Mineralogy, composition and PGM of chromitites from Pefki, Pindos ophiolite complex (NW Greece): evidence for progressively elevated fAs conditions in the upper mantle sequence     

Argirios Kapsiotis  Tassos A. Grammatikopoulos  Basilios Tsikouras  Konstantin Hatzipanagiotou  Federica Zaccarini  Giorgio Garuti 《Mineralogy and Petrology》2011,101(1-2):129-150

The Pindos ophiolite complex, located in the northwestern part of continental Greece, hosts various chromite deposits of both metallurgical (high-Cr) and refractory (high-Al) type. The Pefki chromitites are banded and sub-concordant to the surrounding serpentinized dunites. The Cr# [Cr/(Cr?+?Al)] of magnesiochromite varies between 0.75 and 0.79. The total PGE grade ranges from 105.9 up to 300.0?ppb. IPGE are higher than PPGE, typical of mantle hosted ophiolitic chromitites. The PGM assemblage in chromitites comprises anduoite, ruarsite, laurite, irarsite, sperrylite, hollingworthite, Os-Ru-Ir alloys including osmium and rutheniridosmine, Ru-bearing oxides, braggite, paolovite, platarsite, cooperite, vysotskite, and palladodymite. Iridarsenite and omeiite were also observed as exsolutions in other PGM. Rare electrum and native Ag are recovered in concentrates. This PGM assemblage is of great petrogenetic importance because it is significantly different from that commonly observed in podiform mantle-hosted and banded crustal-hosted ophiolitic chromitites. PGE chalcogenides of As and S are primary, and possibly crystallized directly from a progressively enriched in As boninitic melt before or during magnesiochromite precipitation. The presence of Ru-bearing oxides implies simultaneous desulfurization and dearsenication processes. Chemically zoned laurite and composite paolovite-electrum intergrowths are indicative of the relatively high mobility of certain PGE at low temperatures under locally oxidizing conditions. The PGM assemblage and chemistry, in conjunction with geological and petrologic data of the studied chromitites, indicate that it is characteristic of chromitites found within or close to the petrologic Moho. Furthermore, the strikingly different PGM assemblages between the high-Cr chromitites within the Pindos massif is suggestive of non-homogeneous group of ores.  相似文献   

Advection of passive scalars induced by a bay-trapped nonstationary vortex     

Eugene A. Ryzhov  Konstantin V. Koshel 《Ocean Dynamics》2018,68(3):411-422

A simple model of fluid particle advection induced by the interaction of a point vortex and incident plane flow occurring near a curved boundary is analyzed. The use of the curved boundary in this case is aimed at mimicking the geometry of an isolated bay of a circular shape. An introduction of such a boundary to the model results in the appearance of retention zones, where the vortex can be permanently trapped being either stationary or periodically oscillating. When stationary, it induces a steady velocity field that in turn ensures regular advection of nearby fluid particles. When the vortex oscillates periodically, the induced velocity field turns unsteady leading to the manifestation of chaotic advection of fluid particles. We show that the size of the fluid region engaged into chaotic advection increases almost monotonically with the increased magnitude of the vortex oscillations provided the magnitude remains relatively small. The monotonicity is accounted for the fact that the frequency of the vortex oscillations incommensurable with the proper frequency of fluid particle rotations in the steady state. Another point of interest is that it is demonstrated that bounded regions, in which the vortex may be trapped, can appear even at a significant distance from the bay. Making use of a Lagrangian indicator, examples of fluid particle advection induced by the periodic motion of the vortex inside the bay are adduced.  相似文献   

Reply to “Discussion of ‘Study of Air-Ventilated Cavity under Model Hull on Water Surface’ by K.I. Matveev,T.J. Burnett,and A.E. Ockfen [Ocean Engineering 36 (12–13) 891–1038 (September 2009)]”     

Konstantin I. Matveev 《Ocean Engineering》2010,37(14-15):1392

  相似文献   

The shedding of mesoscale anticyclonic eddies from the Alaskan Stream and westward transport of warm water   总被引：1，自引：0，他引：1  

Konstantin Rogachev  Natalya Shlyk  Eddy Carmack 《Deep Sea Research Part II: Topical Studies in Oceanography》2007,54(23-26):2643

