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A precise, accurate and rapid method for the sequential determination of FeO and Fe2O3 in rocks, soils and some non‐refractory minerals by 1,10‐phenanthroline spectrophotometry is described. Fe(II) and Fe(III) were leached from the sample (?200 mesh) using a mixture of NH4HF2 and H2SO4 at 40–80 °C for 10 min on a hot plate. Both Fe(II) and Fe(III) could be conveniently estimated sequentially from the same reaction mixture at the μg g?1 to percentage level. The method is better than the existing wet chemical methods, including the commonly used Pratt's titrimetric redox method, for Fe(II) and Fe(III) determinations in rock and soil samples in terms of precision, accuracy and rapidity. The throughput of the method was very high; at least forty to fifty samples could be estimated easily in a day. The results obtained compare favourably with those obtained by Pratt's method, as well as for certified/recommended values of a set of eleven certified reference materials having FeO and Fe2O3 contents in the range 0.21–14.63% and 0.58–8.48%, respectively. The optimised 1,10 phenanthroline method was found to be accurate to within 0.21% m/m FeO and 0.30% m/m Fe2O3 compared with the literature values of the certified reference materials studied.  相似文献   
3.
ABSTRACT

Urban areas presently consume around 75% of global primary energy supply, which is expected to significantly increase in the future due to urban growth. Having sustainable, universal energy access is a pressing challenge for most parts of the globe. Understanding urban energy consumption patterns may help to address the challenges to urban sustainability and energy security. However, urban energy analyses are severely limited by the lack of urban energy data. Such datasets are virtually non-existent for the developing countries. As per current projections, most of the new urban growth is bound to occur in these data-starved regions. Hence, there is an urgent need of research methods for monitoring and quantifying urban energy utilization patterns. Here, we apply a data-driven approach to characterize urban settlements based on their formality, which is then used to assess intra-urban urban energy consumption in Johannesburg, South Africa; Sana’a, Yemen; and Ndola, Zambia. Electricity is the fastest growing energy fuel. By analyzing the relationship between the settlement types and the corresponding nighttime light emission, a proxy of electricity consumption, we assess the differential electricity consumption patterns. Our study presents a simple and scalable solution to fill the present data void to understand intra-city electricity consumption patterns.  相似文献   
4.
We introduce a multipolar scheme for describing the structure of stationary, axisymmetric, force-free black hole magnetospheres in the '3+1' formalism. We focus here on Schwarzschild spacetime, giving a complete classification of the separable solutions of the stream equation. We show a transparent term-by-term analogy of our solutions with the familiar multipoles of flat-space electrodynamics. We discuss electrodynamic processes around disc-fed black holes in which our solutions find natural applications: (i) 'interior' solutions in studies of the BlandfordZnajek process of extracting the rotational energy of holes, and of the formation of relativistic jets in active galactic nuclei and 'microquasars'; (ii) 'exterior' solutions in studies of accretion disc dynamos, disc-driven winds and jets. On the strength of existing numerical studies, we argue that the poloidal field structures found here are also expected to hold with good accuracy for rotating black holes, except for the cases of the maximum possible rotation rates. We show that the closed-loop exterior solutions found here are not in contradiction with the MacdonaldThorne theorem, as these solutions, which diverge logarithmically on the horizon of the hole , only apply to those regions that exclude .  相似文献   
5.
Geomagnetism and Aeronomy - Discrete spectra of frequencies at 8, 14, 20, 26, … Hz are generated by electromagnetic emission from lightning sources and can be regarded as excitation of AC...  相似文献   
6.
I review our understanding of the evolution of the spin periods of neutron stars in binary stellar systems, from their birth as fast, spin-powered pulsars, through their middle life as accretion-powered pulsars, upto their recycling or “rebirth” as spin-powered pulsars with relatively low magnetic fields and fast rotation. I discuss how the new-born neutron star is spun down by electromagnetic and “propeller” torques, until accretion of matter from the companion star begins, and the neutron star becomes an accretion-powered X-ray pulsar. Detailed observations of massive radio pulsar binaries like PSR 1259-63 will yield valuable information about this phase of initial spindown. I indicate how the spin of the neutron star then evolves under accretion torques during the subsequent phase as an accretion-powered pulsar. Finally, I describe how the neutron star is spun up to short periods again during the subsequent phase of recycling, with the accompanying reduction in the stellar magnetic field, the origins of which are still not completely understood.  相似文献   
7.
