Drying increases organic colloidal mobilization in the karst vadose zone: Evidence from a 15-year cave-monitoring study     

Jin Liao  Chaoyong Hu  Xiuli Li  Jiaoyang Ruan 《水文研究》2021,35(4):e14163

Understanding the hydrological processes of colloids within the karst vadose zone is vital to the security of karst groundwater and providing appropriate paleohydrological explanations of colloid-facilitated metals in speleothem. This study addresses the mobilization mechanisms driving colloidal organic matter (COM) transport in the karst vadose zone using a 15-year long monthly monitoring dataset from a cave drip point (HS4) in Heshang Cave, Qingjiang Valley, China. Variations in COM concentrations were reported as the fluorescence difference values of raw and filtered (<0.22 μm) samples at an excitation wavelength of 320 nm and emission wavelength of ~400 nm. A fluorescence humification index (HIX) lower than 0.8 and an autochthonous index (BIX) higher than 1.2 indicated that the origin of COM was mainly from the karst vadose zone, rather than the soil zone. The COM concentration varied from 0.001 to 0.038 Raman Unit (RU), with evident seasonal fluctuations. Rising limbs for COM values occurred prior to rising limbs within a dripwater hydrograph; moreover, the COM peak values corresponding to the beginning of the increasing hydrograph generally suggested that the mobilization of COM reflected the movement of the air–water interface (AWI) in the karst vadose zone rather than rainfall intensity or flow velocity. COM peak values were positively correlated with the antecedent drying duration and negatively correlated with HIX values. These phenomena may be explained by the increased amount of organic matter that was aggregated and absorbed on the surface of carbonate in the karst vadose zone during a longer drying duration. Moreover, the longer drying duration was also beneficial to autochthonous biological activity, which subsequently decreased the HIX value of the organic matter in the karst vadose zone. The movement of AWI and the drying duration are both controlled by the outside weather conditions. This study is therefore conducive to evaluating the security of karst groundwater in response to climate change, and challenges prevailing paleoclimate interpretations of colloid-facilitated metal abundance timeseries reported from speleothems.  相似文献   

2020年1月19日新疆伽师MS6.4地震InSAR同震形变场特征及发震构造初步探讨     

温少妍  李成龙  李金 《内陆地震》2020,(1):1-9

基于Sentinel-1 SAR升、降影像,利用D-InSAR技术获取新疆伽师M S6.4地震的同震形变场,结果表明,本次地震引起的同震形变场整体呈近椭圆状分布,形变区东西长约66 km,南北宽约40 km,整个形变场由南部隆升区和北部沉降区组成,南部最大隆升量约7 cm,北部最大沉降量约3 cm。本次地震发生在块体俯冲界面处的低倾角逆冲推覆构造带上,隆升和沉降两个中心均位于逆冲推覆体的上盘,形变主要以隆升形变为主,符合低倾角逆断层中强震的变形特征。在沉降区与隆升区之间干涉条纹连续分布,未出现表征地表破裂位置的空间失相关带,表明地震未引起明显的地表破裂。结合震源机制、余震精定位及区域构造特征,初步推断认为伽师地震的发震构造可能为柯坪塔格推覆构造前缘的N倾的柯坪断裂。  相似文献   

南海北部西沙海槽沉积物管状黄铁矿特征及其形成机理^*          下载免费PDF全文

石思思  吴朝东  梁金强  王熠哲  叶云涛  方允鑫  马健  翟俪娜 《古地理学报》2020,22(1):175-192

南海北部西沙海槽S1站位的岩心柱沉积物中广泛发育自生矿物黄铁矿,其形态以管状为主,且具有内部中空的圈层结构。使用扫描电镜、电子探针、LA-ICP-MS、SIMS等测试方法研究了管状黄铁矿的形态及圈层结构,结果显示: (1)管状黄铁矿发育内部中空的圈层结构,其中内圈层(I_py)由莓球状黄铁矿呈五角十二面体紧密堆积组成,外圈层(O_py)由晶形较好晶粒较大的八面体黄铁矿组成,并混有沉积碎屑及钙质生物壳体;(2)内圈层和外圈层分别呈现出贫S富Fe和富S贫Fe的特征,其成因是甲烷渗漏造成的局部还原环境使得As进入黄铁矿中导致晶格空缺或被扭曲,从而促进Ni、Co、Cu、Zn、Pb等微量元素的掺入;(3)内圈层、外圈层发生了明显的硫同位素分馏现象,内圈层中 δ³⁴S 平均为-37.8‰,外圈层中 δ³⁴S 平均为-29.3‰。研究认为,管状黄铁矿作为曾经甲烷渗漏的通道,其生长机制可分为3个阶段: (1)气水通道形成阶段: 向上运移的甲烷流体在沉积物孔隙中逐渐形成气水通道;(2)外圈层形成阶段: 当向上运移的甲烷与硫酸盐发生甲烷厌氧氧化时,逐渐形成晶体较大、晶形较好的八面体黄铁矿外圈层;(3)内圈层形成阶段: 随着甲烷浓度逐渐降低,在气水通道中的微生物作用下,剩余甲烷与向下运移的硫酸盐继续反应形成莓球状黄铁矿内圈层。因此,南海北部的泥岩中大量发育的管状黄铁矿常常与地层中甲烷水合物的存在有关。  相似文献   

