Manganese and iron distributions off central California influenced by upwelling and shelf width   总被引：4，自引：1，他引：4  

Zanna Chase  Kenneth S. Johnson  Virginia A. Elrod  Joshua N. Plant  Steve E. Fitzwater  Lisa Pickell  Carol M. Sakamoto 《Marine Chemistry》2005,95(3-4):235-254

In July 2002, a combination of underway mapping and discrete profiles revealed significant along-shore variability in the concentrations of manganese and iron in the vicinity of Monterey Bay, California. Both metals had lower concentrations in surface waters south of Monterey Bay, where the shelf is about 2.5 km wide, than north of Monterey Bay, where the shelf is about 10 km wide. During non-upwelling conditions over the northern broad shelf, dissolvable iron concentrations measured underway in surface waters reached 3.5 nmol L⁻¹ and dissolved manganese reached 25 nmol L⁻¹. In contrast, during non-upwelling conditions over the southern narrow shelf, dissolvable iron concentrations in surface waters were less than 1 nmol L⁻¹ and dissolved manganese concentrations were less than 5 nmol L⁻¹. A pair of vertical profiles at 1000 m water depth collected during an upwelling event showed dissolved manganese concentrations of 10 decreasing to 2 nmol L⁻¹, and dissolvable iron concentrations of 12–20 nmol L⁻¹ in the upper 100 m in the north, compared to 3.5–2 nmol L⁻¹ Mn and 0.6 nmol L⁻¹ Fe in the upper 100 m in the south, suggesting the effect of shelf width influences the chemistry of waters beyond the shelf.These observations are consistent with current understanding of the mechanism of iron supply to coastal upwelling systems: Iron from shelf sediments, predominantly associated with particles greater than 20 μm, is brought to the surface during upwelling conditions. We hypothesize that manganese oxides are brought to the surface with upwelling and are then reduced to dissolved manganese, perhaps by photoreduction, following a lag after upwelling.Greater phytoplankton biomass, primary productivity, and nutrient drawdown were observed over the broad shelf, consistent with the greater supply of iron. Incubation experiments conducted 20 km offshore in both regions, during a period of wind relaxation, confirm the potential of these sites to become limited by iron. There was no additional growth response when copper, manganese or cobalt was added in addition to iron. The growth response of surface water incubated with bottom sediment (4 nmol L⁻¹ dissolvable Fe) was slightly greater than in control incubations, but less than in the presence of 4 nmol L⁻¹ dissolved iron. This may indicate that dissolvable iron is not as bioavailable as dissolved iron, although the influence of additional inhibitory elements in the sediment cannot be ruled out.  相似文献   

Transequatorial loops interconnecting McMath regions 12472 and 12474     

Švestka  Z.  Krieger  A. S.  Chase  R. C.  Howard  R. 《Solar physics》1977,52(1):69-90

We discuss the life-story of a transequatorial loop system which interconnected the newly born active region McMath 12474 with the old region 12472. The loop system was probably born through reconnection accomplished 1.5 to 5 days after the birth of 12474 and the loops were observed in soft X-rays for at least 1.5 days. Transient sharpenings of the interconnection and a striking brightening of the whole loop system for about 6 hr appear to be caused by magnetic field variations in the region 12474. A flare might have been related to the brightening, but only in an indirect way: the same emerging flux could have triggered the flare and at the same time strengthened the magnetic field at the foot-points of the loops. Electron temperature in the loop system, equal to 2.1 × 10⁶ K in its quiet phase, increased to 3.1 × 10⁶ K during the brightening. Electron density in the loop system was 1.3 × 10⁹ cm^–3 and it could be estimated to 7 × 10⁸ cm^–3 prior to the brightening. During the brightening the loops became twisted. There was no obvious effect whatsoever of the activity in 12474 upon the in erconnected old region. The final decay of the loop system reflected the decay of magnetic field in the region 12474.  相似文献   

Changes in Global Monsoon Circulations Since 1950   总被引：6，自引：0，他引：6  

Chase  T. N.  Knaff  J. A.  Pielke  R. A.  Kalnay  E. 《Natural Hazards》2003,29(2):229-254

We examined changes in several independent intensity indices of four majortropical monsoonal circulations for the period 1950–1998. Theseintensity indices included observed land surface precipitation andobserved ocean surface pressure in the monsoon regions aswell as upper-level divergence calculated at severalstandard levels from the NCAR/NCEP reanalysis. These values wereaveraged seasonally over appropriate regions of southeastern Asian, western Africa, eastern Africa and the Australia/Maritime continent and adjacent ocean areas. Asa consistency check we also examined two secondary indices: mean sea level pressure trends and low level convergence both from theNCEP reanalysis.We find that in each of the four regions examined, a consistentpicture emerges indicating significantly diminished monsoonalcirculations over the period of record, evidence of diminished spatialmaxima in the global hydrological cycle since 1950. Trends since 1979,the period of strongest reported surface warming, do not indicate any change inmonsoon circulations. When strong ENSO years are removed from each of the time series the trends still show a general, significant reduction of monsoon intensity indicating that ENSO variability is not the direct cause for the observed weakening.Most previously reported model simulations of theeffects of rising CO₂ show an increase in monsoonal activity withrising global surface temperature. We find no support in these datafor an increasing hydrological cycle or increasing extremes as hypothesized bygreenhouse warming scenarios.  相似文献   

