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1.
The pore structure characteristics of soil are closely related to soil engineering properties. For saline soil distributed in seasonally frozen areas, existing studies have focused on the influence of freeze–thaw cycles on pore structure, while the influence of soluble salt in the soil is not well understood. This study aims to explore the influence of salt content and salt type on the pore structure of freeze-thawed soil. Soil samples with different salt contents (0–2%) and types (bicarbonate salt and sulfate salt) were subjected to 10 freeze–thaw tests, and their pore size distributions (PSDs) were obtained by mercury intrusion porosimetry tests. In addition, the PSDs were quantitatively analyzed by fractal theory. For both salts, the PSDs of the tested soil samples were bimodal after the freeze–thaw cycles, and the porosity of saline soil samples increased with increasing salt content overall. However, the contents of various types of pores in soil samples with two salt types were quite different. The variation in bicarbonate salt content mainly affected the mesopore and macropore contents in the soil samples, and their change trends were opposite to each other. For soil samples with sulfate salt, the porosity and macropore content increased significantly when the salt content exceeded 1%. In addition, the pore structures in saline soil presented fractal characteristics after the freeze–thaw cycles, and the fractal dimension was positively correlated with macropore content. This study may provide references for understanding the engineering properties of saline soil in seasonally frozen areas at the microscale.  相似文献   
2.
Stochastic Environmental Research and Risk Assessment - In recent years, multiple-point geostatistical (MPS) approaches have gained significant popularity for modeling subsurface heterogeneity in...  相似文献   
3.
The waste produced by coal washing process produces many environmental problems. In this study, the pollution problems associated with the waste produced by Alborz Sharghi Coal Washing Plant was investigated by mathematical modeling. The study area is located at 11 km. to Razmjah coal region and 45 km. to Tehran-Mashhad road in the north part od Iran. To achieve the goal, a few samples were taken from different depths at three points on the waste dump in order to investigate pyrite oxidation and pollution generation. The samples were then analysed, using an AA-670 Shimadzu atomic absorption to determine the fraction of pyrite remained within the waste particles. A numerical finite volume model using Phoenics package has been developed to simulate pyrite oxidation and pollution generation from the Alborz Sharghi coal washing waste dump. The pyrite oxidation reaction is described by the shrinking-core model. Gaseous diffusion is the main mechanism for the transport of oxygen through the waste. The results of numerical modelling were compared with the field observations and close agreement was achieved. A simple mathematical model incorporating advection and hydrodynamic dispersion processes was also presented in order to verify the results of geophysical time-laps method showing transportation of the pollutants through the downstream of the waste dump. Both mathematical model and geophysical time-laps method are agreed in the identification of pollutant transport emanated from the waste dump. The results of such investigations can be used for designing an effective environmental management program.  相似文献   
4.
In this paper, an abandoned waste coal pile, which is resulted from Alborz-Sharghi coal washing plant, NE of Iran was mineralogically and geochemically characterized to evaluate pyrite oxidation, acid mine drainage (AMD) generation, and trace element mobility. After digging ten trenches and vertical sampling, a quantitative method including the atomic absorption test, and the quality-based methods including optical study were carried out for determination of pyrite fractions in the waste pile. The geochemical results revealed that the fraction of remaining pyrite increased with depth, indicating that pyrite oxidation is limited to the shallower depths of the pile which were confirmed by variations of sulfate, pH, EC, and carbonate with depth of the pile. To evaluate the trend of trace elements and mineralogical constituents of the waste particles, the samples were analyzed by using XRD, ICP-MS, and ICP-OES methods. The results showed the secondary and neutralizing minerals comprising gypsum have been formed below the oxidation zone. Besides, positive values of net neutralization potential indicated that AMD generation has not taken in the waste pile. In addition, variations of trace elements with depth reveal that Pb and Zn exhibited increasing trends from pile surface toward the bottom sampling trenches while another of them such as Cu and Ni had decreasing trends with increasing depth of the waste pile.  相似文献   
5.
A simple one-dimensional analytical solution is presented to model oxygen diffusion through the pore space of mine spoils containing pyrite. The model incorporates volumetric oxygen consumption terms due to pyrite oxidation, oxidation of Fe 2+ to Fe 3+ and bacterial activity. Based on this analytical solution, a graphical user interface (GUI) tool is programmed and designed in MATLAB software. This tool can be used to model transport of oxygen through the mine spoils either with or without a cap. Results of several simulation scenarios of sensitivity analysis showed a significant change in oxygen concentration with varying effective diffusion coefficient of oxygen transport model and simulation time. Efficiency and flexibility of the tool developed here is verified by modelling oxygen transport through the pore space of a coal waste pile (case A) and a copper mine tailings (case B). Maximum depth of oxygen diffusion is obtained approximately equal to 2 and 1.5 m through the cases A and B, respectively.  相似文献   
6.
