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1.
Natural Resources Research - Geological contacts in lateritic metal deposits (footwall topographies) often delineate the orebody boundaries. Spatial variations seen in such contacts are frequently...  相似文献   
2.
The 176Lu–176Hf and 147Sm–143Nd decay systems are routinely used to determine garnet (Grt)–whole-rock (WR) ages; however, the 176Lu–176Hf age of garnet is typically older than the 147Sm–143Nd age determined from the same aliquots. Here we present experimental data for Lu3+ and Hf4+ diffusion in garnet as functions of temperature, pressure and oxygen fugacity and show that the diffusivity of Hf4+ in almandine/spessartine garnet is significantly slower than that of Lu3+. The diffusive closure temperature (T C) of Hf4+ is significantly higher than that of Nd3+, and although this property is partly responsible for the observed 176Lu–176Hf and 147Sm–143Nd Grt–WR age discrepancies, the difference between the T C-s of Lu3+ and Hf4+ could lead to apparent Grt–WR 176Lu–176Hf ages that are skewed from the age of Hf4+ closure in garnet. In addition, the slow diffusivity of Hf4+ indicates that the bulk of metamorphic garnets retain a substantial fraction of prograde radiogenic 176Hf throughout peak metamorphic conditions, a phenomenon that further complicates the interpretation of 176Lu–176Hf garnet ages and invalidates the use of analytical T C expressions. We argue that the diffusion of trivalent rare earth elements in garnet becomes much faster when their concentration level falls below a few hundred ppm, as in the experiments of Tirone et al. (Geochim Cosmochim Acta 69: 2385–2398, 2005), and further argue that this low-concentration mechanism is appropriate for modeling the susceptibility of 147Sm–143Nd garnet ages to diffusive resetting.  相似文献   
3.
Proterozoic basement-hosted unconformity-related uranium deposits of the Athabasca Basin (Saskatchewan, Canada) were affected by significant uranium redistribution along oxidation–reduction redox fronts related to cold and late meteoric fluid infiltration. These redox fronts exhibit the same mineralogical and geochemical features as the well-studied uranium roll-front deposits in siliclastic rocks. The primary hydrothermal uranium mineralisation (1.6–1.3 Ga) of basement-hosted deposits is strongly reworked to new disseminated ores comprising three distinctly coloured zones: a white-green zone corresponding to the previous clay-rich alteration halo contemporaneous with hydrothermal ores, a uranium front corresponding to the uranium deposition zone of the redox front (brownish zone, rich in goethite) and a hematite-rich red zone marking the front progression. The three zones directly reflect the mineralogical zonation related to uranium oxides (pitchblende), sulphides, iron minerals (hematite and goethite) and alumino-phosphate-sulphate (APS) minerals. The zoning can be explained by processes of dissolution–precipitation along a redox interface and was produced by the infiltration of cold (<50°C) meteoric fluids to the hydrothermally altered areas. U, Fe, Ca, Pb, S, REE, V, Y, W, Mo and Se were the main mobile elements in this process, and their distribution within the three zones was, for most of them, directly dependent on their redox potential. The elements concentrated in the redox fronts were sourced by the alteration of previously crystallised hydrothermal minerals, such as uranium oxides and light rare earth element (LREE)-rich APS. The uranium oxides from the redox front are characterised by LREE-enriched patterns, which differ from those of unconformity-related ores and clearly demonstrate their distinct conditions of formation. Uranium redox front formation is thought to be linked to fluid circulation episodes initiated during the 400–300 Ma period during uplift and erosion of the Athabasca Basin when it was near the Equator and to have been still active during the last million years. A major kaolinisation event was caused by changes in the fluid circulation regime, reworking the primary uranium redox fronts and causing the redistribution of elements originally concentrated in the uranium-enriched meteoric-related redox fronts.  相似文献   
4.
