Organic carbon deposition and phosphorus accumulation during Oceanic Anoxic Event 2 in Tarfaya, Morocco     

Haydon P. Mort  Thierry Adatte  Gerta Keller  David Bartels  Karl B. Fllmi  Philipp Steinmann  Zsolt Berner  E.H. Chellai 《Cretaceous Research》2008,29(5-6):1008

With a multi-proxy approach, an attempt was made to constrain productivity and bottom-water redox conditions and their effects on the phosphorus accumulation rate at the Mohammed Plage section on the Tarfaya coast, Morocco, during the Cenomanian-Turonian Anoxic Event (OAE 2). A distinct δ¹³C_org isotope excursion of +2.5‰ occurs close to the top of the section. The unusually abrupt shift of the isotope excursion and disappearance of several planktonic foraminiferal species (e.g. Rotalipora cushmani and Rotalipora greenhornensis) in this level suggests a hiatus of between 40–60 kyrs at the excursion onset. Nevertheless, it was possible to determine both the long-term environmental history as well as the processes that took place immediately prior to and during OAE 2. TOC% values increase gradually from the base of the section to the top (from 2.5% to 10%). This is interpreted as the consequence of a long-term eustatic sea-level rise and subsidence causing the encroachment of less oxic waters into the Tarfaya Basin. Similarly a reduction in the mineralogically constructed ‘detrital index’ can be explained by the decrease in the continental flux of terrigenous material due to a relative sea-level rise. A speciation of phosphorus in the upper part of the section, which spans the start and mid-stages of OAE 2, shows overall higher abundances of P_reactive mass accumulation rates before the isotope excursion onset and lower values during the plateau. Due to the probable short hiatus, the onset of the decrease in phosphorus content relative to the isotope excursion is uncertain, although the excursion plateau already contains lower concentrations. The C_org/P_total and V/Al ratios suggest that this reduction was mostly likely caused by a decrease in the available bottom oxygen content (probably as a result of higher productivity) and a corresponding fall in the phosphorus retention ability of the sediment. Productivity appears to have remained high during the isotope plateau possibly due to a combination of ocean-surface fertilisation via increased aridity (increased K/Al and Ti/Al ratios) and/or higher dissolved inorganic phosphorus content in the water column as a result of the decrease in sediment P retention. The evidence for decreased P-burial has been observed in many other palaeoenvironments during OAE 2. Tarfaya's unique upwelling paleosituation provides strong evidence that the nutrient recycling was a global phenomenon and therefore a critical factor in starting and sustaining OAE 2.  相似文献   

Carbon, sulfur and O₂ across the Permian–Triassic boundary     

Robert A. Berner   《Journal of Geochemical Exploration》2006,88(1-3):416

A model for the carbon and sulfur cycles across the Permian–Triassic boundary has been constructed from carbon and sulfur isotopic data. Results indicate a drop in global organic matter burial, the formation of an anoxic deep ocean, and a large drop in atmospheric oxygen over the time span 270 to 240 Ma. Much of these changes were probably due to a drop in terrestrial productivity and preservation and an increase in global aridity.  相似文献   

Factors useful for predicting future mineral-commodity supply trends     

F.-W. Wellmer  U. Berner 《International Journal of Earth Sciences》1997,86(2):311-321

The analysis of various factors influencing mineral availability documents future short-and long-term mineral-commodity supply trends. The lifetime of reserves, the development of the relative importance of production centres and the forecasting of the depletion of a resource base are mainly geological factors, although the category “reserves”, in contrast to “resources”, is determined by technical and economical aspects. These three factors govern the short-and long-term supply of mineral commodities. The intensity-of-use factors and the growth rate of consumption are variables related to the demand of mineral commodities. They influence the decision of companies for certain commodities as targets for exploration and investment in production centres. Both factors control the short-to medium-term mineral supply. Finally, the lead time to production is a technical variable, although influenced by ore deposit type, and controls short-term mineral availability.  相似文献   

A statistical procedure for the analysis of seismotectonically induced hydrochemical signals: A case study from the Eastern Carpathians, Romania   总被引：3，自引：0，他引：3  

Jens Hartmann  Zsolt Berner  Doris Stüben  Norbert Henze   《Tectonophysics》2005,405(1-4):77-98