Phenol is one of the aromatic hydrocarbons. Phenol and its derivatives are highly toxic. These pollutants can be observed in the effluents of many industries. This research investigates the removal of phenol by the use of activated sludge in a batch system. The effects of influencing factors on biodegradation efficiency have been evaluated. The main factors considered in this study were the volume of acclimatized activated sludge inoculation, pH, temperature, and initial concentration of phenol. The inoculation volumes of 1, 3, and 5 mL of acclimatized activated sludge were taken into account. Different pH values of 3, 5, 7, 9, and 11 were examined. The experiments were conducted for temperatures of 25, 30, 35, and 40 °C and initial phenol concentrations of 400, 800, 1,000, and 1,500 ppm. The results show that the acclimatized activated sludge has a high capacity for the removal of phenol. From a 100-mL aqueous solution was removed 1,500 ppm of phenol after 80 h. Furthermore, maximum phenol removal was observed for an inoculation volume of 5 mL for three different phenol concentrations of 100, 400, and 800 ppm. The best pH was 7 for the biodegradation process, and the optimum temperature was 30 °C. It was further found that an increase in the phenol concentration increased its removal time. Moreover, the activated sludge could effectively remove about 99.9 % of phenol from a synthetic aqueous solution in a batch system.  相似文献   
7.
Acid mine drainage (AMD) pollution is considered to be the most serious water pollution problem in mining areas. AMD containing iron sulfates and other components can affect the receiving water bodies. Pyrite oxidation and AMD generation can be considered as important processes that may take place in the wastes produced by coal mining and coal washing operations in the Golestan province (northeast Iran). The study area is characterized by appropriate atmospheric conditions that favor pyrite oxidation and the presence of a large amount of water bodies. This study attempts to consider pyrite oxidation and AMD generation in the Azad shahr–Ramian region. The impact of AMD on the quality of the surface water bodies was investigated by taking samples and analyzing them for hydro-geochemical parameters. Stiff and Piper diagrams were used to represent chemical analyses of water samples. The coal samples taken from different depths at four points on two different coal waste dumps were analyzed to find the fraction of pyrite that remained in the waste particles to investigate the pyrite oxidation process. A computational fluid dynamic package called PHOENICS was used to model pyrite oxidation process numerically. The results obtained from the geochemical analyses of water and coal samples and numerical simulation show pyrite oxidation and acid generation in the region. However, the presence of carbonate rocks raised the pH of the water samples. The drainages of the Razi mine may be recognized as natural alkaline mine drainages.  相似文献   
8.
Groundwater and soil pollution from pyrite oxidation, acid mine drainage generation, and release and transport of toxic metals are common environmental problems associated with the mining industry. Nickel is one toxic metal considered to be a key pollutant in some mining setting; to date, its formation mechanism has not yet been fully evaluated. The goals of this study are 1) to describe the process of nickel mobilization in waste dumps by introducing a novel conceptual model, and 2) to predict nickel concentration using two algorithms, namely the support vector machine (SVM) and the general regression neural network (GRNN). The results obtained from this study have shown that considerable amount of nickel concentration can be arrived into the water flow system during the oxidation of pyrite and subsequent Acid Drainage (AMD) generation. It was concluded that pyrite, water, and oxygen are the most important factors for nickel pollution generation while pH condition, SO4, HCO3, TDS, EC, Mg, Fe, Zn, and Cu are measured quantities playing significant role in nickel mobilization. SVM and GRNN have predicted nickel concentration with a high degree of accuracy. Hence, SVM and GRNN can be considered as appropriate tools for environmental risk assessment.  相似文献   
9.
Water is one of the basic and fundamental requirements for the survival of human beings. Mining of the sulphide mines usually produce a significant amount of acid mine drainage (AMD) contributing to huge amounts of chemical components and heavy metals in the receiving waters. Prediction of the heavy metals in the AMD is important in developing any appropriate remediation strategy. This paper attempts to predict heavy metals (Cu, Fe, Mn, Zn) from the AMD using backpropagation neural network (BPNN), general regression neural network (GRNN) and multiple linear regression (MLR), by taking pH, sulphate (SO4) and magnesium (Mg) concentrations in the AMD into account in Shur River, Sarcheshmeh porphyry copper deposit, southeast Iran. The comparison between the predicted concentrations and the measured data resulted in the correlation coefficients, R, 0.92, 0.22, 0.92 and 0.92 for Cu, Fe, Mn and Zn ions using BPNN method. Moreover, the R values were 0.89, 0.37, 0.9 and 0.91 for Cu, Fe, Mn, and Zn taking the GRNN method into consideration. However, the correlation coefficients were low for the results predicted by MLR method (0.83, 0.14, 0.9 and 0.85 for Cu, Fe, Mn and Zn ions, respectively). The results further indicate that the ANN can be used as a viable method to rapidly and cost-effectively predict heavy metals in the AMD. The results obtained from this paper can be considered as an easy and cost-effective method to monitor groundwater and surface water affected by AMD.  相似文献   
10.
This paper presents a two-dimensional finite volume model to predict multi-species reactive transport processes in the saturated zone of a simulated semi-confined aquifer. A multipurpose commercial software called PHOENICS was used to solve model equations numerically. Capability of the present model was first confirmed using experimental data and the results obtained by a published one-dimensional finite element reactive transport model by other researchers taking different scenarios into consideration. The model was then expanded to a two-dimensional case to simulate reactive transport of BTX compounds with discontinuous source in the saturated zone of the groundwater flow system. In addition to the physical transport processes, the two-dimensional model also incorporates linear and nonlinear adsorption isotherms, first order and Monod kinetics. The two-dimensional model considers both static and dynamics modes into account. The results show that considering chemical reactions during reactive transport of contaminants could successfully predict the contaminated zone. The results of such studies can be used for monitoring of contaminated areas, designing methods to control pollution transport, and minimize its harmful effects on aquifer systems.  相似文献   
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