The modern geoid and ancient plate boundaries     

Clement G. Chase  Donald R. Sprowl 《Earth and Planetary Science Letters》1983,62(3):314-320

The non-hydrostatic geoid is dominated by three large anomalies: an area of high gravity potential in the equatorial Pacific; another stretching from Greenland through Africa to the southwest Indian Ocean; and a semi-continuous low region passing from Hudson's Bay through Siberia to India and on to Antarctica. None of these three high-amplitude (greater than 60 m) and long-wavelength anomalies corresponds to present-day plate boundaries. However, if the modern geoid is plotted over the positions of continents and plate boundaries at 125 Ma B.P. (reconstructed relative to hotspots) a strong correlation emerges. The modern geoidal low corresponds in position to the areas of subduction surrounding the Pacific 125 Ma ago. The geoidal high now centered on Africa is entirely contained within ancient Pangaea, and the equatorial Pacific high overlies the location of the spreading centers preserved in the magnetic anomalies of the central Pacific. The most plausible cause of the large geoidal undulations is lower mantle convection only weakly coupled to plate motions. The correspondence between modern geoid and ancient plate boundaries implies either that the coupling was much more intimate in the past, or that there is a lag of at least 100 Ma in response of the lower mantle to upper mantle conditions.  相似文献   

A hydrothermal deposit from explorer ridge in the northeast Pacific Ocean   总被引：1，自引：0，他引：1  

E.V. Grill  R.L. Chase  R.D. MacDonald  J.W. Murray 《Earth and Planetary Science Letters》1981,52(1):142-150

Crusts composed of nontronite and ferromanganese oxides were recovered from Explorer Ridge, a spreading ridge segment in the northeastern Pacific Ocean located off the west coast of Canada. The chemical and mineralogical composition of the crusts closely resembles that of the mound-like hydrothermal deposits recently discovered at the FAMOUS site on the Mid-Atlantic Ridge and on the Galapagos spreading centre. Compositional anomalies suggest that the crusts are precipitates of hydrothermal vent solutions which were ejected discontinuously and subsequently mixed with seawater.  相似文献   

Rank of coal beds of the Narragansett basin,Massachusetts and Rhode Island     

Paul C. Lyons  Harry B. Chase 《International Journal of Coal Geology》1981,1(2):155-168

Coal of the Narragansett basin generally has been considered to be anthracite and/or meta-anthracite. However, no single reliable method has been used to distinguish these two ranks in this basin. Three methods — chemical, X-ray, and petrographic — have been used with some degree of success on coal of the Narragansett basin, but too often the results are in conflict. Chemical methods have been limited by inadequate sampling on a coal-bed-by-coal-bed basis and by a lack of analyses made according to (American Society for Testing and Materials, 1974) standard specifications.In addition, when corrections are made by using the Parr formulas, as required by the ASTM (1974) procedures, the generally high to very high ash content of coal from the Narragansett basin causes the fixed-carbon content to appear higher than it actually is. X-ray methods using the degree of graphitization as a measure of rank are not reliable because some of the graphite is related to shearing and brecciation associated with folding and faulting. Petrographic methods using reflectance on vitrinite give results that are generally consistent with results from chemical determinations. However, it is not clear whether the mean maximum reflectance or mean bireflectance is a better indicator of similar rank of such high-rank coals that have been structurally deformed.Coal from the Cranston Mine, RI, is probably meta-anthracite and coal from the Portsmouth Mine is probably anthracite. These ranks are based on chemical,X-ray, and petrographic data and are supported by associated metamorphic mineral assemblages that indicate that the Cranston Mine is in a higher metamorphic zone than the zone containing the Porthmouth Mine. Interpretation of the rank of Mansfield, MA, coal on the basis of extant chemical data is difficult because it is an impure coal with an ash content of 33 to 50%. Reflectance data indicate that the Mansfield, Foxborough, and Plainville coals in the northern part of the Narragansett basin are meta-anthracite but this is in disagreement with the rank suggested by the low degree of metamorphism of the associated rocks.  相似文献   

Semi‐active tuned mass damper building systems: Application     

Min‐Ho Chey  J. Geoffrey Chase  John B. Mander  Athol J. Carr 《地震工程与结构动力学》2010,39(1):69-89

