Toxicity studies of elemental sulfur in marine sediments     

Monika Cieszynska-Semenowicz  Justyna Rogowska  Wojciech Ratajczyk  Joanna Ratajczyk  Lidia Wolska 《国际泥沙研究》2018,33(2):191-197

Elemental sulfur(ES) is a component essential for proper development of animals, but it can be toxic for aquatic organisms. The objectives of the study reported here included determination of ES concentrations in sediment collected in the area of the Gulf of Gdansk(Baltic Sea) and search for the possible correlations with the ecotoxicity results. Sediment samples were collected from four locations: the Vistula River mouth, in the Port Basin, in the area of discharge of the treated wastewater from the Wastewater Treatment Plant(WWTP) and in the area of the sunken World War Ⅱ s/s 'Stuttgart' shipwreck. The levels of elemental sulfur were determined using a gas chromatograph coupled with a mass spectrometer(GC-MS). Toxicity of marine sediment samples was estimated for three biotest organisms-bioluminescent bacteria Vibrio fischeri, crustacean Heterocypris incongruens, and Synapis alba plant. The highest toxicity of sediments for all indicator organisms was observed in samples taken at the place of the shipwreck(2-100%). The same samples had a high sulfur content(16.7-143.2 μg/g dry weight(d.w.))therefore, it was decided to investigate whether the presence of ES in the sediment in the studied area can have an impact on the results of the ecotoxicity determination in real samples. However, the removal of sulfur from the samples resulted in no significant changes in the level of toxicity of the samples. In this research it could not be confirmed that the presence of elemental sulfur is the only factor responsible for the observed sediment toxicity. It seems that other compounds or their mixtures present in the sediment may have a significant influence on the results obtained.  相似文献   

A SIMS zircon age for a biostratigraphically dated Upper Viséan (Asbian) bentonite in the Central-European Variscides (Bardo Unit,Polish Sudetes)   总被引：1，自引：1，他引：0  

Ryszard Kryza  Jolanta Muszer  Joanna Haydukiewicz  Czesław August  Marta Jurasik  Nickolay Rodionov 《International Journal of Earth Sciences》2011,100(6):1227-1235

A Lower Carboniferous platform sedimentary sequence (the Paprotnia Beds) in the Bardo Unit of the central Sudetes (NE part of the Bohemian Massif, SW Poland) is biostratigraphically well dated, based on rich macro- and micro-fossil evidence, as Late Viséan (late Asbian, crenistria, Go III α zone). The beds contain several bentonite layers, one of which was dated using the U–Pb SHRIMP method on volcanic zircons and yielded an age of 334 ± 3 Ma. This date fits well to the recently established chronostratigraphic limits of the Viséan, and is consistent with the newest isotopic age constraints of 336.5–332 Ma for the Asbian boundaries.  相似文献   

Multi‐Criteria Analysis for Optimization of Sodium Chromate Production from Chromic Waste     

Agnieszka Generowicz  Zygmunt Kowalski  Joanna Kulczycka  Agnieszka Makara 《洁净——土壤、空气、水》2011,39(7):688-696

The proposal of application of multi‐criteria analysis and technological quality method for optimization of technological processes on the case study of sodium chromate production variants from waste was presented. The research on the use of chromic waste for the production of sodium chromate made it possible to determine the optimal process parameters. Technological quality method was used to define the value of criterions for multi‐criteria analysis while multi‐criteria analysis allowed determining the impact of criterions weights for ranking variants of technological process. Both methods in a complex way evaluate the degree of modernization of technologies, describing them qualitatively within the area of environmental, technical, and the economic effects of the proposed technological variants. Based on the proposed evaluating criteria both methods yield comparable results. The most advantageous alternatives provided realization of the sodium chromate production process with the use of in‐process recycling of chromic mud, off‐site recycling of chromic tannery waste and on‐site recycling of waste from the old chromic heaps.  相似文献   

Characterizing and classifying urban watersheds with compositional and structural attributes     

Joseph M. Delesantro  Jonathan M. Duncan  Diego Riveros-Iregui  Joanna R. Blaszczak  Emily S. Bernhardt  Dean L. Urban  Lawrence E. Band 《水文研究》2021,35(9):e14339