The south-flowing waters of the Kamchatka and Oyashio Currents and west-flowing waters of the Alaskan Stream are key components of the western sub-Arctic Pacific circulation. We use CTD data, Argo buoys, WOCE surface drifters, and satellite-derived sea-level observations to investigate the structure and interannual changes in this system that arise from interactions among anticyclonic eddies and the mean flow. Variability in the temperature of the upstream Oyashio and Kamchatka Currents is evident by warming in mesothermal layer in 1994–2005 compared to 1990–1991. A major fraction of the water in these currents is derived directly from the Alaskan Stream. The stream also sheds large anticyclonic (Aleutian) eddies, averaging approximately 300 km in diameter with a volume transport significant in comparison with that of the Kamchatka Current itself. These eddies enclose pools of relatively warm and saline water whose temperature is typically 4 °C warmer and salinity is 0.4 greater than that of cold-core Kamchatka eddies in the same density range. Aleutian eddies drift at approximately 1.2 km d⁻¹ and retain their distinctive warm and salty characteristics for at least 2 years. Selected westward pathways during 1990–2004 are identified. If the shorter northern route is followed, Aleutian eddies remain close to the stream and persist sufficiently long to carry warm and saline water directly to the Kamchatka Current. This was observed during 1994–1997 with substantial warming of the waters in the Kamchatka Current and upstream Oyashio. If the eddies take a more southern route they detach from the stream but can still contribute significant quantities of warm and saline water to the upstream Oyashio, as in 2004–2005. However, the eddies following this southern route may dissipate before reaching the western boundary current region.  相似文献   

Monitoring the Kuroshio Extension with Dynamically Constrained Synthesis of the Acoustic Tomography, Satellite Altimeter and in situ Data     

Konstantin V. Lebedev  Max Yaremchuk  Humio Mitsudera  Iwao Nakano  Gang Yuan 《Journal of Oceanography》2003,59(6):751-763

A finite-difference quasigeostrophic (QG) model of an open ocean region has been employed to produce a dynamically constrained synthesis of acoustic tomography and satellite altimetry data with in situ observations. The assimilation algorithm is based upon the 4D variational data interpolation scheme controlled by the model's initial and boundary conditions. The data sets analyzed include direct and differential travel times measured at the array of five acoustic transceivers deployed by JAMSTEC in the region of the Kuroshio Extension in 1997, Topex/Poseidon altimetry, CTD soundings, and ADCP velocity profiles. The region monitored is located within the area 27.5°–36.5°N, 143°–155°. The results of assimilation show that mesoscale variability can be effectively reconstructed by five transceivers measuring direct and reciprocal travel times supported by relatively sparse in situ measurements. The misfits between model and data lie within the observational error bars for all the data types used in assimilation. We have compared the results of assimilation with the statistical inversion of travel time data and analyzed energy balances of the optimized model solution. Energy exchange between the depth-averaged and shear components of the observed currents reveals a weak decay of the barotropic mode at the rate of 0.2 ± 0.7⋅10⁻⁵ cm²/s³ due to topographic interaction. Mean currents in the region are unstable with an estimate of the available potential energy flux from the mean current to the eddies of 4.7 ± 2.3⋅10⁻⁵ cm²/s³. Kinetic energy transition has the same sign and is estimated as 2.8 ± 2.5⋅10⁻⁵ cm²/s³. Potential enstrophy is transferred to the mesoscale at a rate of 5.5 ± 2.7⋅10⁻¹⁸ s⁻³. These figures provide observational evidence of the properties of free geostrophic turbulence which were predicted by theory and observed in numerical experiments. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

Rodingites from the Veria-Naousa ophiolite (Greece): Mineralogical evolution,metasomatism and petrogenetic processes     

Aikaterini Rogkala  Petros Petrounias  Petros Koutsovitis  Panagiota P. Giannakopoulou  Panagiotis Pomonis  Paraskevi Lampropoulou  Konstantin Hatzipanagiotou 《Chemie der Erde / Geochemistry》2022,82(2):125860

In the Veria-Naousa ophiolitic complex (north Greece), rodingite appears mainly in the form of cross cutting dykes within serpentinised peridotites. It is distinguished into three types, based upon the provenance of its protoliths, textural characteristics, mineralogical assemblages and geochemical affinities. Type I rodigites were derived from boninitic diabasic protoliths and their mineralogical assemblage include garnet + clinopyroxene + chlorite. Type II rodingites were formed at the expense of gabbroic precursors, comprising clinopyroxene + garnet + vesuvianite ± quartz, whereas Type III rodingites replaced diabasic tholeiitic protoliths comprising of garnets + vesuvianite + clinopyroxene + chlorite. Rodingitisation resulted in desilification, decrease of alkalies, Al, Fe, Mg and increase in Ca contents. In Type I rodingites the MREE (middle rare earth elements) and HREE (heavy rare earth elements) were slightly reduced. Type II rodingites experienced LREE (light rare earth elements) depletions, whereas MREE and HREE remained fairly stable. Restricted mobility of REE in Type III rodingites is assigned to shallow-level rodingitisation under decreasing pH.Rodingitisation occured in two distinct stages at fore-arc settings. The first stage occured under mildly oxidising conditions and enhanced CO₂/H₂O ratios. This stage affected the protoliths of all rodingite types. The second rodingitisation stage occured under more oxidising conditions and lower CO₂/H₂O ratios, which corresponds to the exhumation stage of the serpentinite-rodingite formations. Types II and III rodingites were subjected to further rodingitisation under the increasing influence of slab-derived hydrous phases at shallower depths, leading to the formation of late-stage andradite and vesuvianite. All stages of rodingitisation are estimated to have occurred under relatively moderate temperatures and pressure (~300 to 450 °C; ~2–6 kbar respectively).  相似文献   

