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1.
Lifetimes of six levels belonging to the 4f106p configuration of Ho  iii have been measured for the first time using the time-resolved laser-induced fluorescence method. They are compared with multiconfigurational pseudo-relativistic Hartree–Fock calculations. A very good agreement is found. Using the experimental lifetimes and theoretical branching fractions, a first set of transition probabilities of astrophysical interest has been obtained for this ion.  相似文献   
2.
Precipitation episodes in the form of freezing rain and ice pellets represent natural hazards affecting eastern Canada during the cold season. These types of precipitation mainly occur in the St. Lawrence River valley and the Atlantic provinces of Canada. This study aims to evaluate the ability of the fifth-generation Canadian Regional Climate Model (CRCM5), using a 0.11° horizontal grid mesh, to hindcast mixed precipitation when driven by reanalyses produced by the European Centre for Medium-range Weather Forecasts (ERA-Interim) for a 35-year period. In general, the CRCM5 simulation slightly overestimates the occurrence of freezing rain, but the geographical distribution is well reproduced. The duration of freezing rain events and accompanying surface winds in the Montréal region are reproduced by CRCM5. A case study is performed for an especially catastrophic freezing-rain event in January 1998; the model succeeds in simulating the intensity and duration of the episode, as well as the propitious meteorological environment. Overall, the model is also able to reproduce the climatology and a specific event of freezing rain and ice pellets.  相似文献   
3.
The Strait of Georgia is a large, semi-enclosed body of water between Vancouver Island and the mainland of British Columbia connected to the Pacific Ocean via Juan de Fuca Strait at the south and Johnstone Strait at the north. During the winter months, coastal communities along the Strait of Georgia are at risk of flooding caused by storm surges, a natural hazard that can occur when a strong storm coincides with high tide. This investigation produces storm surge hindcasts using a three-dimensional numerical ocean model for the Strait of Georgia and the surrounding bodies of water (Juan de Fuca Strait, Puget Sound, and Johnstone Strait) collectively known as the Salish Sea. The numerical model employs the Nucleus for European Modelling of the Ocean architecture in a regional configuration. The model is evaluated through comparisons of tidal elevation harmonics and storm surge with observations. Important forcing factors contributing to storm surges are assessed. It is shown that surges entering the domain from the Pacific Ocean make the most significant contribution to surge amplitude within the Strait of Georgia. Comparisons between simulations and high-resolution and low-resolution atmospheric forcing further emphasize that remote forcing is the dominant factor in surge amplitudes in this region. In addition, local wind patterns caused a slight increase in surge amplitude on the mainland side of the Strait of Georgia compared with Vancouver Island coastal areas during a major wind storm on 15 December 2006. Generally, surge amplitudes are found to be greater within the Strait of Georgia than in Juan de Fuca Strait.  相似文献   
4.
5.
Critical tissue copper (Cu) residues associated with adverse effects on embryo-larval development were determined for the Mediterranean mussel (Mytilus galloprovincialis) and purple sea urchin (Strongylocentrotus purpuratus) following laboratory exposure to Cu-spiked seawater collected from San Diego Bay, California, USA. Whole body no-observed-effect-residues (NOER) were similar, with means of 21 and 23mugg(-1)dw, for M. galloprovincialis and S. purpuratus, respectively. Mean whole body median effect residues (ER50) were 49 and 142mugg(-1)dw for M. galloprovincialis and S. purpuratus, respectively. The difference in ER50s between species was reduced to a factor of <2 when expressed as soft tissue residues. Coefficients of variation among whole body-ER50s were 3-fold lower than median waterborne effect concentrations (EC50) for both species exposed to samples varying in water quality characteristics. This suggests that tissue concentrations were a better predictor of toxicity than water concentrations. The CBRs described herein do not differentiate between the internal Cu concentrations that are metabolically available and those that are accumulated and then detoxified. They do appear, however, to be well enough related to the level of accumulation at the site of action of toxicity that they serve as useful surrogates for the copper concentration that affects embryonic development of the species tested. Results presented have potentially important implications for a variety of monitoring and assessment strategies. These include regulatory approaches for deriving saltwater ambient water quality criteria for Cu, contributions towards the development of a saltwater biotic ligand model, the conceptual approach of using CBRs, and ecological risk assessment.  相似文献   
6.
Severe weather has important social and economic impacts. Some studies have indicated that its intensity may increase over this century as a consequence of climate change induced by greenhouse gases. This study aims to investigate the possibility of a future increase in deep convective events over North America resulting from the evolution of favourable atmospheric conditions. Our analysis is based on an ensemble of projections performed using the Canadian Regional Climate Model (CRCM) at 45?km resolution, driven by different Global Climate Models (GCMs) and reanalyses. We concentrate our study on Convective Available Potential Energy (CAPE), vertical wind shear, and convective precipitation. Based on two different approaches to linking atmospheric conditions and severe weather, we find that the number of extreme weather events is expected to increase during the twenty-first century. In agreement with other studies on this subject, we find that CAPE is expected to increase, whereas wind shear is expected to decrease slightly. Through the analysis of the CRCM's convective precipitation outputs, we show that severe convective liquid precipitation events may become both more frequent and slightly more intense. Sensitivity experiments show that results depend on the driving GCM although they confirm the general conclusions. Additional experiments conducted with reduced humidity input at the lateral boundaries show the significant role that the humidity level of the driving GCMs has on simulated extreme regional events. At the regional level results are, in general, consistent with those found at the continental scale, but large inter-regional variations exist.  相似文献   
7.
