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Nancy L. Chabot Rachel H. Cueva Andrew W. Beck Richard D. Ash 《Meteoritics & planetary science》2020,55(4):726-743
Some of the defining characteristics of the IIG iron meteorite group are their high bulk P contents and massive, coarse schreibersite, which have been calculated to make up roughly 11–14 wt% of each specimen. In this study, we produced two data sets to investigate the formation of schreibersites in IIG irons: measurements of trace elements in the IIG iron meteorite Twannberg and experimental determinations of trace element partitioning into schreibersite. The schreibersite‐bearing experiments were conducted with schreibersite in equilibrium with a P‐rich melt and with bulk Ni contents ranging from 0 to 40 wt%. The partitioning behavior for the 20 elements measured in this study did not vary with Ni content. Comparison of the Twannberg measurements with the experimental results required a correction factor to account for the fact that the experiments were conducted in a simplified system that did not contain a solid metal phase. Previously determined solid metal/P‐rich melt partition coefficients were applied to infer schreibersite/solid metal partitioning behavior from the experiments, and once this correction was applied, the two data sets showed broad similarities between the schreibersite/solid metal distribution of elements. However, there were also differences noted, in particular between the Ni and P contents of the solid metal relative to the schreibersite inferred from the experiments compared to that measured in the Twannberg sample. These differences support previous interpretations that subsolidus schreibersite evolution has strongly influenced the Ni and P content now present in the solid metal phase of IIG irons. Quantitative attempts to match the IIG solid metal composition to that of late‐stage IIAB irons through subsolidus schreibersite growth were not successful, but qualitatively, this study corroborates the striking similarities between the IIAB and IIG groups, which are highly suggestive of a possible genetic link between the groups as has been previously proposed. 相似文献
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Evidence for high‐temperature fractionation of lithium isotopes during differentiation of the Moon 
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下载免费PDF全文 James M. D. Day Lin Qiu Richard D. Ash William F. McDonough Fang‐Zhen Teng Roberta L. Rudnick Lawrence A. Taylor 《Meteoritics & planetary science》2016,51(6):1046-1062
Lithium isotope and abundance data are reported for Apollo 15 and 17 mare basalts and the LaPaz low‐Ti mare basalt meteorites, along with lithium isotope data for carbonaceous, ordinary, and enstatite chondrites, and chondrules from the Allende CV3 meteorite. Apollo 15 low‐Ti mare basalts have lower Li contents and lower δ7Li (3.8 ± 1.2‰; all uncertainties are 2 standard deviations) than Apollo 17 high‐Ti mare basalts (δ7Li = 5.2 ± 1.2‰), with evolved LaPaz mare basalts having high Li contents, but similar low δ7Li (3.7 ± 0.5‰) to Apollo 15 mare basalts. In low‐Ti mare basalt 15555, the highest concentrations of Li occur in late‐stage tridymite (>20 ppm) and plagioclase (11 ± 3 ppm), with olivine (6.1 ± 3.8 ppm), pyroxene (4.2 ± 1.6 ppm), and ilmenite (0.8 ± 0.7 ppm) having lower Li concentrations. Values of δ7Li in low‐ and high‐Ti mare basalt sources broadly correlate negatively with 18O/16O and positively with 56Fe/54Fe (low‐Ti: δ7Li ≤4‰; δ56Fe ≤0.04‰; δ18O ≥5.7‰; high‐Ti: δ7Li >6‰; δ56Fe >0.18‰; δ18O <5.4‰). Lithium does not appear to have acted as a volatile element during planetary formation, with subequal Li contents in mare basalts compared with terrestrial, martian, or vestan basaltic rocks. Observed Li isotopic fractionations in mare basalts can potentially be explained through large‐degree, high‐temperature igneous differentiation of their source regions. Progressive magma ocean crystallization led to enrichment in Li and δ7Li in late‐stage liquids, probably as a consequence of preferential retention of 7Li and Li in the melt relative to crystallizing solids. Lithium isotopic fractionation has not been observed during extensive differentiation in terrestrial magmatic systems and may only be recognizable during extensive planetary magmatic differentiation under volatile‐poor conditions, as expected for the lunar magma ocean. Our new analyses of chondrites show that they have δ7Li ranging between ?2.5‰ and 4‰. The higher δ7Li in planetary basalts than in the compilation of chondrites (2.1 ± 1.3‰) demonstrates that differentiated planetary basalts are, on average, isotopically heavier than most chondrites. 相似文献
