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Concentrations of polychlorinated biphenyls (PCBs), dichlorodiphenyl trichloroethane and its metabolites (DDTs), isomers of hexachlorocyclohexane (HCHs), hexachlorobenzene (HCB), chlordane compounds (CHLs) and butyltin compounds (mono-, di- and tributyltin) were determined in biota and sediments collected from locations on the west coast of Sri Lanka. The PCB concentrations found in fish from the Kelani River mouth were higher than those from other Asian developing countries. The pattern of organochlorine accumulation was in the order of PCBs > DDTs > CHLs > HCHs > HCB, and resembled those reported for most developed countries. The accumulation pattern of butyltins in fish was in the order of TBT > DBT > MBT suggesting recent exposure to TBT sources. Total butyltin concentrations found in rabbit fish liver (11-38 micrograms/g wet wt), collected from the Colombo dockyard, could be the highest ever reported for fish in the world.  相似文献   
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The concentrations of 27 major and trace elements are determined in surface water samples collected from 48 sites of diverse waterways in four states (Tamil Nadu, Kerala, Karnataka, and Telangana) of South India. The aims of this study are to identify the element distribution, comparatively assess the pollution risk, and evaluate human health risks related to diverse waterways in the study area. The results indicate that elements such as Cr, Se, As, Fe, and Mn are the major pollutants, as their concentrations exceeded the acceptable national and international water quality standards in several sites of Ennore, Adyar, Cooum, Periyar, and Vrishabhavathi rivers. Furthermore, statistical analysis reveals that the Ennore, Adyar, Cooum, Periyar, and Kaveri river basins are affected by various anthropogenic activities, leading to moderate-to-high pollution by As, Cr, Mn, Fe, and Se. Potential pollution sources are industrial waste, sewage intrusion, paint industry waste, and automobile runoff. Overall, the investigated sites are categorized into three major groups: highly, moderately, and least polluted. Risk on human health by metals is then evaluated using hazard quotients (HQs) and carcinogenic risk evaluation; the results indicated that As with HQ >1 is the most hazardous pollutant, which could lead to non-carcinogenic and carcinogenic concerns, particularly in children. This study helps in establishing pollutant loading reduction goal and the total maximum daily loads and consequently contributes to preserving public health and developing water conservation strategies.  相似文献   
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Proper urban planning and effective implementation requires reliable urban land use statistics. In this context, satellite remote sensing data has been studied using both visual and digital techniques. A portable eight-band radiometer has been used to collect spectral signatures of surface features present in Ahmedabad city and its environs. Using these signatures a suitable approach employing visual and digital techniques has been developed for urban land use/sprawl mapping. Urban land-use maps of Ahmedabad city and its environs were prepared on 1:25,000 scale and for Ahmedabad Urban Development Authority Area on 1:50,000 scale using this methodology. It has been found that edge-enhancement techniques are useful to enhance the contrast among different urban land uses. Classification techniques such as MXL and Bayes classifiers are not successful in discriminating urban land uses. Tonal characteristics alongwith other elements of interpretation are required to classify urban land uses such as residential, industrial etc. Spatial distribution of various urban and uses and the space devoted to each urban land use has been brought out.  相似文献   
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Concentrations of PCBs and their toxic potential were examined in subcutaneous fat of eight albatross and one petrel species collected from the North Pacific and the Southern Oceans. Among all the species analyzed, high PCB levels were found in adult male blackfooted albatross from the North Pacific with the mean value of 92 microg/g wet weight. No significant gender difference in PCB accumulation was observed (P>0.1). The mean PCB levels in Southern Oceanic birds were 1 or 2 orders of magnitude lower than those from the North Pacific albatrosses. A regional-specific accumulation of non-ortho coplanar congeners were observed, most birds from the Southern Ocean had higher IUPAC 169 levels while IUPAC 126 concentrations were higher in those from the North Pacific. The estimated toxic equivalents for black-footed and Laysan albatrosses from the North Pacific were in the same range of some fish-eating birds, which were highly contaminated by PCBs. The correlation between ratio of IUPAC 169/126 concentration and total PCBs concentration indicated the possibility of induction in cytochrome P450 activities in North Pacific albatrosses (P<0.01). The calculated hazard indices indicated that black-footed and Laysan albatrosses inhabiting in the North Pacific had similar threshold levels which were known to cause toxic effects in some populations of fish-eating birds.  相似文献   
