The Varre-Sai chondrite,a Brazilian fall: petrology and geochemistry     

Caio Vinícius Gabrig Turbay Rangel  Marcos Tadeu D’Azeredo Orlando  Cláudio De Morisson Valeriano  Alexandre de Oliveira Chaves 《International Geology Review》2017,59(15):1966-1973

The Varre-Sai meteorite fell along the border of the states of Espirito Santo and Rio de Janeiro, Brazil; on 19 June 2010 at 5:40 pm. Petrography and X-ray powder diffraction (XRD) indicate that the rock is an L5 S4 chondrite, with blastoporphyritic texture that has not been previously described. Geochemical data based on major and rare-earth elements (REEs) show that Varre-Sai is highly similar to the other L chondrites. In Harker diagrams, Varre-Sai, L, and LL chondrites form a single group, suggesting no significant chemical differences between them and contributing to the long-standing debate of whether LL chondrites form a distinct group or whether they are a subset of the L group. Harker diagrams also define a trend from E to H and L/LL chondrites, similar to the cosmochemical trends suggested by other authors. The behaviour of Fe₂O_3t and NiO indicates a relationship with Fe-Ni alloys, and their trend in the diagram suggests some chemical differentiation in the ordinary chondrite parental bodies. The REE content in Varre-Sai, normalized to C chondrites, falls in the field of L chondrites and others, but with slight REE enrichment. The chemical differences in chondrites, mainly in REEs, Fe₂O_3t and NiO could be alternatively interpreted as variations in the inherited agglutinated materials as chondrules, Ca–Al-rich inclusions and Fe–Ni nodules.  相似文献   

Towards a predictive model to assess the natural position of the Posidonia oceanica seagrass meadows upper limit     

Matteo Vacchi  Monica Montefalcone  Chiara F. Schiaffino  Valeriano Parravicini  Carlo Nike Bianchi  Carla Morri  Marco Ferrari 《Marine pollution bulletin》2014

The upper portion of the meadows of the protected Mediterranean seagrass Posidonia oceanica occurs in the region of the seafloor mostly affected by surf-related effects. Evaluation of its status is part of monitoring programs, but proper conclusions are difficult to draw due to the lack of definite reference conditions. Comparing the position of the meadow upper limit with the beach morphodynamics (i.e. the distinctive type of beach produced by topography and wave climate) provided evidence that the natural landwards extension of meadows can be predicted. An innovative model was therefore developed in order to locate the region of the seafloor where the meadow upper limit should lie in natural conditions (i.e. those governed only by hydrodynamics, in absence of significant anthropogenic impact). This predictive model was validated in additional sites, which showed perfect agreement between predictions and observations. This makes the model a valuable tool for coastal management.  相似文献   

Implementation of the European Water Framework Directive: Natural variability associated with the CARLIT method on the rocky shores of the Ligurian Sea (Italy)     

Valentina Asnaghi  Mariachiara Chiantore  Rosa‐Maria Bertolotto  Valeriano Parravicini  Riccardo Cattaneo‐Vietti  Federico Gaino  Paolo Moretto  Davide Privitera  Luisa Mangialajo 《Marine Ecology》2009,30(4):505-513

The Water Framework Directive (WFD) 2000/60/EC, adopted by the European Community in 2000 with the goal of maintaining and improving the aquatic environments, requires that member states achieve and maintain a good ecological status of all water bodies by 2015. In the marine context, the ecological status has to be quantified applying indexes based on appropriate key biological elements, which allow the categorization of water bodies into five Ecological Status (ES) classes. The CARLIT index is a cartographic monitoring tool enabling the Ecological Quality Ratio (EQR) to be calculated using macroalgae in coastal hard bottoms as a key biological element; at present it is being applied in Spain, France and Italy. To detect actual changes of water quality and, consequently, rely on the application of indexes for the assessment of the ecological status in the marine environment, it is necessary to evaluate their sensitivity to natural variability at different temporal and spatial scales. In this study we present a first quantification of natural (spatial and temporal) variability of EQR‐CARLIT quality assessment in 2006 and 2007 along the Ligurian coast (North‐Western Mediterranean, Italy). The EQR‐CARLIT values recorded along the Ligurian coastline show that natural variability of EQR‐CARLIT is low and that it does not affect the attribution of a given stretch of coast to a particular ES class, in agreement with the major human pressures acting in the area (urbanization, river load, sea‐farming). A small‐scale variability was detected, strengthening the use of cartography of the whole rocky shore, whenever possible, or, alternatively, the assessment of the ecological status for long stretches of coast, to encompass the small‐scale variability due to local factors.  相似文献   

K–Ar and Ar/Ar ages of dikes emplaced in the onshore basement of the Santos Basin, Resende area, SE Brazil: implications for the south Atlantic opening and Tertiary reactivation     

