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1.
Surface-active organic substances (SAS), nutrients, chlorophyll a (Chl a), dissolved oxygen (O2), salinity (S) and temperature (T) were measured approximately monthly in the northern Adriatic Sea (NA) during two years. Results were elaborated for two stations of different trophic status. Exhaustive statistical examinations of measured variables were performed to contribute to better understanding of the processes and interdependence of the measured parameters. The results of those analyses allowed the region to be described based on several groups of data relevant for particular processes. Chl a appear to be independent parameter; orthosilicate, nitrite and ammonium represent the parameter group most relevant for regeneration processes; the second group includes nutrients dominant in freshwater inputs (orthophosphate and nitrate), while in the third group are parameters related to primary production processes (T, O2, organic phosphorus and SAS). Probably due to time lags between nutrient uptake and phytoplankton growth as well as between cells growth/division and SAS release, both, the correlation between nutrients and Chl a and the correlation between Chl a and SAS were not statistically significant. Although significantly higher nutrient and Chl a concentrations were found in the mesotrophic western part of the region in comparison to the oligotrophic eastern part, the SAS concentration differences were less marked. It is assumed that more OM is produced, but also at the same time remineralized, at the mesotrophic western part, leading to higher concentrations of regenerated nutrients there. Presence of different phytoplankton taxa and/or fractions (micro and nano) at the two stations may have also contributed to minimize the difference in SAS contents. Higher SAS acidities were noticed in the mesotrophic than in the oligotrophic part.  相似文献   
2.
We present a new inversion method to estimate, from prestack seismic data, blocky P‐ and S‐wave velocity and density images and the associated sparse reflectivity levels. The method uses the three‐term Aki and Richards approximation to linearise the seismic inversion problem. To this end, we adopt a weighted mixed l2, 1‐norm that promotes structured forms of sparsity, thus leading to blocky solutions in time. In addition, our algorithm incorporates a covariance or scale matrix to simultaneously constrain P‐ and S‐wave velocities and density. This a priori information is obtained by nearby well‐log data. We also include a term containing a low‐frequency background model. The l2, 1 mixed norm leads to a convex objective function that can be minimised using proximal algorithms. In particular, we use the fast iterative shrinkage‐thresholding algorithm. A key advantage of this algorithm is that it only requires matrix–vector multiplications and no direct matrix inversion. The latter makes our algorithm numerically stable, easy to apply, and economical in terms of computational cost. Tests on synthetic and field data show that the proposed method, contrarily to conventional l2‐ or l1‐norm regularised solutions, is able to provide consistent blocky and/or sparse estimators of P‐ and S‐wave velocities and density from a noisy and limited number of observations.  相似文献   
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4.
Compositional control on the annealing kinetics of fission-tracks (FT) in apatite requires routine measurement of sample grain composition. However, for practical reasons the bulk composition of analysed grains is not routinely measured and instead grain chlorine content or etch-pit dimensions are used to characterise a samples annealing behaviour. A more desirable approach is to measure crystallographic parameters (i.e. unit cell dimension) of a grain as these represent the summed effect of all substitutions and crystal defects. We show how Raman microspectrometry can be used as a routine non-destructive tool to obtain rapid measurement of the crystallographic structure of apatite grains etched for FT analysis. Variations of unit cell parameter a are found to correspond to a systematic variation of Raman shift in the range of 452–440 cm− 1 for measurements made on c-parallel sections of apatite where the direction of the polarized incident beam is parallel to the c axis.  相似文献   
5.
This paper deals with ground-hugging, gas–pyroclast currents from explosive volcanic eruptions and their deposits. Key field observations and laboratory determinations are proposed to relate specific deposit types with flow regimes and particle concentration in the transport and depositional systems. Three relevant flow scenarios and corresponding deposit types have been recognized from a survey of pyroclastic successions of the Vulsini Volcanic District (central Italy): (1) dilute, turbulent, pyroclastic currents producing normally or multiply graded beds by direct suspension sedimentation; (2) concentrated bedload regions beneath suspension currents, depositing inversely graded beds by traction carpet sedimentation; (3) self-sustained, high particle concentration, laminar, mass flows developing massive, poorly sorted bodies, with opposite grading of coarse lithic and pumice clasts, overlying fine-grained, inversely graded, basal layers. Main distinguishing criteria include the occurrence and pattern of clast grading, clast–thickness relationships, grain size, ash matrix componentry and pyroclast size–density relationships. Downcurrent and temporal transitions among identified flow scenarios are likely to occur for changing energy conditions and gas–pyroclast ratio both on regional and local scales. The nature and efficiency of magma fragmentation, volatile content, conduit geometry (which determine the characteristics of the erupted mixture and possible lateral blast component at the vent), and the angle of incidence of the column collapse, are suggested as the main factors controlling the generation of one type over the other at flow inception. Dilute, fine-grained, overpressured eruption clouds are thought to favor the formation of low particle concentration turbulent currents. Column collapse over slightly inclined volcano slopes, causing a high degree of compression of the collapsing mixture and of gas expulsion, would favor the generation of high particle concentration pyroclastic currents.  相似文献   
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The shore stranding of mesopelagic fauna is a recurrent phenomenon in the Strait of Messina (Central Mediterranean Sea). The aim of this paper is to test the influence of lunar phases, winds and seasons upon the frequency of occurrence of strandings of mesopelagic fish. Species abundance in relation to these factors was quantified for the first time. Specimens were collected stranded on the shore along the Sicilian coast of the Strait of Messina between 2008 and 2016. Overall 32 species belonging to seven families (Gonostomatidae, Microstomatidae, Myctophidae, Paralepididae, Phosichthyidae, Sternoptychidae, Stomiidae) were found stranded. Myctophidae was the family including the highest number of species (16), whereas Gonostomatidae was the most abundant in terms of total number of individuals (47.2%), mainly thanks to the species Cyclothone braueri. The moon, which influences the strength of currents (highest during full and new moon phases) and irradiance (higher in some lunar phases, such as the full moon), affected the abundance of stranded mesopelagic fish in the study area. The highest number of stranding events was recorded during the new moon: 34.6% of the total relative abundance of stranded mesopelagic fish. Wind blowing from the sea towards the coastline (southeasterly and easterly winds) created the best conditions for strandings. The highest abundance of stranded specimens was recorded during the winter season.  相似文献   
8.