We show here that the Amalaoulaou complex, in the Pan-African belt of West Africa (Gourma, Mali), corresponds to the lower and middle sections of a Neoproterozoic intra-oceanic arc. This complex records a 90–130-Ma-long evolution of magmatic inputs and differentiation above a subducting oceanic slab. Early c. 793 Ma-old metagabbros crystallised at lower crustal or uppermost mantle depths (25–30 km) and have geochemical characteristic of high-alumina basalts extracted from a depleted mantle source slightly enriched by slab-derived sedimentary components ((La/Sm)N < 1; εNd: +5.4–6.2; 87Sr/86Sr: 0.7027–0.7029). In response to crustal thickening, these mafic rocks were recrystallised into garnet-granulites (850–1,000°C; 10–12 kbar) and subject to local dehydration–melting reactions, forming trondhjemititic leucosomes with garnet–clinopyroxene–rutile residues. Slightly after the granulitic event, the arc root was subject to strong HT shearing during partial exhumation (detachment faults/rifting or thrusting), coeval with the emplacement of spinel- and garnet-pyroxenite dykes crystallised from a high-Mg andesitic parental magma. Quartz and hornblende-gabbros (700–660 Ma) with composition typical of hydrous volcanic rocks from mature arcs ((La/Sm)N: 0.9–1.8; εNd: +4.6 to +5.2; 87Sr/86Sr: 0.7028–0.7031) were subsequently emplaced at mid-arc crust levels (~15 km). Trace element and isotopic data indicate that magmas tapped a depleted mantle source significantly more enriched in oceanic sedimentary components (0.2%). Exhumation occurred either in two stages (700–660 and 623 Ma) or in one stage (623 Ma) with a final exhumation of the arc root along cold P-T path (550°C, 6–9 kbar; epidote–amphibolite and greenschist facies conditions) during the main Pan-African collision event (620–580 Ma). The composition of magmas forming the Cryogenian Amalaoulaou arc and the processes leading to intra-arc differentiation are strikingly comparable to those observed in the deep section of exposed Mezosoic oceanic arcs, namely the Kohistan and Talkeetna complex. This evolution of the Amalaoulaou oceanic arc and its accretion towards the West African craton belong to the life and closure of the Pharusian Ocean that eventually led to the formation of the Greater Gondwana supercontinent, a similar story having occurred on the other side of the Sahara with the Mozambique Ocean.  相似文献   
5.
6.
This study aims at presenting various methodologies to separate the reproducible and irreproducible components of seasonal and intraseasonal climate variability simulated by a regional climate model over Southern Africa (south of 15°S), during an austral summer rainy season representative of the climatology. To that end, a 30-member ensemble simulation is performed using WRF laterally forced by the ERA40 reanalyses. Retained metrics include the analysis of weather regimes, signal-to-noise ratio, inter-member standard deviation and coefficient of variation. At the seasonal timescale, simulated rainfall amounts generally show a strong reproducibility, except in the subtropics and over the southern part of the Mozambique Channel. There, the number of rainy days is roughly similar in all members, while their average intensity varies extensively. At the intraseasonal timescale, the chronology of weather regimes, derived from the 500?hPa geopotential height, is highly reproducible. Rainfall variability is much less reproducible, especially in the central parts of the domain and near its outflow boundaries. Analysis of a South African regional index nonetheless indicates that both wet and dry spells tend to be accurately simulated and occur in phase in most members, demonstrating that they are embedded in large-scale variability patterns. Internal variability is lastly related to the lateral forcings along the domain boundaries. An objective classification of inflow/outflow mass fluxes allows identification of the recurrent synoptic configurations that favor strong or weak regional reproducibility. The main uncertainties concern the basic morphological features of rain-bearing systems (i.e., their spatial extension, location and propagation speed). Consequences for tropical-temperate interactions are then discussed.  相似文献   
7.