Eliane Guedes  Monica Heilbron  Paulo M. Vasconcelos  Cludio de Morisson Valeriano  Júlio Csar Horta de Almeida  Wilson Teixeira  Antonio Thomaz Filho 《Journal of South American Earth Sciences》2005,18(3-4):371-382

New K–Ar and ⁴⁰Ar/³⁹Ar data of tholeiitic and alkaline dike swarms from the onshore basement of the Santos Basin (SE Brazil) reveal Mesozoic and Tertiary magmatic pulses. The tholeiitic rocks (basalt, dolerite, and microgabbro) display high TiO₂ contents (average 3.65 wt%) and comprise two magmatic groups. The NW-oriented samples of Group A have (La/Yb)_N ratios between 15 and 32.3 and range in age from 192.9±2.2 to 160.9±1.9 Ma. The NNW-NNE Group B samples, with (La/Yb)_N ratios between 7 and 16, range from 148.3±3 to 133.9±0.5 Ma. The alkaline rocks (syenite, trachyte, phonolite, alkaline basalts, and lamprophyre) display intermediate–K contents and comprise dikes, plugs, and stocks. Ages of approximately 82 Ma were obtained for the lamprophyre dikes, 70 Ma for the syenite plutons, and 64–59 Ma for felsic dikes. Because Jurassic–Early Cretaceous basic dikes have not been reported in SE Brazil, we might speculate that, during the emplacement of Group A dikes, extensional stresses were active in the region before the opening of the south Atlantic Ocean and coeval with the Karoo magmatism described in South Africa. Group B dikes yield ages compatible with those obtained for Serra Geral and Ponta Grossa magmatism in the Paraná Basin and are directly related to the breakup of western Gondwana. Alkaline magmatism is associated with several tectonic episodes that postdate the opening of the Atlantic Ocean and related to the upwelling of the Trindade plume and the generation of Tertiary basins southeast of Brazil. In the studied region, alkaline magmatism can be subdivided in two episodes: the first one represented by lamprophyre dykes of approximately 82 Ma and the second comprised of felsic alkaline stocks of approximately 70 Ma and associated dikes ranging from 64 to 59 Ma.

Resumo

Novos dados K–Ar e ⁴⁰Ar/³⁹Ar de enxames de diques toleíticos e alcalinos localizados no embasamento onshore da Bacia de Santos (SE Brasil) apontam para diferentes pulsos magmáticos ocorridos entre o Jurássico e o Terciário. Os diques de rochas toleíticas (basalto, diabásio e microgabro), são mais velhos, exibem altos teores de TiO₂ (3,65% peso na média) e podem ser subdivididos em dois grupos magmáticos. O Grupo A aflora a norte da Bacia de Resende, compreende diques orientados na direção NW, com razões (La/Yb)_N entre 15 e 32,3, e idades entre 192.9±2.2 e 160.9±1.9 Ma. O Grupo B aflora a sul e a leste da Bacia de Resende, engloba diques orientados na direção NNW e NNE, com razões (La/Yb)_N entre 7 e 16, e idades obtidas entre 148.3±3 e 133.9±0.5 Ma. As rochas alcalinas (sienito, traquito, fonolito, basalto alcalino e lamprófiro) possuem teores médios de K, e afloram como diques, plugs e stocks.. As idades obtidas são de ca. 82 Ma para os diques lamprofíricos, de ca. 70 Ma para os plugs sieníticos, e entre 64 e 59 Ma para os diques félsicos. Como estas idades Jurássicas para diques toleíticos ainda não foram descritas para a região sudeste do Brasil, pode-se especular que durante o emplacement dos diques do GrupoA o cenário tectônico indicaria esforços extensionais anteriores à abertura do Oceano atlântico Sul, e contemporânea ao derrame basáltico do Karoo na África do Sul. Já os diques do Grupo B são contemporâneos ao magmatismo Serra Geral e ao enxame de diques de Ponta Grossa, e portanto este episódio está diretamente relacionado à separação entre o Brasil e África no Cretáceo. O magmatismo alcalino está associado a diversos episódios tectônicos que sucedem à abertura do Oceano Atlântico Sul e que resultaram no desenvolvimento das Bacias terciárias do sudeste brasileiro. Está provavelmente relacionado à chegada da Pluma de Trindade e as idades obtidas para a região em estudo indicam que o magmatismo lamprofírico é mais antigo (ca. 82 Ma), seguido pelos plútons sieníticos (ca. 70 Ma) e diques associados (64 a 59 Ma.)  相似文献   

U–Pb geochronology of the southern Brasília belt (SE-Brazil): sedimentary provenance, Neoproterozoic orogeny and assembly of West Gondwana     