Current land-use classifications used to assess urbanization effects on stream water quality date back to the 1980s when limited information was available to characterize watershed attributes that mediate non-point source pollution. With high resolution remote sensing and widely used GIS tools, there has been a vast increase in the availability and precision of geospatial data of built environments. In this study, we leverage geospatial data to expand the characterization of developed landscapes and create a typology that allows us to better understand the impact of complex developed landscapes across the rural to urban gradient. We assess the ability of the developed landscape typology to reveal patterns in stream water chemistry previously undetected by traditional land-cover based classification. We examine the distribution of land-cover, infrastructure, topography and geology across 3876 National Hydrography Dataset Plus catchments in the Piedmont region of North Carolina, USA. From this dataset, we generate metrics to evaluate the abundance, density and position of landscape features relative to streams, catchment outlets and topographic wetness metrics. While impervious surfaces are a key distinguishing feature of the urban landscape, sanitary infrastructure, population density and geology are better predictors of baseflow stream water chemistry. Unsupervised clustering was used to generate a distinct developed landscape typology based on the expanded, high-resolution landscape feature information. Using stream chemistry data from 37 developed headwater catchments, we compared the baseflow water chemistry grouped by traditional land-cover based classes of urbanization (rural, low, medium and high density) to our composition and structure-based classification (a nine-class typology). The typology based on 22 metrics of developed landscape composition and structure explained over 50% of the variation in NO₃⁻-N, TDN, DOC, Cl⁻, and Br⁻ concentration, while the ISC-based classification only significantly explained 23% of the variation in TDN. These results demonstrate the importance of infrastructure, population and geology in defining developed landscapes and improving discrete classes for water management.  相似文献   

Exoplanet atmospheres with EChO: spectral retrievals using EChOSim     

Joanna K. Barstow  Neil E. Bowles  Suzanne Aigrain  Leigh N. Fletcher  Patrick G. J. Irwin  Ryan Varley  Enzo Pascale 《Experimental Astronomy》2015,40(2-3):545-561

We demonstrate the effectiveness of the Exoplanet Characterisation Observatory mission concept for constraining the atmospheric properties of hot and warm gas giants and super Earths. Synthetic primary and secondary transit spectra for a range of planets are passed through EChOSim [13] to obtain the expected level of noise for different observational scenarios; these are then used as inputs for the NEMESIS atmospheric retrieval code and the retrieved atmospheric properties (temperature structure, composition and cloud properties) compared with the known input values, following the method of [1]. To correctly retrieve the temperature structure and composition of the atmosphere to within 2 σ, we find that we require: a single transit or eclipse of a hot Jupiter orbiting a sun-like (G2) star at 35 pc to constrain the terminator and dayside atmospheres; 20 transits or eclipses of a warm Jupiter orbiting a similar star; 10 transits/eclipses of a hot Neptune orbiting an M dwarf at 6 pc; and 30 transits or eclipses of a GJ1214b-like planet.  相似文献   

The South East Regional Marine Plan: Implementing Australia's Oceans Policy     

Joanna Vince 《Marine Policy》2006

In 1998, the Australian Government released Australia's Oceans Policy (AOP), a world first policy initiative focused on providing a framework for integrated ecosystem-based management of Australia's vast marine domain. The South East Regional Marine Plan, the first regional marine plan to be implemented under AOP, was released on 21 May 2004. This paper argues that although full integration across sectors and jurisdictions has not occurred, new AOP initiatives, institutions and governance processes have considerably increased sectoral and jurisdictional coordination in the South East region.  相似文献   

Characterization of chromophoric dissolved organic matter (CDOM) in the Baltic Sea by excitation emission matrix fluorescence spectroscopy   总被引：11，自引：0，他引：11  

Piotr Kowalczuk  Joanna Sto&#x;-Egiert  William J. Cooper  Robert F. Whitehead  Michael J. Durako 《Marine Chemistry》2005,96(3-4):273-292

