-thrust belt. This study constrains the depositional environments, timing of deposition and provenance of nonmarine clastic deposits of the Injana (Upper Fars), Mukdadiya (Lower Bakhtiari) and Bai-Hasan (Upper Bakhtiari) Formations in the Kurdistan region of Iraq. Sediments of the Injana Formation (~12.4–7.75 Ma) were transported axially (orogen-parallel) from northwest to southeast by meandering and low-sinuosity channel belt system. In contrast, during deposition of the Mukdadiya Formation (~7.75–5 Ma), sediments were delivered transversely (orogen-perpendicular) from northeast to southwest by braided and low-sinuosity channel belt system in distributive fluvial megafans. By ~5 Ma, the northwestern Zagros foreland basin became partitioned by growth of the Mountain Front Flexure and considerable gravel was introduced in localized alluvial fans derived from growing topographic highs. Foredeep accumulation rates during deposition of the Injana, Mukdadiya and Bai-Hasan Formations averaged 350, 400 and 600 m/Myr respectively, suggesting accelerated accommodation generation in a rapidly subsiding basin governed by flexural subsidence. Detrital zircon U-Pb age spectra show that in addition to sources of Mesozoic-Cenozoic cover strata, the Injana Formation was derived chiefly from Palaeozoic-Precambrian (including Carboniferous and latest Neoproterozoic) strata in an axial position to the northwest, likely from the Bitlis-Puturge Massif and broader Eastern Anatolia. In contrast, the Mukdadiya and Bai-Hasan Formations yield distinctive Palaeogene U-Pb age peaks, particularly in the southeastern sector of the study region, consistent with transverse delivery from the arc-related terranes of the Walash and Naopurdan volcano-sedimentary groups (Gaveh-Rud domain?) and Urumieh-Dokhtar magmatic arc to the northeast. These temporal and spatial variations in stratigraphic framework, depositional environments, sediment routing and compositional provenance reveal a major drainage reorganization during Neogene shortening in the Zagros fold-thrust belt. Whereas axial fluvial systems initially dominated the foreland basin during early orogenesis in the Kurdistan region of Iraq, transverse fluvial systems were subsequently established and delivered major sediment volumes to the foreland as a consequence of the abrupt deformation advance and associated topographic growth in the Zagros.  相似文献   

Petrology and oxygen isotopic compositions of clasts in HED polymict breccia NWA 5232          下载免费PDF全文

Katrina D. van Drongelen  Douglas Rumble III  Kimberly T. Tait 《Meteoritics & planetary science》2016,51(6):1184-1200

Northwest Africa (NWA) 5232, an 18.5 kg polymict eucrite, comprises eucritic and exogenic CM carbonaceous chondrite clasts within a clastic matrix. Basaltic clasts are the most abundant eucritic clast type and show a range of textures and grain size, from subophitic to granoblastic. Other eucritic clast types present include cumulate (high‐En pyroxene), pyroxene‐lath, olivine rich with symplectite intergrowths as a break‐down product of a quickly cooled Fe‐rich metastable pyroxferroite, and breccia (fragments of a previously consolidated breccia) clasts. A variable cooling rate and degree of thermal metamorphism, followed by a complex brecciation history, can be inferred for the clasts based on clast rounding, crystallization (and recrystallization) textures, pyroxene major and minor element compositions, and pyroxene exsolution. The range in δ¹⁸O of clasts and matrix of NWA 5232 reflects its origin as a breccia of mixed clasts dominated by eucritic lithologies. The oxygen isotopic compositions of the carbonaceous chondrite clasts identify them as belonging to CM group and indicate that these clasts experienced a low degree of aqueous alteration while part of their parent body. The complex evolutionary history of NWA 5232 implies that large‐scale impact excavation and mixing was an active process on the surface of the HED parent body, likely 4 Vesta.  相似文献   

Long-term monitoring of the behavior of a talus-colluvium deposit     

Ehrlich  Mauricio  da Costa  Douglas Pereira  Silva  Rafael Cerqueira 《Landslides》2021,18(6):2225-2245