Previous studies suggest that the metamorphic evolution of the ultrahigh‐pressure garnet peridotite from Alpe Arami was characterized by rapid subduction to a depth of c. 180 km with partial chemical equilibration at c. 5.9 Gpa/1180 °C and an initial stage of near‐isothermal decompression followed by enhanced cooling. In this study, average cooling rates were constrained by diffusion modelling on retrograde Fe–Mg zonation profiles across garnet porphyroclasts. Considering the effects of temperature, pressure and garnet bulk composition on the Fe–Mg interdiffusion coefficient, cooling rates of 380–1600 °C Myr?1 for the interval from 1180 to 800 °C were obtained. Similar or even higher average cooling rates resulted from thermal modelling, whereby the characteristics of the calculated temperature‐time path depend on the shape and size of the hot peridotite body and the boundary conditions of the cooling process. The very high cooling rates obtained from both geospeedometry and thermal modelling imply extremely fast exhumation rates of c. 15 mm yr?1 or more. These results agree with the range of exhumation rates (16–50 mm yr?1) deduced from geochronological results. It is suggested that the Alpe Arami peridotite passively returned towards the surface as part of a buoyant sliver, caused as a consequence of slab breakoff.  相似文献   
8.
Ocean Dynamics - In the context of Canada’s Ocean Protection Plan (OPP), improved coastal and near-shore modelling is needed to enhance marine safety and emergency response capacity in the...  相似文献   
9.
An updated version of the Canadian Regional Climate Model (CRCM-II) has been used to perform time-slice simulations over northwestern North America, nested in the coupled Canadian General Circulation Model (CGCM2). Both driving and driven models are integrated in a scenario of transient greenhouse gases (GHG) and aerosols. The time slices span three decades that were chosen to correspond roughly to single, double and triple current GHG concentration levels. Several enhancements have been implemented in CRCM-II since the CRCM-I climate-change simulations reported upon earlier. The larger computational domain, extending further to the west, north and south, allows for a better spin-up of weather systems as they enter the regional domain. The increased length of the simulations, from 5 to 10 years, strengthens the statistical robustness of the results. The improvements to the physical parameterisation, notably the moist convection scheme and the diagnostic cloud formulation, cure the excessive cloud cover problem present in CRCM-I, reduce the warm surface bias and prevent the occurrence of grid-point precipitation storms that occurred with CRCM-I in summer. The dynamical ocean and sea-ice components of CGCM2 that is used to provide atmospheric lateral and surface boundary conditions to CRCM-II, as well as the use of transient rather than equilibrium conditions of GHG and the inclusion of direct aerosols forcing, in both CGCM2 and CRCM-II, increase the realism of the CRCM-II climate-change simulation.  相似文献   
10.
The inter- and intragrain distribution of Li and Be in the subduction-related ultrahigh-pressure (UHP) garnet peridotite from Alpe Arami, Central Swiss Alps, was studied using secondary ion mass spectrometry. The data indicate substantial Li infiltration during exhumation of this ultramafic body. Orthopyroxene porphyroclasts and neoblasts are characterised by low Li contents (0.11-0.36 µg/g) typical of depleted peridotites, whereas Li zonation profiles across porphyroclasts of garnet and clinopyroxene document a metasomatic addition of Li. Small clinopyroxene grains in the matrix contain extremely high and variable abundances of Li (4-16 µg/g). In marked contrast to the behaviour of Li, the abundances of Be (77-134 ng/g) are similar in all textural types of clinopyroxene. Olivine porphyroclasts and neoblasts are characterised by somewhat elevated Li contents (0.95-1.79 µg/g), typical of fertile lherzolites. All textural types of clinopyroxene in the Alpe Arami peridotite are enriched in Li, providing evidence for infiltration of Li-rich and Be-poor aqueous solutions after the peak of UHP metamorphism. The lack of Li enrichment in orthopyroxene is consistent with orthopyroxene dissolution and formation of secondary olivine and clinopyroxene during metasomatism. Cr-diopside pyroxenite veins and boudins within the peridotite show low abundances of Li, with 0.7-2.5 µg/g in clinopyroxene and 1.1-1.5 µg/g in olivine. These pyroxenites likely represent precipitates from aqueous solutions which infiltrated the host peridotite after Li enrichment of the peridotite. A slab-derived nature of the metasomatic agent is suggested by the general lack of Ti enrichment in the Alpe Arami rocks.  相似文献   
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