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The reluctance of resource-users to adopt seasonal climate forecasts to enhance resilience to climate variability on the rangelands 总被引：1，自引：0，他引：1
As the impacts of climate-change on resource-dependent industries manifest, there is a commensurate effort to identify and implement strategies to reduce them. Yet, even when useful knowledge and tools exist, there can be poor adoption of adaptation strategies. We examine the reasons behind sub-optimal adoption of seasonal climate forecasts by graziers for managing climate variability. We surveyed 100 graziers in north-east Queensland, Australia and examined the influence of adaptive capacity, resource-dependency and forecast-perception on uptake. Technical perceptions were not important. Strategic skills, environmental awareness and social capital were. Results suggest that social factors (but not technical factors) are significant. These insights are important for adaptation planning and for maximising the resilience of communities and industries dependent on climate-sensitive resources. 相似文献
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Environmental change in grasslands: Assessment using models 总被引：7，自引：0，他引：7
Modeling studies and observed data suggest that plant production, species distribution, disturbance regimes, grassland biome boundaries and secondary production (i.e., animal productivity) could be affected by potential changes in climate and by changes in land use practices. There are many studies in which computer models have been used to assess the impact of climate changes on grassland ecosystems. A global assessment of climate change impacts suggest that some grassland ecosystems will have higher plant production (humid temperate grasslands) while the production of extreme continental steppes (e.g., more arid regions of the temperate grasslands of North America and Eurasia) could be reduced substantially. All of the grassland systems studied are projected to lose soil carbon, with the greatest losses in the extreme continental grassland systems. There are large differences in the projected changes in plant production for some regions, while alterations in soil C are relatively similar over a range of climate change projections drawn from various General Circulation Models (GCM's). The potential impact of climatic change on cattle weight gains is unclear. The results of modeling studies also suggest that the direct impact of increased atmospheric CO2 on photosynthesis and water use in grasslands must be considered since these direct impacts could be as large as those due to climatic changes. In addition to its direct effects on photosynthesis and water use, elevated CO2 concentrations lower N content and reduce digestibility of the forage. 相似文献
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Ash Kumar Rai 《湖泊科学》1998,10(S1):181-201
Harnessing the natural resources is one of the basis of natural economy in developing countries. The wise use of such resources is very important to sustain the balance between immediate benefits and maintenance of the ecosystem. In Phewa, Begnas and Rupa lakes of Pokhara Valley, plankton feeding fish farming in net cage,enclosure and open water stocking is one of the effective example of natural resources utilisation which sustains a number of households in surrounding lakes for economic activities. These lakes are also used for drinking water, hydroelectricity, irrigation and recreation etc. However, the understanding of trophic status of the lakes is very important for long term sustainable use of the lakes in harmony with human activities. Here, we present the trophic status of three lakes of Pokhara Valley and discuss the impacts of human and natural activities on the trophic status of the lake. The study shows that heavy rain fall in the valley during monsoon is one of the strongest natural forces which flush out the accumulated nutrients from the lakes and migrate the eutrophication processes. Recommendations for sustainable use of lake water have also been discussed. 相似文献
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Experimental determination of partitioning in the Fe‐Ni system for applications to modeling meteoritic metals 下载免费PDF全文
下载免费PDF全文 Nancy L. Chabot E. Alex Wollack William F. McDonough Richard D. Ash Sarah A. Saslow 《Meteoritics & planetary science》2017,52(6):1133-1145