A note on maar eruption energetics: current models and their application   总被引:1,自引:1,他引:0  
Hydromagmatic eruptions convert thermal into mechanical energy via the expansion of ground- and/or surface-water. Several models address the energetics of these eruptions based on different physical-volcanological approaches. Here we test different models with two case studies in the Colli Albani Volcanic District (central Italy): the monogenetic Prata Porci and the polygenetic Albano maars. Test results are mutually consistent, and show cumulative mechanical energy releases on the order of 1015–1017 J for single maars. The fraction of thermal energy turned into mechanical ranges from 0.45 (as calculated from the theoretical maximum mechanical energy), through 0.1 (calculated from country rock fragmentation, crater formation and ballistic ejection), to 0.03 (derived from magma fragmentation by thermohydraulic explosions). It appears that the energy released during the most intense hydromagmatic events may account for a dominant fraction of the total mechanical energy released during the whole maar eruptive histories. Finally, we consider the role of magmatic explosive activity intervening during maar eruptions in causing departures from predictions of the models evaluated.  相似文献   
9.
Large silicic explosive eruptions are the most catastrophic volcanic events. Yet, the intratelluric mechanisms underlying are not fully understood. Here we report a field and laboratory study of the Kos Plateau Tuff (KPT, 161 ka, Aegean Volcanic Arc), which provides an excellent geological example of conduit processes that control magma vesiculation and fragmentation during intermediate- to large-scale caldera-forming eruptions. A prominent feature of the KPT is the occurrence of quite unusual platy-shaped tube pumice clasts in pyroclastic fall and current deposits from the early eruption phases preceding caldera collapse. On macroscopic and SEM observations, flat clast faces are elongated parallel to tube vesicles, while transverse surfaces often occur at ~ 45° to vesicle elongation. This peculiar pumice texture provides evidence of high shear stresses related to strong velocity gradients normal to conduit walls, which induced vesiculation and fragmentation of the ascending magma. Either an increasing mass discharge rate without adequate enlargement of a narrow central feeder conduit or a developing fissure-like feeder system related to incipient caldera collapse provided suitable conditions for the generation of plate tube pumice within magma volumes under high shear during the pre-climactic KPT eruption phases. This mechanism implies that the closer to the conduit walls (where the stronger are the velocity gradients) the larger was the proportion of plate vs. conventional (lensoid) juvenile fragments in the ascending gas–pyroclast mixture. Consequently, plate pumice clasts were mainly entrained in the outer portions of the jet and convecting regions of a sustained, Plinian-type, eruption column, as well as in occasional lateral blast currents generated at the vent. As a whole, plate pumice clasts in the peripheral portions of the column were transported at lower altitudes and deposited by fallout or partial collapse closer to the vent relative to lensoid ones that dominated in the inner column portions. The plate tube pumice proportion decreased abruptly up to disappearance during the emplacement of the main pyroclastic currents and lithic-rich breccias related to extensive caldera collapse at the eruption climax, as a consequence of an overall widening of the magma feeder system through the opening of multiple conduits and eruptive vents, along with fissure erosion, concomitant to the disruption of the collapsing block.  相似文献   
10.
In this work, 8‐hydroxyquinoline is used as the active sites in cross‐linked chitosan beads with epichlorohydrin (CT‐8HQ). The CT‐8HQ material was shaped in bead form and used for heavy metal removal from aqueous solution. The study was carried out at pH 5.0 with both batch and column methods and the maximum adsorption capacity of metal ions by the CT‐8HQ was attained in 4 h in the batch experiment. The adsorption capacity order was: Cu2+ > Ni2+ > Zn2+ for both mono‐ and multi‐component systems with batch conditions. From breakthrough curves with column conditions, the adsorption capacity followed the order Cu2+ > Zn2+ > Ni2+ for both mono‐ and multi‐component systems. The CT‐8HQ beads maintained good metal adsorption capacity for all five cycles with absorbent restoration achieved with the use of 1.0 mol L–1 HCl solution, with 90% regeneration.  相似文献   
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