Claudio M. Valeriano  Nuno Machado  Antonio Simonetti  Claudia S. Valladares  Hildor J. Seer  Luiz Sergio A. Simes 《Precambrian Research》2004,130(1-4):27-55

The Brasília belt borders the western margin of the São Francisco Craton and records the history of ocean opening and closing related to the formation of West Gondwana. This study reports new U–Pb data from the southern sector of the belt in order to provide temporal limits for the deposition and ages of provenance of sediments accumulated in passive margin successions around the south and southwestern margins of the São Francisco Craton, and date the orogenic events leading to the amalgamation of West Gondwana.Ages of detrital zircons (by ID–TIMS and LA-MC-ICPMS) were obtained from metasedimentary units of the passive margin of the São Francisco Craton from the main tectonic domains of the belt: the internal allochthons (Araxá Group in the Áraxá and Passos Nappes), the external allochthons (Canastra Group, Serra da Boa Esperança Metasedimentary Sequence and Andrelândia Group) and the autochthonous or Cratonic Domain (Andrelândia Group). The patterns of provenance ages for these units are uniform and are characterised as follows: Archean–Paleoproterozoic ages (3.4–3.3, 3.1–2.7, and 2.5–2.4 Ga); Paleoproterozoic ages attributed to the Transamazonian event (2.3–1.9 Ga, with a peak at ca. 2.15 Ga) and to the ca. 1.75 Ga Espinhaço rifting of the São Francisco Craton; ages between 1.6 and 1.2 Ga, with a peak at 1.3 Ga, revealing an unexpected variety of Mesoproterozoic sources, still undetected in the São Francisco Craton; and ages between 0.9 and 1.0 Ga related to the rifting event that led to the individualisation of the São Francisco paleo-continent and formation of its passive margins. An amphibolite intercalation in the Araxá Group yields a rutile age of ca. 0.9 Ga and documents the occurrence of mafic magmatism coeval with sedimentation in the marginal basin.Detrital zircons from the autochthonous and parautochthonous Andrelândia Group, deposited on the southern margin of the São Francisco Craton, yielded a provenance pattern similar to that of the allochthonous units. This result implies that 1.6–1.2 Ga source rocks must be present in the São Francisco Craton. They could be located either in the cratonic area, which is mostly covered by the Neoproterozoic epicontinental deposits of the Bambuí Group, or in the outer paleo-continental margin, buried under the allochthonous units of the Brasília belt.Crustal melting and generation of syntectonic crustal granites and migmatisation at ca. 630 Ma mark the orogenic event that started with westward subduction of the São Francisco plate and ended with continental collision against the Paraná block (and Goiás terrane). Continuing collision led to the exhumation and cooling of the Araxá and Passos metamorphic nappes, as indicated by monazite ages of ca. 605 Ma and mark the final stages of tectonometamorphic activity in the southern Brasília belt.Whilst continent–continent collision was proceeding on the western margin of the São Francisco Craton along the southern Brasília belt, eastward subduction in the East was generating the 634–599 Ma Rio Negro magmatic arc which collided with the eastern São Francisco margin at 595–560 Ma, much later than in the Brasília belt. Thus, the tectonic effects of the Ribeira belt reached the southernmost sector of the Brasília belt creating a zone of superposition. The thermal front of this event affected the proximal Andrelândia Group at ca. 588 Ma, as indicated by monazite age.The participation of the Amazonian craton in the assembly of western Gondwana occurred at 545–500 Ma in the Paraguay belt and ca. 500 Ma in the Araguaia belt. This, together with the results presented in this work lead to the conclusion that the collision between the Paraná block and Goiás terrane with the São Francisco Craton along the Brasília belt preceded the accretion of the Amazonian craton by 50–100 million years.  相似文献   

Size matters more than method: Visual quadrats vs photography in measuring human impact on Mediterranean rocky reef communities     

Valeriano Parravicini  Carla Morri  Giada Ciribilli  Monica Montefalcone  Giancarlo Albertelli  Carlo Nike Bianchi 《Estuarine, Coastal and Shelf Science》2009,81(3):359-367

The performances of two commonly used non-destructive sampling procedures for rocky benthic assemblages (i.e. photography and visually assessed quadrats) were compared. A damaging human activity, date mussel (Lithophaga lithophaga) harvesting (DMH), was chosen. Directly impacted sites were compared with reference conditions (controls). Both visual quadrats and photography were equally able to detect differences between impacted situations and controls. However, visual quadrats showed high variability among replicates and estimated higher species richness for controls, while photography did so for impacts. Pooling photos in a ‘sum photo quadrat’ showed that differences between the two methods are due to sampling unit size rather than sampling procedure itself. As a small sampling unit is unavoidable with photography, visual quadrats should be preferred in investigating shallow rocky reefs for their larger size; however, longer working time underwater with quadrats does not allow for numerous replicates. Pooling many photos to reach sampling sizes comparable with those of quadrats may be a valid alternative to reconcile image resolution and areal coverage.  相似文献   