Experimental trace element partitioning values are often used to model the chemical evolution of metallic phases in meteorites, but limited experimental data were previously available to constrain the partitioning behavior in the basic Fe‐Ni system. In this study, we conducted experiments that produced equilibrium solid metal and liquid metal phases in the Fe‐Ni system and measured the partition coefficients of 25 elements. The results are in good agreement with values modeled from IVB iron meteorites and with the limited previous experimental data. Additional experiments with low levels of S and P were also conducted to help constrain the partitioning behaviors of elements as a function of these light elements. The new experimental results were used to derive a set of parameterization values for element solid metal–liquid metal partitioning behavior in the Fe‐Ni‐S, Fe‐Ni‐P, and Fe‐Ni‐C ternary systems at 0.1 MPa. The new parameterizations require that the partitioning behaviors in the light‐element–free Fe‐Ni system are those determined experimentally by this study, in contrast to previous parameterizations that allowed this value to be determined as a best‐fit parameter. These new parameterizations, with self‐consistent values for partitioning in the endmember Fe‐Ni system, provide a valuable resource for future studies that model the chemical evolution of metallic phases in meteorites. 相似文献
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C. M. Finlayson J. A. Davis P. A. Gell R. T. Kingsford K. A. Parton 《Aquatic Sciences - Research Across Boundaries》2013,75(1):73-93
The condition of many wetlands across Australia has deteriorated due to increased water regulation and the expansion and intensification of agriculture and increased urban and industrial expansion. Despite this situation, a comprehensive overview of the distribution and condition of wetlands across Australia is not available. Regional analyses exist and several exemplary mapping and monitoring exercises have been maintained to complement the more general information sets. It is expected that global climate change will exacerbate the pressures on inland wetlands, while sea level rises will adversely affect coastal wetlands. It is also expected that the exacerbation of these pressures will increase the potential for near-irreversible changes in the ecological state of some wetlands. Concerted institutional responses to such pressures have in the past proven difficult to sustain, although there is some evidence that a more balanced approach to water use and agriculture is being developed with the provision of increasing funds to purchase water for environmental flows being one example. We identify examples from around Australia that illustrate the impacts on wetlands of long-term climate change from palaeoecological records (south-eastern Australia); water allocation (Murray-Darling Basin); dryland salinisation (south-western Australia); and coastal salinisation (northern Australia). These are provided to illustrate both the extent of change in wetlands and the complexity of differentiating the specific effects of climate change. An appraisal of the main policy responses by government to climate change is provided as a basis for further considering the opportunities for mitigation and adaptation to climate change. 相似文献
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J. D. Gilmour R. D. Ash R. Hutchison J. C. Bridges I. C. Lyon G. Turner 《Meteoritics & planetary science》1995,30(4):405-411
Abstract— Iodine-xenon analyses of chondrules from the Bjurböle L4 and Parnallee LL3.6 meteorites have been made using a continuous wave laser microprobe and the resonance ionisation mass spectrometer RELAX. The excess 129Xe content released from the Bjurböle chondrule is lower than previous stepped-heating studies have found, suggesting that the technique does not completely degas the samples. Nonetheless, clear isochrons were produced, and data for initial 129Xe/130Xe are consistent with earlier work. A correlation is evident in each chondrule between 131Xe* and 128Xe* perhaps indicating a common host-phase for their parent nuclides, a condition possibly fulfilled by a Te- and I-bearing sulfide. The I-Xe system of a Parnallee macrochondrule exhibits no excess 129Xe, possibly as a result of thermal alteration or deformation before accumulation of the meteorite. A cristobalite-bearing chondrule depleted in 16O yields an I-Xe age of 4.5 ± 0.5 Ma after the mean Bjurböle age. 相似文献
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