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The unique occurrence of abundant (~1 vol%) near‐pure‐Fe metal in the Camel Donga eucrite is more complicated than previously believed. In addition to that component of groundmass metal, scattered within the meteorite are discrete nodules of much higher kamacite abundance. We have studied the petrology and composition of two of these nodules in the form of samples we call CD2 and CD3. The nodules are ovoids 11 (CD2) to 15 (CD3) mm across, with metal, or inferred preweathering metal, abundances of 12–17 vol% (CD2 is unfortunately quite weathered). The CD3 nodule also includes at its center a 5 mm ovoid clumping (6 vol%) of F‐apatite. Both nodules are fine‐grained, so the high Fe metal and apatite contents are clearly not flukes of inadequate sampling. The metals within the nodules are distinctly Ni‐rich (0.3–0.6 wt%) compared to the pure‐Fe (Ni generally 0.01 wt%) groundmass metals. Bulk analyses of three pieces of the CD2 nodule show that trace siderophile elements Ir, Os, and Co are commensurately enriched; Au is enriched to a lesser degree. The siderophile evidence shows the nodules did not form by in situ reduction of pyroxene FeO. Moreover, the nodules do not show features such as silica‐phase enrichment or pyroxene with reduced FeO (as constrained by FeO/MgO and especially FeO/MnO) predicted by the in situ reduction model. The oxide minerals, even in groundmass samples well away from the nodules, also show little evidence of reduction. Although the nodule boundaries are generally sharp, groundmass‐metal Ni content is anti‐correlated with distance from the CD3 nodule. We infer that the nodules represent materials that originated within impactors into the Camel Donga portion of the eucrite crust, but probably were profoundly altered during later metamorphism/metasomatism. Origin of the pure‐Fe groundmass metal remains enigmatic. In situ reduction probably played an important role, and association in the same meteorite of the Fe‐nodules is probably significant. But the fluid during alteration was probably not (as previously modeled) purely S and O, of simple heat‐driven internal derivation. We conjecture a two‐stage metasomatism, as fluids passed through Camel Donga after impact heating of volatile‐rich chondritic masses (survivors of gentle accretionary impacts) within the nearby crust. First, reduction to form troilite may have been triggered by fluids rich in S2 and CO (derived from the protonodules?), and then in a distinct later stage, fluids were (comparatively) H2O‐rich, and thus reacted with troilite to form pure‐Fe metal along with H2S and SO2. The early eucrite crust was in places a dynamic fluid‐bearing environment that hosted complex chemical processes, including some that engendered significant diversity among metal+sulfide alterations.  相似文献   
3.
We measured total selenium and total mercury concentrations ([TSe] and [THg]) in hair (n = 138) and blood (n = 73) of harbor seals (Phoca vitulina) from California to assess variation by geography and sex, and inferred feeding relationships based on carbon, nitrogen, and sulfur stable isotopes. Harbor seals from Hg-contaminated sites had significantly greater [THg], and lesser [TSe] and TSe:THg molar ratios than seals from a relatively uncontaminated site. Males had significantly greater [THg] than females at all locations. Sulfur stable isotope values explained approximately 25% of the variability in [THg], indicating increased Hg exposure for seals with a greater use of estuarine prey species. Decreased [TSe] in harbor seals from Hg-contaminated regions may indicate a relative Se deficiency to mitigate the toxic effects of Hg. Further investigation into the Se status and the potential negative impact of Hg on harbor seals from Hg-contaminated sites is warranted.  相似文献   
4.
To assess risks of chemically-dispersed oil to marine organisms, oil concentrations in the water were simulated using a hypothetical spill accident in Tokyo Bay. Simulated oil concentrations were then compared with the short-term no-observed effect concentration (NOEC), 0.01 mg/L, obtained through toxicity tests using marine diatoms, amphipod and fish. Area of oil concentrations higher than the NOEC were compared with respect to use and non-use of dispersant. Results of the simulation show relatively faster dispersion near the mouth of the bay compared to its inner sections which is basically related to its stronger water currents. Interestingly, in the inner bay, a large area of chemically-dispersed oil has concentrations higher than the NOEC. It seems emulsifying oil by dispersant increases oil concentrations, which could lead to higher toxicity to aquatic organisms. When stronger winds occur, however, the difference in toxic areas between use and non-use of dispersant is quite small.  相似文献   
5.