Changes in the stress field of an aquifer system induced by seismotectonic activity may change the mixing ratio of groundwaters with different compositions in a well, leading to hydrochemical signals which in principle could be related to discrete earthquake events. Due to the complexity of the interactions and the multitude of involved factors the identification of such relationships is a difficult task. In this study we present an empiric statistical approach suitable to analyse if there is an interdependency between changes in the chemical composition of monitoring wells and the regional seismotectonic activity of a considered area. To allow a rigorous comparison with hydrochemistry the regional earthquake time series was aggregated into an univariate time series. This was realized by expressing each earthquake in form of a parameter “e”, taking into consideration both energetic (magnitude of a seismic event) and spatial parameters (position of epi/hypocentrum relative to the monitoring site). The earthquake and the hydrochemical time-series were synchronised aggregating the e-parameters into “earthquake activity” functions E, which takes into account the time of sampling relative to the earthquakes which occurred in the considered area. For the definition of the aggregation functions a variety of different “e” parameters were considered. The set of earthquake functions E was grouped by means of factor analysis to select a limited number of significant and representative earthquake functions E to be used further on in the relation analysis with the multivariate hydrochemical data set. From the hydrochemical data a restricted number of hydrochemical factors were extracted. Factor scores allow to represent and analyse the variation of the hydrochemical factors as a function of time. Finally, regression analysis was used to detect those hydrochemical factors which significantly correlate with the aggregated earthquake functions.This methodological approach was tested with a hydrochemical data set collected from a deep well monitored for two years in the seismically active Vrancea region, Romania. Three of the hydrochemical factors were found to correlate significantly with the considered earthquake activities. A screening with different time combinations revealed that correlations are strongest when the cumulative seismicity over several weeks was considered. The case study also showed that the character of the interdependency depends sometimes on the geometrical distribution of the earthquake foci. By using aggregated earthquake information it was possible to detect interrelationships which couldn't have been identified by analysing only relations between single geochemical signals and single earthquake events. Further on, the approach allows to determine the influence of different seismotectonic patterns on the hydrochemical composition of the sampled well. The method is suitable to be used as a decision instrument in assessing if a monitoring site is suitable or not to be included in a monitoring net within a complex earthquake prediction strategy.  相似文献   

Aragonite dissolution on the Bermuda pedestal: Its depth and geochemical significance     

Robert A. Berner  Elizabeth K. Berner  Robin S. Keir 《Earth and Planetary Science Letters》1976,30(2):169-178

The depth distribution of pteropod and planktonic foram tests, and fine-grained (<62 μm) aragonite, high-Mg calcite (12 mode mol.% MgCO₃), and low-Mg calcite has been determined for surface sediments of an area of the eastern slope of the Bermuda pedestal. Over the range 1800–3000 m, fine-grained aragonite and fine-grained high-Mg calcite gradually disappear relative to fine-grained low-Mg calcite, and pteropods gradually disappear relative to planktonic forams. This is interpreted as preferential dissolution of aragonite (and high-Mg calcite) relative to low-Mg calcite over this depth range. Coarse aragonitic debris derived from shallow-water organisms living on the Bermuda platform does not show consistent disappearance over the same depth zone. Chemical analyses of bottom water samples taken at the same time as some of the sediment samples indicate that the degree of saturation with respect to aragonite Ω_A over the zone of aragonite disappearance ranges from 0.55 to 0.85; i.e. major dissolution occurs only at Ω_A values distinctly less than one. These results lend credence to the hypothesis that CaCO₃ dissolution in the oceans, both as aragonite and as calcite, takes place mainly as a response to complex chemical kinetic phenomena and not as a result of the simple attainment of undersaturation (thermodynamic hypothesis) or the resuspension of bottom sediment (hydrodynamic hypothesis).  相似文献   

Applying size segregation to relate the surrounding aerosol pollution to its source   总被引：1，自引：0，他引：1  

Irena Grgić  Janja Turšič  Axel Berner 《Journal of Atmospheric Chemistry》2009,63(3):247-257

Size segregated sampling of aerosol particles at the coal-fired power station Šoštanj, Slovenia was performed by a newly developed system. In addition, simultaneous sampling of particles was performed at two locations, Velenje and Veliki vrh, chosen on the basis of long term monitoring of SO₂ in the influential area of power plant. The signature of the power plant (e.g. characteristic size distributions of some typical trace elements) was identified. For elements, like As, Mo, Cd and Ga, which are typical for coal combustion, the highest concentrations were observed in the size range between 1 and 4 μm. For Se and sometimes for Ga two modes were identified, first between 0.1 and 0.5 μm and second between 1 and 4 μm. Ratios between the average concentrations of selected elements in fine and coarse particles collected at Veliki vrh (the most influenced location) and Velenje (usually not influenced by the thermo power station) were significantly higher than 1 in the case of Mo and Se for coarse and fine size range, while for As the ratio was higher than 1 for the coarse fraction. Consequently, Mo, Se and As were found as the most important tracers for the emissions from the investigated source. On the basis of the ratios between the concentrations of elements measured in particles at low and high SO₂ concentrations at Veliki vrh, Cd was shown to be a typical tracer as well. Our results definitely showed that size segregated measurements of particles at the source and in the influenced area give more precise information on the influence of source to the surrounding region. It was found that patterns of size distributions for typical trace elements observed at the source are found also in the influenced area, i.e. Veliki vrh.  相似文献   