We show that the strong correlation observed between the braking indices (n) and the slowing-down ages (Τ) of pulsars is inconsistent with counteralignment between their rotation and magnetic axes, but that the data on pulsars with positive braking indices is consistent with alignment. Alternatively, slowing-down noise can quantitatively account for the data on all pulsars except the Crab and the Vela, and so for the apparent|n| ∼ Τ2 correlation observed for the older pulsars.  相似文献   
8.
I summarize X-ray diagnostic studies of cosmic star formation history in terms of evolutionary schemes for X-ray binary evolution in normal galaxies with evolving star formation. Deep X-ray imaging studies byChandra andXMM-Newton are now beginning to constrain both the X-ray luminosity evolution of galaxies and the logN- logS diagnostics of the X-ray background. I discuss these in the above context, summarizing current understanding and future prospects.  相似文献   
9.
The morphotectonic features of the Central Indian Ocean Basin (CIOB) provide information regarding the development of the basin. Multibeam mapping of the CIOB reveals presence of abundant isolated seamounts and seamount chains sub-parallel to each other and major fracture zones along 73° E, 79° E and 75°45′ E. Morphological analyses were carried out for 200 seamounts that occur either as isolated edifies or along eight sub-parallel chains. The identified eight parallel seamount chains that trend almost north–south and reflecting the absolute motion of the Indian plate, probably originated from the ancient propagative fractures. Inspite of the differences in their height, the seamounts of these eight chains are morphologically correlatable. In the study area the seamounts are clustered north and south of 12° S latitude. Interestingly, in the area north of 12° S (area II: 9°–12° S) the seamounts are distinctly smaller (≤ 400 m height) whereas, the area south of 12° S (area I: 12°–15° S) has a mixed population of seamounts. The normalized abundance of the CIOB seamount is 976 seamounts/106 km2 but on a finer scale this value varies from 500 to 1600 seamounts/106 km2, which is less than the seamount concentrations of the Pacific and Atlantic oceans (9000 to 16,000 seamounts/106 km2). Three categories of seamounts are present in the CIOB e.g. (1) single-peaked (2) multi-peaked and (3) composite. The study indicate that single-peaked seamounts are dominant (89%) while multi-peaked is less (8%) and composite ones are rare (3%) in the CIOB.The progressive northward movement of the Indian continent caused collision between India and Asia at around 62 Ma ago. A majority of the near-axis originated seamounts in the CIOB seemed to have formed as a consequence of the temporally widespread (Cretaceous  65 Ma to late Eocene < 49 Ma) collision between India and Eurasia. The regional stress patterns in the Indian plate vary N to NE in the continent and N to NW in Indian Ocean areas. The combined effect of the regional stress patterns maintained the orientation of the seamount chains and the local stress regime helped in the upwelling of magma and formation of seamounts. The low heat flow, morphological features and geochemical signature indicate that the morphotectonic structures formed contemporaneously with the oceanic crust.  相似文献   
10.
Considerations of the collision losses for protons traversing the 2.7-K blackbody microwave radiation field have led to the conclusion that the highest energy cosmic rays, those observed at ≥1020 eV, must come from sources within the present epoch. In light of this constraint, it is here suggested that these particles may be accelerated near the event horizons of spinning supermassive black holes associated with presently inactive quasar remnants. The required emf is generated by the black hole induced rotation of externally supplied magnetic field lines threading the horizon. Producing the observed flux of the highest energy cosmic rays would constitute a negligible drain on the black hole dynamo. Observations with upcoming air shower arrays and space missions may lead to the identification of candidate dormant galaxies that harbour such black holes. Although the highest energy events observed so far are accounted for within the context of this scenario, a spectral upper bound at ∼1021 eV is expected since the acceleration to higher energies appears to be precluded, on general grounds.  相似文献   
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