Early solar system aqueous activity: K isotope evidence from Allende     

Yun Jiang  Piers Koefoed  Olga Pravdivtseva  Heng Chen  Chun‐Hui Li  Fang Huang  Li‐Ping Qin  Jia Liu  Kun Wang 《Meteoritics & planetary science》2021,56(1):61-76

The alkali element K is moderately volatile and fluid mobile; thus, it can be influenced by both primary processes (evaporation and recondensation) in the solar nebula and secondary processes (thermal and aqueous alteration) in the parent body. Since these primary and secondary processes would induce different isotopic fractionations, K isotopes could become a potential tracer to distinguish them. Using recently developed methods with improved precision (0.05‰, 95% confidence interval), we systematically measured the K isotopic compositions and major/trace elemental compositions of chondritic components (18 chondrules, 3 CAIs, 2 matrices, and 5 bulks) in the carbonaceous chondrite fall Allende. Among all the components analyzed in this study, CAIs, which formed initially under high‐temperature conditions in the solar nebula and were dominated by nominally K‐free refractory minerals, have the highest K₂O content (average 0.53 wt%) and have K isotope compositions most enriched in heavy isotopes (δ⁴¹K: ?0.30 to ?0.25‰). Such an observation is consistent with previous petrologic studies that show CAIs in Allende have undergone alkali enrichment during metasomatism. In contrast, chondrules contain lower K₂O content (0.003–0.17 wt%) and generally lighter K isotope compositions (δ⁴¹K: ?0.87‰ to ?0.24‰). The matrix and bulks are nearly identical in K₂O content and K isotope compositions (0.02–0.05 wt%; δ⁴¹K: ?0.62 to ? 0.46‰), which are, as expected, right in the middle of CAIs and chondrules. This strongly indicates that most of the chondritic components of Allende suffered aqueous alteration and their K isotopic compositions are the ramification of Allende parent‐body processing instead of primary nebular signatures. Nevertheless, we propose the small K isotope fractionations observed (< 1‰) among Allende components are likely similar to the overall range of K isotopic fractionation that occurred in nebular environment. Furthermore, the K isotope compositions seen in the components of Allende in this study are consistent with MC‐ICP‐MS analyses of the components in ordinary chondrites, which also show an absence of large (10‰) isotope fractionations. This is not expected as evaporation experiments in nebular conditions suggest there should be large K isotopic fractionations. Nevertheless, possible nebular processes such as chondrules back exchanging with ambient gas when they formed could explain this lack of large K isotopic variation.  相似文献   

中国区域水资源系统韧性与效率的发展协调关系评价   总被引：1，自引：0，他引：1  

孙才志  孟程程 《地理科学》2020,40(12):2094-2104

在界定水资源系统韧性概念的基础上，综合应用赋权法、SBM-DEA模型及发展协调度模型对2000—2016年全国31个省区的区域水资源系统的效率、韧性以及两者之间的发展协调关系进行评价。结果如下：① 中国区域水资源系统效率整体上处于非有效区，在研究期间呈现出在波动中上升的趋势。② 中国区域水资源系统韧性的平均值为0.39，总体水平较低，研究期间整体上呈波动上升趋势。③ 中国区域水资源系统效率与韧性的发展度总体呈现平稳上升—较快上升—急剧下降—上升的趋势，呈倒“U”型发展；协调度在研究期间呈现波动中上升趋势，大部分省区的发展度较好，而协调度较弱。④ 2000—2016年，水资源效率与韧性的发展协调度一直维持着“东?中?西”阶梯式递减格局，失调省区的数量降低，初级协调、中级协调、良好协调省区的数量逐渐提升，整体向协调趋势发展；空间格局上呈现由2000年倒“E”型对称式分布格局向如今北部围绕天津、中部围绕上海、南部围绕广东的三级格局演变，格局分布与中国三大经济区基本吻合，可知中国水资源系统效率与韧性的发展协调水平与经济发展水平之间有明显的关系。  相似文献   

High‐resolution quantification of earthworm calcite granules from western European loess sequences reveals stadial–interstadial climatic variability during the Last Glacial     

Charlotte Prud'homme  Olivier Moine  Jerome Mathieu  Segolene Saulnier‐Copard  Pierre Antoine 《Boreas: An International Journal of Quaternary Research》2019,48(1):257-268