Chromophoric dissolved organic matter (CDOM) is the major light absorber in the Baltic Sea. In this study, excitation emission matrix (EEM) fluorescence spectra and UV–visible absorption spectra of CDOM are reported as a function of salinity. Samples from different locations and over different seasons were collected during four cruises in 2002 and 2003 in the Baltic Sea in both Pomeranian Bay and the Gulf of Gdansk. Absorption by CDOM decreased with increased distance from the riverine source and reached a relatively stable absorption background in the open sea. Regression analysis showed that fluorescence intensity was linearly related to absorption by CDOM at 375 nm and a_CDOM(375) absorption coefficients were inversely related to salinity. Analysis of CDOM-EEM spectra indicated that a change in composition of CDOM occurred along the salinity gradient in the Baltic Sea. Analysis of percent contribution of respective fluorophore groups to the total intensity of EEM spectra indicated that the fluorescence peaks associated with terrestrial humic components of the CDOM and total integrated fluorescence decreased with decreasing CDOM absorption. In contrast, the protein-like fraction of CDOM decreased to a lesser degree than the others. Analysis of the percent contribution of fluorescence peak intensities to the total fluorescence along the salinity gradient showed that the contribution of protein-like fluorophores increased from 2.6% to 5.1% in the high-salinity region of the transect. Fluorescence and absorption changes observed in the Baltic Sea were similar to those observed in similar transects that have been sampled elsewhere, e.g. in European estuaries, Gulf of Mexico, Mid-Atlantic Bight and the Cape Fear River plume in the South Atlantic Bight, although the changes in the Baltic Sea occurred over a much smaller salinity gradient.  相似文献   

Meiobenthic Organisms as Indicators of Mixing Processes in the Baltic Surface Sediments*     

Janusz Pempkowiak  Joanna Kozuch  Maria Szymelfenig 《Marine Ecology》1996,17(1-3):175-179

Abstract. Two sediment cores were collected in the southern Baltic Sea and sliced into 1.0cm-thick layers. Sediments of each layer were analysed for activities of ²¹⁰Pb, ¹³⁷Cs, ¹³⁴Cs and for the density of meiobenthic organisms (meiofauna). Zones with the rapid mixing occur in the uppermost layers (0–3 cm) of the cores based on ^I34Cs profiles. The extent and density of meiofauna confirmed the rapid mixing and revealed layers with slow mixing (4–8 cm). Sedimentation rates were derived from ²¹⁰Pb profiles below the mixing zones (1.21 and 1.72 mm a-^I) and were confumed by ¹³⁷Cs distribution. Of twenty-one major meiofauna taxa commonly found in the Baltic sediments, three were present in the cores.  相似文献   

Impact of the azores front propagation on deep ocean particle flux     

Birte Fründt  Joanna J. Waniek 《Central European Journal of Geosciences》2012,4(4):531-544

The Azores Current originating as a branch of the Gulf Stream is a highly dynamic system in the subtropical North Atlantic. The associated front forms the northeastern boundary of the North Atlantic Subtropical Gyre. In this study we analyzed 42 years of assimilated modeled temperature fields to localize the position of the Azores Front at 22°W and observed a fast north- and southward propagation between 30°N and 37°N on monthly to decadal time scales. The North Atlantic Oscillation with correlated changes of the wind direction was identified as one driving mechanism. As the front is acting as a guide for Rossby waves, the signal of the front??s propagation is transferred to the western Atlantic and, among other atmospheric forcing mechanisms, induces a shifting of the Northern Wall of the Gulf Stream with one year delay. Shallower mixed layer depths in the northern frontal region of the Azores Current caused by the rise of the isotherms lead to nutrient supply and primary production different from those found in the southern frontal region of the current system. A high interannual variability is manifested in deep ocean particle flux, derived from a sediment trap in 2000 m water depth at the mooring site KIEL276 (33°N, 22°W) from 1993 to 2008, which is directly related to the phytoplankton bloom in the euphotic zone. This variability is explained by the propagation of the front and strong variations in the catchment areas of the sediment trap due to the associated eddy activity in the frontal region.  相似文献   

Tidal pattern instabilities on multi-moon planets     

Joanna Furno 《Icarus》2007,189(1):246-255

The equilibrium tide-generating forces in the lunar orbital plane of a planet of radius R are calculated for the case of N moons of mass Mi orbiting the planet at instantaneous polar coordinates (Di, αi). For the case of a single moon, there are only two high tides. For the case of two moons, it is found that there can exist a critical lunar orbital distance at which two high tides become unstable with respect to formation of three high tides. Bifurcation diagrams are presented which depict how the angular positions of the high and low tides on the planet vary with the lunar distances and lunar separation angle. Tidal stability diagrams, which illustrate the stability regions for various tidal patterns as a function of lunar distances and lunar separation angle, are presented for various values of D₂/D₁ and M₂/M₁. Generally speaking, the aforementioned tidal instability, and hence the propensity for formation of three high tides on a two-moon planet, exists over a significant range of lunar distances and separation angles provided that M₂/M₁∼³(D₂/D₁). For the case of N>2 moons, the tidal stability diagram becomes more complex, revealing a diversity of potential tidal patterns.  相似文献