High stress late Maastrichtian – early Danian palaeoenvironment in the Neuquén Basin, Argentina     

G. Keller  T. Adatte  A.A. Tantawy  Z. Berner  W. Stinnesbeck  D. Stueben  H.A. Leanza 《Cretaceous Research》2007,28(6):939-960

During the late Maastrichtian to early Danian the Neuquén Basin of Argentina was adjacent to an active volcanic arc to the west and an extensive land area to the northeast. Mineralogical and geochemical studies of the Bajada del Jagüel in the Neuquén Basin indicate a generally warm climate with seasonal changes in humidity and an open seaway to the South Atlantic that maintained marine conditions. Biostratigraphic and quantitative foraminiferal and nannofossil analyses indicate that sediment deposition during the late Maastrichtian (zones CF4-CF2, N. frequens) occurred in relatively shallow middle neritic (100 m) depths with largely dysaerobic bottom waters (abundant low O₂ tolerant benthics) and fluctuating sea level. Calcareous nannofossils indicate a high stress marine environment dominated by Micula decussata. Planktic foraminifera mimic the post-K/T high stress environment with alternating blooms of the disaster opportunists Guembelitria and low oxygen tolerant Heterohelix groups, indicating nutrient-rich surface waters and an oxygen depleted water column. The high stress conditions were probably driven by high nutrient influx due to upwelling and terrestrial and volcanic influx. The K/T boundary is marked by an erosional surface that marks a hiatus at the base of a 15-25 cm thick volcaniclastic sandstone, which contains diverse planktic foraminiferal zone P1c assemblages and nannofossils of zone NP1b immediately above it. This indicates deposition of the sandstone occurred 500 ky after the K/T hiatus. No evidence of the Chicxulub impact or related tsunami deposition was detected.  相似文献   

Barremian–Danian chemostratigraphic sequences of the Cauvery Basin,India: Implications on scales of stratigraphic correlation     

Mu. Ramkumar  D. Stüben  Z. Berner 《Gondwana Research》2011,19(1):291-309

Chemostratigraphic concepts postulate that distinct chemozones could be recognized from rock records to help correlate geographically separated strata. Many studies have upheld this view, but were limited to classic boundaries such as Cenomanian–Turonian or Cretaceous–Tertiary. Only a few elements and isotopic compositions were made use in such studies. An attempt to recognize chemozones of Barremian–Danian strata of the Cauvery Basin, South India through whole-rock chemistry had revealed many complex signals and depositional events as expressed by bulk geochemical profiles. The signals indicate major shift in sedimentation pattern from dynamic depocenter to stable depositional conditions during Santonian. Varying sensitivities of different elements towards prevalent depositional conditions are also inferred. Trends of geochemical composition indicated domination of single depositional control all through the depositional history, basinal configuration that limited terrestrial sediment source and episodic influx of detrital materials. Presence of distinct change in whole-rock geochemistry across geochronological and lithostratigraphic boundaries is deciphered through a statistical tool ANOVA. These results demonstrate that visual delineation of chemozones in a long ranging rock record would be tenuous and has to be exercised with caution.  相似文献   

Geochemical processes underlying a sharp contrast in groundwater arsenic concentrations in a village on the Red River delta,Vietnam   总被引：1，自引：0，他引：1  

Elisabeth Eiche  Thomas Neumann  Michael Berg  Beth Weinman  Alexander van Geen  Stefan Norra  Zsolt Berner  Pham Thi Kim Trang  Pham Hung Viet  Doris Stüben 《Applied Geochemistry》2008

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Coupling Size-Exclusion Chromatography and ICP-MS to Investigate the Speciation of Platinum-Group Elements in Environmental Samples     

Christoph M. Menzel  Zsolt Berner  Doris Stüben 《Geostandards and Geoanalytical Research》2001,25(2-3):239-251

The applicability of size-exclusion chromatography (SEC) coupled online with a high resolution ICP-MS (HR-ICP-MS) to investigate the speciation of the platinum-group elements (PGE), Rh, Pd and Pt, was evaluated. Experiments were carried out to determine the efficiency of different hydrophilic and hydrophobic size-exclusion gel materials to select the optimal eluent in respect of resolution, recovery, reproducibility and limit of detection. The suitability of HR-ICP-MS as a reliable detection instrument at low pg ml⁻¹ levels was investigated by examining possible mass interferences with Rh, Pd and Pt. Laboratory experiments demonstrated the interaction and capability of forming complexes of humic substances with PGE, demonstrating the potential role of these ubiquitous natural substances in the mobilisation of PGE in the environment.  相似文献