Seismic performance attributes of multi‐story passive and semi‐active tuned mass damper (PTMD and SATMD) building systems are investigated for 12‐story moment resisting frames modeled as ‘10+2’ stories and ‘8+4’ stories. Segmented upper portion of the stories are isolated as a tuned mass, and a passive viscous damper or semi‐active resetable device is adopted as energy dissipation strategy. The semi‐active approach uses feedback control to alter or manipulate the reaction forces, effectively re‐tuning the system depending on the structural response. Optimum tuned mass damper control parameters and appropriate matching SATMD configurations are adopted from a companion study on a simplified two‐degree‐of‐freedom system. Statistical performance metrics are presented for 30 probabilistically scaled earthquake records from the SAC project. Time history analyses are used to compute response reduction factors across a wide range of seismic hazard intensities. Results show that large SATMD systems can effectively manage seismic response for multi‐degree‐of freedom systems across a broad range of ground motions in comparison to passive solutions. Specific results include the identification of differences in the mechanisms by which SATMD and PTMD systems remove energy, based on the differences in the devices used. Additionally, variability is seen to be tighter for the SATMD systems across the suites of ground motions used, indicating a more robust control system. While the overall efficacy of the concept is shown the major issues, such as isolation layer displacement, are discussed in detail not available in simplified spectral analyses, providing further insight into the dynamics of these issues for these systems. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

Experimental validation of semi‐active resetable actuators in a ⅕th scale test structure     

K. J. Mulligan  J. G. Chase  J. B. Mander  G. W. Rodgers  R. B. Elliott  R. Franco‐Anaya  A. J. Carr 《地震工程与结构动力学》2009,38(4):517-536

The seismic performance of a test structure fitted with semi‐active resetable devices is experimentally investigated. Shaking table tests are conducted on a ?th scale four‐storey building using 27 earthquake records at different intensity scalings. Different resetable device control laws result in unique hysteretic responses from the devices and thus the structure. This device adaptability enables manipulation or sculpting of the overall hysteresis response of the structure to address specific structural cases and types. The response metrics are presented as maximum 3rd floor acceleration and displacement, and the total base shear. The devices reduce all the response metrics compared with the uncontrolled case and a fail‐safe surrogate. Cumulative probability functions allow comparison between different control laws and additionally allow tradeoffs in design to be rapidly assessed. Ease of changing the control law in real‐time during an earthquake record further improves the adaptability of the system to obtain the optimum device response for the input motion and structural type. The findings are an important step to realizing full‐scale structural control with customized semi‐active hysteretic behaviour using these novel resetable device designs. Copyright © 2008 John Wiley & Sons, Ltd.  相似文献   

Simulated impacts of historical land cover changes on global climate in northern winter   总被引：19，自引：2，他引：17  

T. N. Chase  R. A. Pielke Sr.  T. G. F. Kittel  R. R. Nemani  S. W. Running 《Climate Dynamics》2000,16(2-3):93-105

This ten-year general circulation model experiment compared a simulation where land surface boundary conditions were represented by observed, present day land cover to a simulation where the surface was represented by natural, potential land cover conditions. As a result of these estimated changes in historical land cover, significant temperature and hydrology changes affected tropical land surfaces, where some of the largest historical disruptions in total vegetation biomass have occurred. Also of considerable interest because of their broad scope and magnitude were changes in high-latitude Northern Hemisphere winter climate which resulted from changes in tropical convection, upper-level tropical outflow, and the generation of low-frequency tropical waves which propagated to the extratropics. These effects combined to move the Northern Hemisphere zonally averaged westerly jet to higher latitudes, broaden it, and reduce its maximum intensity. Low-level easterlies were also reduced over much of the tropical Pacific basin while positive anomalies in convective precipitation occurred in the central Pacific. Globally averaged changes were small. Comparisons of recent, observed trends in tropical and Northern Hemisphere, mid-latitude climate with these simulations suggests an interaction between the climatic effects of historical land cover changes and other modes of climate variability. Received: 8 September 1998 / Accepted: 31 July 1999  相似文献   

Key Design Elements of Building Pressure Cycling for Evaluating Vapor Intrusion—A Literature Review     

Christopher C. Lutes  Chase W. Holton  Robert Truesdale  John H. Zimmerman  Brian Schumacher 《Ground Water Monitoring & Remediation》2019,39(1):66-72

Building pressure cycling (BPC) is becoming an increasingly important tool for studying vapor intrusion. BPC has been used to distinguish subslab and indoor sources of vapor intrusion as well as to define reasonable worst case volatile organic compound mass discharge into a structure. Analyses have been performed both semi-quantitatively with concentration trends and quantitatively with more rigorous flux calculation and source attribution methods. This paper reviews and compares the protocols and outcomes from multiple published applications of this technology to define the key variables that control performance. Common lessons learned are identified, including those that help define the range of building size and type to which BPC is applicable. Differences in test protocols are discussed, recognizing that the complexity of the test protocol required depends on the particular objectives of each project. Research gaps are identified and tabulated for future validation studies and applications.  相似文献