High concentrations of calcite fossil granules produced by earthworms (ECG) have been identified in most of the stratigraphical units along the loess‐palaeosol reference sequence of Nussloch (Germany). They are particularly abundant in interstadial brown soils and in tundra gley horizons, the latter reflecting short‐term phases of aggradation then degradation of permafrost. These granules are characterized by a radial crystalline structure produced in the earthworms by specific bio‐mineralization processes. In our study, we used this biological indicator combined with ¹⁴C and OSL dating, and sedimentological parameters to characterize millennial‐time scale climatic variations recorded in loess sequences. The approach is based on high‐resolution counts of ECG throughout a 17‐m‐thick loess sequence (332 samples). Strong increases in granule and mollusc concentrations suggest warmer climate conditions during palaeosol formation phases, associated with increasing biodiversity, biological activity and vegetation cover. Decreased granule concentrations occur within primary loess deposits, indicating a strong correlation with palaeoenvironmental conditions and demonstrating the reliability of ECG concentration variations as a new palaeoenvironmental proxy. Finally, this pattern is also recorded in loess sequences located about 600 km westward in northern France demonstrating the large‐scale validity of this new palaeoclimatic proxy.  相似文献   

Northwest Africa 11024—A heated and dehydrated unique carbonaceous (CM) chondrite     

Samuel Ebert  Addi Bischoff  Dennis Harries  Sarah Lentfort  Jean‐Alix Barrat  Andreas Pack  Jrme Gattacceca  Robbin Visser  Peter Schmid‐Beurmann  Stephan Kimpel 《Meteoritics & planetary science》2019,54(2):328-356

Based on the high abundance of fine‐grained material and its dark appearance, NWA 11024 was recognized as a CM chondrite, which is also confirmed by oxygen isotope measurements. But contrary to known CM chondrites, the typical phases indicating aqueous alteration (e.g., phyllosilicates, carbonates) are missing. Using multiple analytical techniques, this study reveals the differences and similarities to known CM chondrites and will discuss the possibility that NWA 11024 is the first type 3 CM chondrite. During the investigation, two texturally apparent tochilinite–cronstedtite intergrowths were identified within two thin sections. However, the former phyllosilicates were recrystallized to Fe‐rich olivine during a heating event without changing the textural appearance. A peak temperature of 400–600 °C is estimated, which is not high enough to destroy or recrystallize calcite grains. Thus, calcites were never constituents of the mineral paragenesis. Another remarkable feature of NWA 11024 is the occurrence of unknown clot‐like inclusions (UCLIs) within fine‐grained rims, which are unique in this clarity. Their density and S concentration are significantly higher than of the surrounding fine‐grained rim and UCLIs can be seen as primary objects that were not formed by secondary alteration processes inside the rims. Similarities to chondritic and cometary interplanetary dust particles suggest an ice‐rich first‐generation planetesimal for their origin. In the earliest evolution, NWA 11024 experienced the lowest degree of aqueous alteration of all known CM chondrites and subsequently, a heating event dehydrated the sample. We suggest to classify the meteorite NWA 11024 as the first type 3 CM chondrite similar to the classification of CV3 chondrites (like Allende) that could also have lost their matrix phyllosilicates by thermal dehydration.  相似文献   

陡立矿山岩壁治理中的飘台稳定性分析          下载免费PDF全文

王腾飞  王蒙 《探矿工程》2020,47(10):61-66

随着国家和社会的发展，人们对生态环境越发重视。在经济发展的过程中，因采矿而遗留下了大量的废弃矿坑，这些矿坑的治理迫在眉睫。飘台作为一种治理高陡光滑岩壁的有效方法，在实际工程中被大量使用，然而对飘台稳定性的分析大多停留在简单的公式上。本文设计了一种适用于陡立矿山岩壁治理的砼制飘台结构，提炼了计算飘台稳定性的公式并结合FLAC3D数值模拟软件，对飘台的稳定性进行了分析。研究结果表明，此砼制飘台比较适用于陡立矿山岩壁的治理。  相似文献   

Clinoform architecture and along‐strike facies variability through an exhumed erosional to accretionary basin margin transition     

Miquel Poyatos‐Mor  George D. Jones  Rufus L. Brunt  Daniel E. Tek  David M. Hodgson  Stephen S. Flint 《Basin Research》2019,31(5):920-947

