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HANS PIRLET LAURA M. WEHRMANN BENJAMIN BRUNNER NORBERT FRANK JAN DEWANCKELE DAVID VAN ROOIJ ANNELEEN FOUBERT RUDY SWENNEN LIEVEN NAUDTS MATTHIEU BOONE VEERLE CNUDDE JEAN‐PIERRE HENRIET 《Sedimentology》2010,57(3):786-805
Authigenic gypsum was found in a gravity core, retrieved from the top of Mound Perseverance, a giant cold‐water coral mound in the Porcupine Basin, off Ireland. The occurrence of gypsum in such an environment is intriguing, because gypsum, a classic evaporitic mineral, is undersaturated with respect to sea water. Sedimentological, petrographic and isotopic evidence point to diagenetic formation of the gypsum, tied to oxidation of sedimentary sulphide minerals (i.e. pyrite). This oxidation is attributed to a phase of increased bottom currents which caused erosion and enhanced inflow of oxidizing fluids into the mound sediments. The oxidation of pyrite produced acidity, causing carbonate dissolution and subsequently leading to pore‐water oversaturation with respect to gypsum and dolomite. Calculations based on the isotopic compositions of gypsum and pyrite reveal that between 21·6% and 28·6% of the sulphate incorporated into the gypsum derived from pyrite oxidation. The dissolution of carbonate increased the porosity in the affected sediment layer but promoted lithification of the sediments at the sediment‐water interface. Thus, authigenic gypsum can serve as a signature for diagenetic oxidation events in carbonate‐rich sediments. These observations demonstrate that fluid flow, steered by environmental factors, has an important effect on the diagenesis of coral mounds. 相似文献
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PAUL BENJAMIN CRILLY Department of Electrical Computer Engineering Knoxville TN - U.S.A. 《地理学报(英文版)》1990,(1)
In previous papers Jansson's method was found to be successful at deconvolving severely overlapped gaschromatographic peaks.In the most recent paper the method was evaluated with respect to quantitativeaceuracy,peak area and retention time repeatability.The problems associated with deconvolving noisydata and some alternatives which can improve the ability of Jansson's method to deconvolve noisy dataare discussed.These alternatives include presmoothing the data with a nine-point,third-order polynomialfilter and data reblurring.This paper will test these methods on peaks with various degrees of resolutionand signal-to-noise ratios. 相似文献
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HOLTZMAN BENJAMIN K.; KOHLSTEDT DAVID L.; MORGAN JASON PHIPPS 《Journal of Petrology》2005,46(12):2569-2592
We develop a steady-state fluid-mechanical analysis describingthe effect of strain partitioning on viscous energy dissipation.As observed in experimental studies of shear deformation ofpartially molten rocks, strain partitions when melt segregatesbecause viscosity is reduced in regions of elevated melt fraction.The equations derived here are based on parameters measuredin experiments, describing the evolution of melt distributionand rheological properties. We find that the dissipation dependsstrongly on the configuration of the melt-rich network of shearzones, including the average angle, volume fraction of meltand amplification of strain rate in the melt-rich bands. Minimain energy dissipation as a function of band angle develop, correspondingto configurations of melt networks that minimize the differencein mean stress between the band and the non-band regions. Wepropose that the organization of band networks occurs by theinterplay between strain localization and viscosity variationsassociated with melt segregation. The band networks maintaina steady-state angle during shear by continuously pumping meltthrough the network. The development of strain partitioningin melt-rich networks will modify the energetics of meltingand melt transport by efficiently extracting melt and reducingeffective viscosity. KEY WORDS: melt transport; rheology; self-organization; strain localization; strain partitioning 相似文献
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The Valanginian is a period of global environmental change as illustrated by sedimentary, palaeontological, geochemical and climatic perturbations. A production crisis in most of the carbonate platforms suggests important changes in palaeoenvironmental conditions. During the same time interval, a major positive excursion in δ13C, the Weissert Event, suggests perturbations of the carbon cycle from the latest Early Valanginian to the Early Hauterivian. In order to better understand the link between these changes, sea‐level fluctuations have been reconstructed in detail from the Middle Berriasian to the earliest Hauterivian. Sections from the Peri‐Vocontian Zone (South‐east France) have been investigated because of the good quality of outcrops on the carbonate platforms, their margins and in the Vocontian Basin. Sections ranging from the most proximal zone (Swiss Jura) to the basin were interpreted in terms of sequence stratigraphy and cyclostratigraphy, and correlated at high resolutions. Using the identified small, medium and large‐scale sequences as well as depositional geometries, sea‐level fluctuations were reconstructed. Two main trends are evidenced during the studied interval: (i) the peak amplitude (magnitude) of the sea‐level fluctuations increased gradually from the Middle Berriasian to the Early Valanginian, and reached a maximum (more than 50 m) from the middle Early Valanginian to the Valanginian/Hauterivian boundary; and (ii) sea‐level variations were quite symmetrical during the Late Berriasian, slightly asymmetrical during the Early Valanginian and strongly asymmetrical (fast sea‐level rise, slow fall) from the latest Early Valanginian to the earliest Hauterivian. Moreover, three orders of sea‐level fluctuations were recognized in the sedimentary rocks of the Peri‐Vocontian Zone. Platform‐basin correlations and cyclostratigraphic interpretations of the basinal sections evidence an astronomical control on the sea‐level variations, mainly by the two eccentricity cycles of 100 and 400 kyr. The increase in the amplitude of the sea‐level fluctuations and their change from symmetrical to asymmetrical can be related to the onset of a major cooling event in the Early Valanginian. Fast transgressions followed by slower regressions would correspond to waxing and waning of high‐latitudinal ice during most of the Valanginian, especially from the latest Early Valanginian to the latest Late Valanginian. Glacio‐eustatic sea‐level fluctuations in tune with the 100 and 400 kyr eccentricity cycles are in agreement with glaciations during the Valanginian. 相似文献