Illite crystallinity, K–Ar dating of illite, and fission‐track dating of zircon are analyzed in the hanging wall (Sampodake unit) and footwall (Mikado unit) of a seismogenic out‐of‐sequence thrust (Nobeoka thrust) within the Shimanto accretionary complex of central Kyushu, southwest Japan. The obtained metamorphic temperatures, and timing of metamorphism and cooling, reveal the tectono‐metamorphic evolution of the complex, and related development of the Nobeoka thrust. Illite crystallinity data indicate that the Late Cretaceous Sampodake unit was metamorphosed at temperatures of around 300 to 310°C, while the Middle Eocene Mikado unit was metamorphosed at 260 to 300°C. Illite K–Ar ages and zircon fission‐track ages constrain the timing of metamorphism of the Sampodake unit to the early Middle Eocene (46 to 50 Ma, mean = 48 Ma). Metamorphism of the Mikado unit occurred no earlier than 40 Ma, which is the youngest depositional age of the unit. The Nobeoka thrust is inferred to have been active during about 40 to 48 Ma, as the Sampodake unit started its post metamorphic cooling after 48 Ma and was thrust over the Mikado unit at about 40 Ma along the Nobeoka thrust. These results indicate that the Nobeoka thrust was active for more than 10 million years.  相似文献   
6.
Although crew members form bedrock of the squid industry, they have not benefitted from the transformation and governance reforms because: the harvesting technique necessitates incentivisation of individual effort; they are highly mobile; and the industry is exempted from revised labour legislation. As a result, they have been unable to organise for laying claim on benefits. As they unionise to strengthen their bargaining position, the conundrum is how to maintain incentive practices on which the catching sector is based while asserting their rights. The challenge is re-structuring the sector to improve quality of employment while maintaining individual crew member productivity incentives.  相似文献   
7.
Journal of Paleolimnology - Sub-annual-scale environmental and ecosystem changes since the mid-18th century were reconstructed in a semi-closed lagoon, Lake Hiruga, located along the Sea of Japan...  相似文献   
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9.
We have performed N-body simulations on the stage of protoplanet formation from planetesimals, taking into account so-called “type-I migration,” and damping of orbital eccentricities and inclinations, as a result of tidal interaction with a gas disk without gap formation. One of the most serious problems in formation of terrestrial planets and jovian planet cores is that the migration time scale predicted by the linear theory is shorter than the disk lifetime (106-107 years). In this paper, we investigate retardation of type-I migration of a protoplanet due to a torque from a planetesimal disk in which a gap is opened up by the protoplanet, and torques from other protoplanets which are formed in inner and outer regions. In the first series of runs, we carried out N-body simulations of the planetesimal disk, which ranges from 0.9 to 1.1 AU, with a protoplanet seed in order to clarify how much retardation can be induced by the planetesimal disk and how long such retardation can last. We simulated six cases with different migration speeds. We found that in all of our simulations, a clear gap is not maintained for more than 105 years in the planetesimal disk. For very fast migration, a gap cannot be created in the planetesimal disk. For migration slower than some critical speed, a gap does form. However, because of the growth of the surrounding planetesimals, gravitational perturbation of the planetesimals eventually becomes so strong that the planetesimals diffuse into the vicinity of the protoplanets, resulting in destruction of the gap. After the gap is destroyed, close encounters with the planetesimals rather accelerate the protoplanet migration. In this way, the migration cannot be retarded by the torque from the planetesimal disk, regardless of the migration speed. In the second series of runs, we simulated accretion of planetesimals in wide range of semimajor axis, 0.5 to 2-5 AU, starting with equal mass planetesimals without a protoplanet seed. Since formation of comparable-mass multiple protoplanets (“oligarchic growth”) is expected, the interactions with other protoplanets have a potential to alter the migration speed. However, inner protoplanets migrate before outer ones are formed, so that the migration and the accretion process of a runaway protoplanet are not affected by the other protoplanets placed inner and outer regions of its orbit. From the results of these two series of simulations, we conclude that the existence of planetesimals and multiple protoplanets do not affect type-I migration and therefore the migration shall proceed as the linear theory has suggested.  相似文献   
10.
Rainwater samples (wet-only; event samples) collected in Niigata in late autumn 1996 and springtime 1997 were used to assess the effectiveness of thymol as a biocide in Japanese rainwater. Upon collection each rainwater sample was divided into sub-samples, with thymol added to one sub-sample. Sub-samples with and without thymol were shipped to CSIRO, Australia, for chemical analysis. Comparison of analytical results for each pair of sub-samples proved the effectiveness of thymol in preventing biological action in this region where effects of rainwater microflaura and fauna on rainwater composition have not before been studied. Sub-samples without thymol exhibited lowered electrical conductivity, loss of the cations H+ and NH 4 - , and loss of the anions HCOO-, CH3COO-, C2O 4 2- , CH3SO 3 - and PO 4 3- . Nitrate showed no change in all but one of the samples, indicating that ammonia was the preferred source of nitrogen for the biological processes that consumed the rainwater organic acids and phosphate. These results suggest that thymol is a suitable rainwater biocide for use under Japanese conditions.  相似文献   
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