Exhumed basin margin‐scale clinothems provide important archives for understanding process interactions and reconstructing the physiography of sedimentary basins. However, studies of coeval shelf through slope to basin‐floor deposits are rarely documented, mainly due to outcrop or subsurface dataset limitations. Unit G from the Laingsburg depocentre (Karoo Basin, South Africa) is a rare example of a complete basin margin scale clinothem (>60 km long, 200 m‐high), with >10 km of depositional strike control, which allows a quasi‐3D study of a preserved shelf‐slope‐basin floor transition over a ca. 1,200 km² area. Sand‐prone, wave‐influenced topset deposits close to the shelf‐edge rollover zone can be physically mapped down dip for ca. 10 km as they thicken and transition into heterolithic foreset/slope deposits. These deposits progressively fine and thin over tens of km farther down dip into sand‐starved bottomset/basin‐floor deposits. Only a few km along strike, the coeval foreset/slope deposits are bypass‐dominated with incisional features interpreted as minor slope conduits/gullies. The margin here is steeper, more channelized and records a stepped profile with evidence of sand‐filled intraslope topography, a preserved base‐of‐slope transition zone and sand‐rich bottomset/basin‐floor deposits. Unit G is interpreted as part of a composite depositional sequence that records a change in basin margin style from an underlying incised slope with large sand‐rich basin‐floor fans to an overlying accretion‐dominated shelf with limited sand supply to the slope and basin floor. The change in margin style is accompanied with decreased clinoform height/slope and increased shelf width. This is interpreted to reflect a transition in subsidence style from regional sag, driven by dynamic topography/inherited basement configuration, to early foreland basin flexural loading. Results of this study caution against reconstructing basin margin successions from partial datasets without accounting for temporal and spatial physiographic changes, with potential implications on predictive basin evolution models.  相似文献   

p-y曲线对成层土体中大直径单桩的适用性研究          下载免费PDF全文

孟晓伟  翟恩地  许成顺 《海洋技术学报》2019,38(2)

API规范推荐的p-y曲线是由均质土体得到的,并未考虑土层间相互作用,Georgiadis基于柔性桩提出了等效深度法修正p-y曲线,把均质土p-y曲线延伸到了成层土体中。为了研究p-y曲线和等效深度法对于大直径单桩在成层土体中的适用性,取4种典型地质条件:成层砂土、砂土-黏土-砂土、成层黏土和黏土-砂土-黏土,通过L-PILE软件计算了6 m直径单桩基础的p-y曲线、桩顶水平荷载-位移曲线、桩身位移和弯矩。并与ABAQUS建立的单桩基础三维有限元模型计算结果进行比较。结果表明等效深度法对于成层砂土影响不大;对于成层黏土影响较大;对于中间为软弱土层的成层土体,在荷载较大时影响显著,等效深度法计算结果更加接近FEM结果。在成层土体中,p-y曲线应用于大直径单桩对于砂土高估了初始刚度,低估了极限抗力;对于黏土则低估了初始刚度和极限抗力。  相似文献   

Long‐term temporal and spatial patterns in bioeroding sponge distribution at the Abrolhos Bank,Brazil, Southwestern Atlantic     

Fernando Coreixas de Moraes  Fernanda Cervi  Cludia S. Karez  Leonardo T. Salgado  Rodrigo L. Moura  Gabriella A. Leal  Alex C. Bastos  Gilberto M. Amado‐Filho 《Marine Ecology》2019,40(3)