Orbital control on cyclical organic matter accumulation in Early Silurian Longmaxi Formation shales     

Siding Jin  Hucheng Deng  Xing Zhu  Yan Liu  Sibing Liu  Meiyan Fu 《地学前缘(英文版)》2020,(2):533-545

High resolution(939 samples)total organic carbon content(TOC)analyses were conducted on the Shuanghe Section of^152.6 m in the Changning area,Sichuan Basin.The sampling section was divided into two units considering the distinct-different deposit environment and sediments accumulation rate.The lower part(Unit 1)and the peer part(Unit 2)with high resolution sample spacing(0.08–0.4 m)enables the identification of the precession cycle in two sedimentary sequences with distinct different sedimentary accumulation rate.MTM Power spectral analyses on untuned TOC series reveals significant peaks exceeding above the 95%confidence level and shows that both Unit 1 and Unit 2 have recorded Milankovitch cycles of 405 kyr long eccentricity,short eccentricity,obliquity and precession.The floating astronomical time scale(ATS)was constructed on the Shuanghe Section in the Early Silurian(~439.673–444.681 Ma),and which was calibrated by 405 kyr long eccentricity cycles.The total duration of the Wufeng and Longmaxi shales is 5.01 Myr.The floating ATS used for estimating the duration of the graptolite zones and each stage in the study interval.Finally,we postulated two models that could verify the linkage between orbital cycle and organic accumulation.To make sure whether productivity or preservation is the main factor that under long eccentricity control,the phase correlation between the obtained filtered signal and the theoretical orbital solution should be made clear in the further research.  相似文献   

2007-2017年中国沙尘气溶胶的三维分布特征及输送过程     

贾瑞  刘玉芝  吴楚樵  祝清哲  汪兵 《中国沙漠》2019,39(6):108-117

利用最新发布的CALIPSO产品，构建了2007-2017年中国沙尘气溶胶的三维分布，并结合HYSPLIT-4模式和再分析数据，探讨了沙尘的三维输送过程。结果表明：中国的沙尘排放源区主要是塔克拉玛干沙漠和巴丹吉林沙漠，沙尘气溶胶出现频率分别为60%和35%。塔克拉玛干沙漠排放的沙尘主要（50%~70%）停留在源地0~6 000 m高度，少部分向东输送至甘肃和内蒙古；巴丹吉林沙漠排放的沙尘则主要向东输送。中国沙尘排放量在春季最大，向东输送最强；夏季，东亚夏季风限制了沙尘向东输送；秋季，沙尘排放减弱，输送强度和夏季相当；沙尘排放量在冬季最小，输送最弱。夏季，沙尘在输送过程中可被抬升至高度5 000 m以上，春季次之，秋、冬季的沙尘主要在低层大气输送。沙尘在向东输送的过程中被抬升并和当地人为污染物混合变为污染性沙尘，华北地区污染性沙尘出现频率高达30%；输送到海洋的沙尘也会与洋面上（0~3 000 m高度）的海盐气溶胶混合，出现频率约为10%。  相似文献   

CG-6型重力仪零漂特性研究     

郝洪涛  刘少明  韦进  胡敏章 《大地测量与地球动力学》2019,39(10):1086-1090

对中国地震局地震研究所最新引进的4台CG-6型相对重力仪的零漂特性进行测试研究，结果表明，4台重力仪的静态零漂率、混合零漂率和动态零漂率均小于8 μGal/h，满足厂家给出的技术指标。在较长观测时间内，各台仪器的零漂均存在不同程度的非线性特征，因此在进行较长时间的野外观测以及后续数据处理中，不宜将零漂率作为常数进行解算和零漂改正。  相似文献   