Zooplanktonic Communities of the Divergence Zone in the Northwestern Alboran Sea     

Jaime  Rodríguez  Alberto  García Valeriano  Rodriguez 《Marine Ecology》1982,3(2):133-142

Abstract. Using principal component analysis, the zooplanktonic communities of the divergence zone in the northwestern sector of the Alboran Sea were studied. The study was based on 35 vertical trawls in the 200 metres superficial level. The two first components account for 65 % of the total variance. The first component is a contrast between a warm water coastal community (characterized by low specific diversity and the abundance of Cladocera and Copepoda such as Acartia clausi, Centropages chierchiae and Temora stylifera) and a community of cold subsuperficial water distinguished by high specific diversity and a low number of individuals, one of its most characteristic elements being the eggs and larval stages of the Conostomasidae Maurolicus muelleri. The second component appears to be associated with an ecotone between the communities previously cited, and with a specific grouping (Rhincalanus nasutus, Eucalanus monachiis, Pseudocalanus elongatus, Temora longicornis , etc.) resulting from the peripheral displacement of subsuperficial elements brought to the surface by the cyclonic circulation of water masses between the Atlantic current and the Spanish coast.  相似文献   

Consequences of sea water temperature anomalies on a Mediterranean submarine cave ecosystem     

Valeriano Parravicini  Paolo Guidetti  Carla Morri  Monica Montefalcone  Marco Donato  Carlo Nike Bianchi 《Estuarine, Coastal and Shelf Science》2010

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Application of WetSpass model to estimate groundwater recharge variability in the Nile Delta aquifer     

Asaad M. Armanuos  Abdelazim Negm  C. Yoshimura  Oliver C. Saavedra Valeriano 《Arabian Journal of Geosciences》2016,9(10):553

Long-term groundwater recharge from rainfall in the Nile Delta is needed as an input for integrated groundwater modelling in the Nile Delta aquifer for more accurate simulation. The main objective is to estimate the spatial and temporal variation of groundwater recharge from rainfall in the Nile Delta aquifer. Water and Energy Transfer between Soil, Plants and Atmosphere under quasi-Steady State (WetSpass) model parameters were identified for the Nile Delta based on the available meteorological data for the area collected in 1991 and 2000. The collected data were rainfall, temperature, wind speed and evapotranspiration. Geomorphological characteristics, such as soil type, topography, groundwater depth and slope, were also collected as input data for the WetSpass model. ENVI software was used to come up with land use classification based on available land cover images of the Nile Delta for 1972, 1984, 1990, 2000 and 2009. The WetSpass model was calibrated by comparing the simulated groundwater recharge with the calculated one by using the water balance equation model. The results indicated close agreement in groundwater recharge between the two model outputs with R ² of 0.99 and 0.94, while the root-mean-square errors (RMSEs) were 4.86 and 9.39 mm for 1991 and 2000, respectively. The WetSpass model was then applied in respect of 1970, 1980, 1990 and 2010 for the purpose of validation. The overall RMSE and R ² for the 6 years were 8.83 mm and 0.88, respectively. The results of the WetSpass calibrated model provide information to support integrated groundwater modelling. The results reveal that WetSpass works well in simulating the components of the hydrological balance in the Nile Delta.  相似文献   

Is the forward problem of ground water hydrology always well posed?     

Valota G  Giudici M  Parravicini G  Ponzini G  Romano E 《Ground water》2002,40(5):500-508

Complex aquifer systems are often modeled with quasi-three-dimensional models, which consider two-dimensional horizontal flow in the aquifers and one-dimensional vertical flow through aquitards. When the aquifer system consists of a phreatic aquifer and one or more semiconfined aquifers connected by aquitards, the discrete model consists of a nonlinear system of algebraic equations, because the transmissivity of the phreatic aquifer depends on the phreatic head. If the water extraction is very high, the phreatic aquifer can be depleted and the equations of the model must be modified accordingly. There are not simple and general criteria to state if the phreatic aquifer is depleted before solving the system of equations. Therefore, the iterative procedures (e.g., relaxation methods), used to find the solution to the forward problem, must handle these particular conditions and can suffer several problems of convergence. These problems can be caused by the choice of the initial head values or of the relaxation coefficient of the iterative algorithms; however, they can also be caused by the nonexistence or nonuniqueness of the solution to the system of nonlinear equations. The study of existence and uniqueness of the general problem is very difficult and, therefore, we consider a simplified problem, for which the discrete model can be handled analytically. The results of the numerical experiments show that the solution to the forward problem can be nonunique. Only for some cases it is possible to invoke physical arguments to eliminate tentative solutions.  相似文献