Static performance of power-augmented ram vehicle model on water   总被引：1，自引：0，他引：1  

Konstantin I. Matveev  Ryan K. Soderlund 《Ocean Engineering》2008,35(10):1060-1065

An experimental parametric study of a novel air-assisted platform-type model called power-augmented ram vehicle is described. The zero-speed regimes of the model over the water are investigated. The recovered thrust, pressure underneath the platform, and the model attitude are recorded for variable system geometry, loading conditions, and propulsor thrust. The stern flap under the model platform provides an effective mechanism for controlling the thrust recovery and the air-jet-induced lift. Unstable behavior of the model is found at sufficiently high levels of the propulsor thrust.  相似文献   

Preindustrial, historical, and fertilization simulations using a global ocean carbon model with new parameterizations of iron limitation, calcification, and N₂ fixation     

Konstantin Zahariev  James R. Christian  Kenneth L. Denman 《Progress in Oceanography》2008,77(1):56-82

The Canadian Model of Ocean Carbon (CMOC) has been developed as part of a global coupled climate carbon model. In a stand-alone integration to preindustrial equilibrium, the model ecosystem and global ocean carbon cycle are in general agreement with estimates based on observations. CMOC reproduces global mean estimates and spatial distributions of various indicators of the strength of the biological pump; the spatial distribution of the air-sea exchange of CO₂ is consistent with present-day estimates. Agreement with the observed distribution of alkalinity is good, consistent with recent estimates of the mean rain ratio that are lower than historic estimates, and with calcification occurring primarily in the lower latitudes. With anthropogenic emissions and climate forcing from a 1850-2000 climate model simulation, anthropogenic CO₂ accumulates at a similar rate and with a similar spatial distribution as estimated from observations. A hypothetical scenario for complete elimination of iron limitation generates maximal rates of uptake of atmospheric CO₂ of less than 1 PgC y⁻¹, or about 11% of 2004 industrial emissions. Even a ‘perfect’ future of sustained fertilization would have a minor impact on atmospheric CO₂ growth. In the long term, the onset of fertilization causes the ocean to take up an additional 77 PgC after several thousand years, compared with about 84 PgC thought to have occurred during the transition into the last glacial maximum due to iron fertilization associated with increased dust deposition.  相似文献   

Dust torus formed by particles ejected from a celestial body at an arbitrary point of its elliptic orbit     

Sergei A. Orlov  Konstantin V. Kholshevnikov 《Celestial Mechanics and Dynamical Astronomy》2013,116(1):35-52

Dust comnplexes make one of the components of the Solar System. The surface shape of a typical dust complex consisting of particles ejected by a celestial body is found analytically, under reasonable assumptions (the main one being the smallness of perturbations). Parametric equations of the surface are obtained. The main properties of the surface are established and studied. Singular points are found, and the topological type of the surface as a whole and in the vicinity of the singular points (one conic points and one constriction) is examined.  相似文献   

On the sublimation of ice particles on the surface of Mars; with applications to the 2007/8 Phoenix Scout mission     

Peter A. Taylor  Konstantin Baibakov  Michael H. Hecht  P.-Y. Li  Luis Prieto 《Icarus》2006,181(2):375-387

Experimental studies related to the sublimation of ice, in bulk or as small particles, alone or mixed with dust similar to that expected on the surface of Mars, are reported. The experiments, a cloud physics particle sublimation model, and a convection model presented by Ingersoll, all indicate a strong dependence of sublimation rate on temperature, and this appears to be the dominant factor, assuming that the relative humidity of the air is fairly low. In addition the rate of loss of water vapour appears to depend primarily on exposed surface area and less on particle size and the total mass of the sample, or the mass of ice in the sample. The 2007/8 Phoenix Scout mission plans to obtain and analyse samples of sub-surface ice from about 70° N on Mars. A concern is that these samples, in the form of ice chips of size about 1 mm diameter, could be prone to sublimation when exposed for prolonged periods (many hours) to a relatively warm and dry atmosphere. Our laboratory simulations confirm that this could be a problem if particles are simply left lying on the surface, but also indicate that samples kept suitably cold and collected together in confined piles will survive long enough for the collection and delivery (to the analysis instruments) procedure to be completed.  相似文献