Landslides - This article describes the behavior of a talus-colluvium deposit up to 70-m thick located in the Serra dos Orgaos, Rio de Janeiro/RJ, Brazil. The monitoring dataset of 13 years...  相似文献   

On the effect of bed condition on the development of tsunami-induced loading on structures using OpenFOAM   总被引：2，自引：2，他引：0  

Steven Douglas  Ioan Nistor 《Natural Hazards》2015,76(2):1335-1356

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Elastic Anisotropy of a Metamorphic Rock Sample of the Canadian Shield in Northeastern Alberta     

Judith Chan  Douglas R. Schmitt 《Rock Mechanics and Rock Engineering》2015,48(4):1369-1385

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Degradation of natural organic matter: A thermodynamic analysis     

Douglas E. LaRowe  Philippe Van Cappellen 《Geochimica et cosmochimica acta》2011,75(8):2030-16486

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The long term operation of a biologically based treatment system that removes As, S and Zn from industrial (smelter operation) landfill seepage     

Mattes AlLes J. Evans  W. Douglas GouldW.F.A. Duncan  Susan Glasauer 《Applied Geochemistry》2011,26(11):1886-1896

Passive treatment systems have a long history in the remediation of mining impacted water. The functioning of these systems is poorly understood, in particular the microbial processes that underpin metal removal. A biologically based engineered wetland treatment system that has operated in Trail, B.C. to treat seepage from a historic Pb and Zn smelter landfill, was investigated. The system has functioned for more than a decade, an unusually long life span for a passive bioreactor design. The study focuses on the 5a of operation from 2003 until 2007. Arsenic is a major contaminant in the ore that is processed in Trail, which has caused high As concentrations in the seepage. In addition to As, Zn and Cd removal were investigated. During the 5-a period, the system sequestered 2990 kg of As, 7700 kg of Zn and 85 kg of Cd. Nearly 90% of these elements were removed in two biochemical reactors (BCRs) that comprise the first two components of the six cell system, with the remainder removed in plant-based polishing cells. Average input concentrations over the 5-a period were 2.3 and 4.1 mM for As and Zn, respectively and 0.45 μM for Cd. Final output concentrations were reduced to 0.01 mM for As, 0.05 mM for Zn and 0.18 μM for Cd. Sulfur removal averaged 34% of input concentration. Analysis of mineral formation in the system using X-ray diffraction and scanning electron microscopy indicated kottigite (Zn₃(AsO₄)₂⋅8H₂O) and sphalerite (ZnS) as the major mineral phases controlling As and Zn sequestration; Cd appears to be immobilized as CdS. Evidence for orpiment was obtained from X-ray absorption spectroscopy (XANES) studies, and arsenopyrite was not detected. Although microbial activity dominates the removal of Zn, As and Cd from the soluble phase, abiotic removal mechanisms contribute including sorption of As and Zn to biosolids and filtration of metal precipitates by the solid matrix. The removal of toxic elements over the period appeared to be relatively consistent. Seasonal fluctuations, a large spike in input element concentrations over a 2-month period, and removal of the two biochemical reactors during a period of reconstruction appeared to have relatively little impact on the system as a whole.  相似文献   

Initial seismic observations from a deep borehole drilled into the Canadian Shield in northeast Alberta     

Judith Chan  Douglas R. Schmitt 《International Journal of Earth Sciences》2015,104(6):1549-1562

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Effects of local meteorology and aerosols on ozone and nitrogen dioxide retrievals from OMI and pandora spectrometers in Maryland,USA during DISCOVER-AQ 2011     

Andra J. Reed  Anne M. Thompson  Debra E. Kollonige  Douglas K. Martins  Maria A. Tzortziou  Jay R. Herman  Timothy A. Berkoff  Nader K. Abuhassan  Alexander Cede 《Journal of Atmospheric Chemistry》2015,72(3-4):455-482

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