This paper presents a thermo‐hydro‐mechanical framework to model the drying behavior of Boom clay. First, the experimental campaign conducted Noémie Prime is briefly presented because it is used to validate the model. The data acquisition and processing is emphasized because of the use of X‐ray microtomography to be able to more accurately compare experimental and numerical strain fields. The different submodels are introduced. Numerical simulations are performed to illustrate the capability of the proposed model to reproduce the observed behavior. Finally, a comprehensive sensitivity study on several key model parameters associated with the water retention curve, and the permeability of the medium, is performed to get a better understanding of the physics behind the coupled model.  相似文献   
8.
We explored the submarine portions of the Enriquillo–Plantain Garden Fault zone (EPGFZ) and the Septentrional–Oriente Fault zone (SOFZ) along the Northern Caribbean plate boundary using high‐resolution multibeam echo‐sounding and shallow seismic reflection. The bathymetric data shed light on poorly documented or previously unknown submarine fault zones running over 200 km between Haiti and Jamaica (EPGFZ) and 300 km between the Dominican Republic and Cuba (SOFZ). The primary plate‐boundary structures are a series of strike‐slip fault segments associated with pressure ridges, restraining bends, step overs and dogleg offsets indicating very active tectonics. Several distinct segments 50–100 km long cut across pre‐existing structures inherited from former tectonic regimes or bypass recent morphologies formed under the current strike‐slip regime. Along the most recent trace of the SOFZ, we measured a strike‐slip offset of 16.5 km, which indicates steady activity for the past ~1.8 Ma if its current GPS‐derived motion of 9.8 ± 2 mm a?1 has remained stable during the entire Quaternary.  相似文献   
9.
Palynological and geochemical analyses provide valuable information about modern and past climatic regimes and vegetation. The impact of climate and humans on past vegetation in the semi-arid areas of northwestern Iran has received increased interest in the wake of warming temperatures in the Middle East. Palynological and down-core XRF elemental abundances from a peat core from Lake Neor enabled a reconstruction of vegetational changes of the past 7000 years over the highlands of northwestern Iran. Periods of increased arboreal pollen (AP) types and high (Artemisia + Poaceae)/Chenopodiaceae ratios along with low titanium abundances, high percentages of total organic carbon, more negative δD values, and higher carbon accumulation rates suggest a relatively wet climate. These conditions have persisted during the periods 6700–6200, 5200–4450 and 3200–2200 cal a bp. The overall low AP values, substantial rise of Chenopodiaceae, high Ti abundances and low values of palaeo-redox proxies, are all evidences of a drier climate, as has been reconstructed for the periods 6200–5200 and 4030–3150 cal a bp and the last 2200 years. An important feature of the last centuries is the increase of anthropogenic and pastoral indicator pollen types. Our results may provide basic data to predict future trends in vegetation dynamics under future climate change in western Asia.  相似文献   
10.
Finnish Lapland is known as an area where numerous sites with sediments from Pleistocene glacial and interglacial periods occur. Recent sedimentological observations and dating call for reinterpretation of the record, which shows a complicated Mid‐Weichselian ice‐sheet evolution within the ice‐divide zone. Here, a large, previously unstudied section from a former Hannukainen iron mine was investigated sedimentologically and dated with optically stimulated luminescence (OSL). Ten sedimentary units were identified displaying a variety of depositional environments (glacial, glaciolacustrine, fluvial and aeolian). They are all – except for the lowermost, deeply weathered till – interpreted to be of Mid‐ or Late Weichselian/Holocene age. Five OSL samples from fluvial sediments give ages ranging from 55 to 35 ka, indicating two MIS 3 ice‐free intervals of unknown duration. The Mid‐Weichselian interstadial was interrupted by a re‐advance event, which occurred later than 35 ka and caused glaciotectonic deformation, folding and stacking of older sediments. This new evidence emphasizes the importance of the Kolari area when unravelling the complex Late Pleistocene glacial history of northern Finland and adjacent regions.  相似文献   
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