琼东南盆地华光凹陷天然气水合物稳定带厚度的影响因素     

刘杰  杨睿  邬黛黛  金光荣  张辉 《海洋学报》2019,41(8):13-25

为了探讨琼东南盆地华光凹陷海底天然气水合物稳定带的分布规律，定量研究了静水压力、底水温度、地温梯度和气源组分对水合物稳定带的影响程度。在此基础上，分析了华光凹陷现今甲烷水合物稳定带的厚度分布。最后，综合各因素的历史演化过程，初步探讨了华光凹陷1.05 Ma BP以来天然气水合物稳定带的演化。结果表明:(1)气源组分和海底温度的变化对研究区内水合物稳定带的影响较大；水合物稳定带厚度与海底温度呈良好的线性负相关性。(2)水深超过600 m的海域具备形成天然气水合物的温压条件；超过600 m水深的海域水合物稳定带厚度大部分超过 100 m，其中西北部稳定带的最大厚度超过300 m，是有利的水合物勘探区。(3)华光凹陷1.05 Ma BP以来天然气水合物稳定带厚度经历了快速增厚–窄幅变化–快速减薄和恢复的过程。麻坑群与水合物稳定变化敏感区在空间上具有较好的叠合关系。结合前人的研究成果，推测其形成与天然气水合物的分解释放有关。  相似文献   

Effect of spatially variable saturated hydraulic conductivity with non-stationary characteristics on the stability of reservoir landslides     

Xue  Yang  Wu  Yiping  Miao  Fasheng  Li  Linwei  Liao  Kang  Ou  Guangzhao 《Stochastic Environmental Research and Risk Assessment (SERRA)》2020,34(2):311-329

Stochastic Environmental Research and Risk Assessment - Conventional landslide analyses, based on deterministic methods or simple random variable methods, cannot consider the spatial variability...  相似文献   

Mantle transition zone structure beneath the Central Asian Orogenic Belt     

Jing HE  Qingju WU 《中国科学:地球科学(英文版)》2020,63(4):548-560

Over the past decades, there have been hot debates in the geodynamic community regarding to the deep evolution mechanisms of Cenozoic volcanism in the Central Asian Orogenic Belt(CAOB). Of all the constraints available, high resolution structure of upper mantle discontinuities, especially the discontinuities at depths of 410 km(D410) and 660 km(D660), is of the most important, which may provide reliable clues on the magma channel as well as its evolution. In this work, we adopt the common conversion point stacking technique with teleseismic radial P-wave receiver functions to examine the D410 and D660 discontinuities. The primary results exhibit that the major characteristics of the mantle transition zone(MTZ) obtained by different velocity models are largely consistent. Obviously elevated D410 and slightly depressed D660 are observed beneath the Hannuoba Volcano, suggesting possible delamination of the local lithosphere deposited at the D410. This process may induce upwelling of the asthenospheric materials filling the space left by the delaminated lithosphere, and subsequently trigger volcanic eruptions. Strong depressions are observed at both D410 and D660 depths beneath west of the Dariganga Volcano, and the depression of D660 is more pronounced. It leads to the apparently thickened MTZ, indicating the presence of cold material at the D660. This cold material is speculated as a stagnant slab from the subducted Pacific Plate or the remains of a detached island arc system from the collision and formation of the CAOB. Slightly thinner MTZ is found beneath the Hentey Mountains and the Middle Gobi Volcano. Apparently, this thinner MTZ is not significant enough to support the existence of high thermal anomalies,which may rule out the possibility of large-scale hot material upwelling from either the local MTZ or even the lower mantle.  相似文献   

Metallogenesis and major challenges of porphyry copper systems above subduction zones   总被引：1，自引：0，他引：1  

Chen  Huayong  Wu  Chao 《中国科学:地球科学(英文版)》2020,63(7):899-918

Porphyry copper±molybdenum±gold deposits(PCDs) are the most representative magmatic-hydrothermal metallogenic system above subduction zones with important economic value. Previous studies revealed that large PCDs are generally formed from initial arc magmas(from subduction-induced partial melting of the mantle wedge), which eventually ascend to the shallow crust(3–5 km) for mineralization after a series of complex evolution processes. These processes include(1) the dehydration or partial melting of subducting slab, which induces partial melting of the metasomatized mantle wedge;(2)the ascent of mantle-derived magma to the bottom of the lower crust, which subsequently undergoes crustal processes such as assimilation plus fractional crystallization(AFC) or melting, assimilation, storage and homogenization(MASH);(3) the magma chamber formation at the bottom of the lower, middle and upper crust;(4) the final emplacement and volatilization of porphyry stocks; and(5) the accumulation of ore-forming fluids and metal precipitation. Despite the many decades of research, many issues involving the PCD metallogenic mechanism still remain to resolve, such as(1) the tectonic control on the geochemical characteristics of ore-forming magma;(2) the reason for the different lifespans of the long-term magmatic arc evolution and geologically "instantaneous" mineralization processes;(3) the source of ore-forming materials;(4) the relative contributions of metal pre-enrichment to mineralization by the magma source and by magmatic evolution; and(5) the decoupling behaviors of Cu and Au during the pre-enrichment. These issues point out the direction for future PCD metallogenic research, and the resolution to them will deepen our understanding of the metallogenesis at convergent plate boundaries.  相似文献