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To understand the nature of land degradation and factors responsible for it, investigations were carried out in Etah district with an area of 4.45 lakh hectares. For identification of soil/land degradation problems, multidate Landsat, TM spectral bands and FCC were used. It is observed that salt-affected soils are sharply depicted by light and dark gray mixed tone on band 3, while they are not clear on band 4. Flood plain and waterlogged soils are clearly observed on band 4. Band 6 (10.3 – 12.5 µm) helps in separation of broad zones of coarse and fine-textured soils, active flood plain of rivers, and eroded and gullied lands. The confusion between coarse-textured droughty soils and salt-affected areas in TM FCC (2, 3, 4) could be eliminated by use of band-6 data in combination with FCC. For delineation of problematic areas, two approaches were followed viz. (i) physiographic approach, and (ii) direct approach. In the physiographic approach landscape map associated with image characteristics was prepared. Further the image interpretation units were interpreted for land degradation hazards. With this approach physiography and soil relationship and the degradation problems vis-a-vis soil units could be established and ameliorative measures as per soil condition can be suggested. In direct approach, the problematic areas as per predetermined key were demarcated. Out of 4.45 lakh ha of the area, 1.99 lakh ha is affected by various soil degradation problems, like droughty soils, flooding hazard and salinity and alkalinity which cover 22.1%, 50.0% and 27.9%, respectively. To study the distribution of a salt-affected lands, major physiographic boundaries were superimposed over the land degradation map prepared by direct approach. It is observed that 81.5% of the salt-affected areas lie in the old alluvial plain while 18.5% is in recent flood plain.  相似文献   
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Profiles of nonylphenol isomers in surface waters from Sri Lanka   总被引:1,自引:0,他引:1  
Isomer-specific concentrations of nonylphenol (NP) and their predicted estrogenic potency were investigated in Sri Lankan waters for the first time. The total concentration of 13 NP isomers ranged from 90 to 1835 ng/L, while the predicted estrogenic equivalent concentration ranged from 0.072 to 1.38 ng 17β-estradiol (E2)/L. Bire Lake, located in the central area of the commercial capital, Colombo, had the highest contamination among the studied locations. These data show that NP levels in Sri Lankan waters are well within the recently reported concentrations in other regions of the world. The spatial differences in NP concentrations suggest that NP contamination in Sri Lanka may be widespread, and comprehensive study is vital.  相似文献   
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The ability to achieve meaningful decreases in sediment loads to reservoirs requires a determination of the relative importance of sediment sources within the contributing basins. In an investigation of sources of fine-grained sediment (clay and silt) within the Perry Lake Basin in northeast Kansas, representative samples of channel-bank sources, surface-soil sources (cropland and grassland), and reservoir bottom sediment were collected, chemically analyzed, and compared. The samples were sieved to isolate the 〈63μt m fraction and analyzed for selected nutrients (total nitrogen and total phosphorus), organic and total carbon, 25 trace elements, and the radionuclide cesium-137 (^137Cs). On the basis of substantial and consistent compositional differences among the source types, total nitrogen (TN), total phosphorus (TP), total organic carbon (TOC), and ^137Cs were selected for use in the estimation of sediment sources. To further account for differences in particle-size composition between the sources and the reservoir bottom sediment, constituent ratio and clay-normalization techniques were used. Computed ratios included TOC to TN, TOC to TP, and TN to TP. Constituent concentrations (TN, TP, TOC) and activities (^137Cs) were normalized by dividing by the percentage of clay. Thus, the sediment-source estimations involved the use of seven sediment-source indicators. Within the Perry Lake Basin, the consensus of the seven indicators was that both channel-bank and surface-soil sources were important in the Atchison County Lake and Banner Creek Reservoir subbasins, whereas channel-bank sources were dominant in the Mission Lake subbasin. On the sole basis of ^137Cs activity, surface-soil sources contributed the most free-grained sediment to Atchison County Lake, and channel-bank sources contributed the most fine-grained sediment to Banner Creek Reservoir and Mission Lake. Both the seven-indicator consensus and ^137Cs indicated that channelbank sources were dominant for Perry Lake and that channel-bank sources increased in importance with distance downstream in the basin.  相似文献   
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