Characteristics of normal fatty acids from sediments as a function of geologic-geochemical factors     

Iordanka Kovacheva  Georgi Kovachev 《Geochimica et cosmochimica acta》1985,49(1):299-305

Forty-nine samples from Mesozoic rocks of Northern Bulgaria and from recent marine muds of the Black Sea have been analyzed for fatty acids (FA), using extraction, treatment with ion exchange resin and gas chromatography. There is a higher concentration of normal (n) FA in the recent marine sediments, as well as in their bitumen extracts than in the rocks as a whole. There is twice as much n-FA in the rocks containing dispersed organic matter (DOM) formed mainly by benthonic organisms as compared to ancient sediments with planktonic DOM. The content of n-FA has decreased nine and five times, respectively in planktonic DOM in the sequence: limestones-marls-argillites and clayey siltstones, while the amount of organic carbon has risen four and two times. The n-FA are chiefly represented by C₁₆ and C₁₈ and in the recent sediments also by C₂₂ molecules. However when the level of maturity of DOM corresponds to the katagenetic degrees of MK₃ and MK₄, maximum is in n-FA with 19 and 20 carbon atoms. A gradual decrease in the amount of the n-FA with even-numbered carbon atoms was noted as maturity of the planktonic DOM increases from early diagenesis in recent marine sediments to the katagenetic degrees of MK₃ and MK₄ in ancient rocks. The ratios $\text{FA}\text{HC}$ and $\text{FA}\text{HC}\text{+ FA}$ have also decreased when the katagenetic maturity of DOM changes from PK₃ degree to MK₄ degree. These geochemical features may be used as an additional criterion in determining the principal phase of oil formation.  相似文献   

Geometry of the modelled freshwater/salt-water interface under variable-density-driven flow (Pétrola Lake,SE Spain)     

Sanz  D.  Valiente  N.  Dountcheva  I.  Mu&#;oz-Mart&#;n  A.  Cassiraga  E.  G&#;mez-Alday  J. J. 《Hydrogeology Journal》2022,30(3):975-988

Hydrogeology Journal - Pétrola Lake in southeast Spain is one of the most representative examples of hypersaline wetlands in southern Europe. The rich ecosystem and environmental importance of...  相似文献   

Identifying non-stationary and long-term river–aquifer interactions as a response to large climatic patterns and anthropogenic pressures using wavelet analysis (Mancha Oriental Aquifer,Spain)     

Iordanka Dountcheva  David Sanz  Eduardo Cassiraga  Vassil Galabov  Juan José Gómez-Alday 《水文研究》2020,34(25):5134-5145

The objective of this study was to analyse periodicities and the long-term variability of monthly Júcar River–Mancha Oriental Aquifer interactions (RAI) and regionally measured precipitation (PP) with special focus on the correlations between these local hydrological variables and the large climatic patterns governing the Iberian Peninsula, represented by their teleconnection indices – the North Atlantic Oscillation index (NAOi) and the Western Mediterranean Oscillation index (WeMOi). To that end, wavelet analysis has been applied since it not only provides insight into the time-series dynamics but also permits statistical interpretation and correlation analysis. As a result, several periodicities have been detected: intermittent semi-annual periodicity in PP and the NAOi and annual periodicity in the RAI, NAOi and WeMOi time series. Long cycles (approximately 14 years) are also observed in the PP and WeMOi time series. The cross-wavelet spectra show a correlation between the RAI and the rest of the variables on the semi-annual and the annual scales, while wavelet coherence detects common behaviour with longer cycles – 5–6 years between the NAOi and the RAI and cycles of both 1–5 years and 7–10 years between PP and the RAI. Furthermore, results show that the periodicities in the teleconnection indices and precipitation propagate into the RAI with certain lead times: 3 months between the RAI and PP and 6 months between the RAI and the NAOi. The results indicate that the detected periodicities and the coherence between the studied variables could have applications in strategic planning on a river basin scale, taking into account the propagation times and the frequency scale. This methodological approach can be applied into strategic water resource planning independently of the geographical location of the hydrogeological system, the basin size and the climate region.  相似文献