Bioeroding sponges belong to the most dominant bioeroders, significantly contributing to the erosion of coral reefs. Some species are tolerant or even benefit from environmental conditions such as ocean warming, acidification, and eutrophication. In consequence, increases in sponge bioerosion have been observed on some coral reefs over the last decades. The Abrolhos Bank is the largest coral reef system in the South Atlantic. It has been affected by sedimentation, eutrophication, overfishing, and climate change, mainly affecting coastal reefs, and at lesser intensity outer ones as well. This study aimed to describe spatial and temporal patterns in bioeroding sponge distribution in carbonate substrates in the Abrolhos Bank. Photo‐quadrats were used to compare bioeroding sponge abundance between two shallow reefs: a coastal, Pedra de Leste (PL), and an outer reef, Parcel dos Abrolhos (PAB). Each individual was delimitated over the substrate by determining the sponge surface through a line connecting the outermost papillae. The study was conducted over 6 years in 2008–2009 and 2013–2016. Four species of bioeroding sponges were identified: Cliona carteri Ridley, 1881, C. delitrix Pang, 1973, C. cf. schmidtii Ridley, 1881, and Siphonodictyon coralliphagum Rützler, 1971. The distribution and abundance of species varied between the inner and outer reefs and across the years, and displayed certain selectivity for the calcareous substrates recorded. Crustose coralline algae (CCA) were the main substrate excavated by the most abundant bioeroding species, C. carteri, and represented 70% of the substrate types occupied by this sponge (CCA, coral overgrown by CCA and plain coral). The highest abundance of bioeroding sponges observed in photo‐quadrats was 21.3 individuals/m² at the outer reefs (PAB) in 2014. The abundances or areal extents of bioeroding sponges were up to 10 times greater on the outer reefs than on the coastal ones, where sedimentation is higher and more strongly influenced by siliciclastic material. Moreover, a higher herbivorous fish biomass has been reported on outer reefs which could also influence the higher abundance of bioeroding sponges in outer reefs. During the study period of 6 years, an increase in bioeroding sponge abundance was observed at the outer reefs (PAB), with the sea surface temperature increase. As CCA have an important role in reefal cementation and carbonate production in the Abrolhos reefs, a bioerosion impact might be expected, in particular, on the outer reefs.  相似文献   

Zircon fission‐track ages from Newfoundland—A proxy for high geothermal gradients and exhumation before opening of the Central Atlantic Ocean     

Arne P. Willner  Stuart N. Thomson  Johannes Glodny  Hans‐Joachim Massonne  Rolf L. Romer  Cees R. van Staal  Alexandre Zagorevski 《地学学报》2019,31(1):1-10

Following Appalachian orogenesis, metamorphic rocks in central Newfoundland were exhumed and reburied under Tournaisian strata. New zircon fission‐track (ZFT) ages of metamorphic rocks below the Tournaisian unconformity yield post‐depositionally reset ages of 212–235 Ma indicating regional fluid‐absent reheating to at least ≥220°C. Post‐Tournaisian sedimentary thicknesses in surrounding basins show that burial alone cannot explain such temperatures, thus requiring that palaeo‐geothermal gradients increased to ≥30–40°C/km before final late Triassic accelerated cooling. We attribute these elevated palaeo‐geothermal gradients to localized thermal blanketing by insulating sediments overlying radiogenic high‐heat‐producing granitoids. Late Triassic rifting and magmatism before break up of Pangaea likely also contributed to elevated heat flow, as well as uplift, triggering late Triassic accelerated cooling and exhumation. Thermochronological ages of 240–200 Ma are seen throughout Atlantic Canada, and record rifting and basaltic magmatism on the conjugate margins of the Central Atlantic Ocean preceding the onset of oceanic spreading at ~190 Ma.  相似文献   

海拉尔—塔木察格盆地中部富油凹陷高含凝灰质碎屑岩储层成因及油气勘探意义     

蒙启安  李军辉  李跃  邹越 《吉林大学学报(地球科学版)》2020,50(2):569-578

海拉尔—塔木察格盆地中部富油凹陷下白垩统铜钵庙组和南屯组广泛发育高含凝灰质碎屑岩储层，并已于其中获得了工业突破，但对其成因机制认识不清。在岩心、薄片、录井和测井等资料综合研究的基础上，结合大量海拉尔—塔木察格盆地及周边地区的火山事件分析，认为中部富油凹陷发育的高含凝灰质碎屑岩的岩石类型主要包括凝灰质砂岩、凝灰质泥岩、凝灰岩和沉凝灰岩。不同时期、不同凹陷高含凝灰质碎屑岩储层发育特点各异，整体来看从铜钵庙组到南屯组储层中的凝灰质含量越来越低，高含凝灰质碎屑岩储层主要发育在铜钵庙组和南一段沉积时期。高含凝灰质碎屑岩储层中的火山物质并非来源于自身断陷期发生的基性火山活动，而是来自于大兴安岭地区大规模的酸性火山喷发事件。海拉尔—塔木察格盆地高含凝灰质碎屑岩储层的成因机制包括两种类型：一种是同沉积期火山灰直接空降入湖型；另一种是同沉积期火山灰先沉降至陆上经河流搬运后再沉积的水携型。高含凝灰质碎屑岩储层中的火山碎屑物质受有机酸作用易于溶蚀，次生孔隙发育，为深部油气成藏提供了有效储层空间，并且火山喷发活动对优质烃源岩的形成具有促进作用，对于油气勘探具有重要意义。  相似文献