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1.
The 1·88–1·87 Ga post-kinematic granitoidsof the Central Finland Granitoid Complex (CFGC) provide a keygeochemical link to understanding granite formation in Paleoproterozoicorogenic and post-orogenic terrains. Thickness of the crustand intra-crustal differentiation processes played an importantrole in the formation of three granitoid types that shortlyfollowed the peak of the Svecofennian orogeny. In the easternCFGC, pyroxene-bearing plutons with C-type geochemical affinitiespredominate. These were formed from a mixture of low- to moderate-degreepartial melts (30%) of mafic mantle-derived (basaltic, 49% SiO2)source rocks and partial melts of pre-existing mafic granulitelower crust at depth. In the western CFGC, high-silica, iron-rich,fluorite-bearing plutons with A-type granite characteristicspredominate. A higher thermal gradient, thinner upper and lowercrust, and significantly more shallow Moho depth resulted inhigher proportions of crustal melts (0·3–0·4vs 0·1–0·2 in the eastern CFGC) incorporatedinto the partial melts of a mafic mantle-derived source. A geochemicalmodel focusing on the Jämsä and Honkajoki plutonsof the post-kinematic suite is presented, constraining the natureof the source rock(s), the degree of partial melting, proportionsof partial melts and fractionation processes involved. KEY WORDS: magmatic evolution; geochemistry; Proterozoic; granite; Finland  相似文献   
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Measurements of  Δ14C  in atmospheric CO2 are an effective method of separating CO2 additions from fossil fuel and biospheric sources or sinks of CO2. We illustrate this technique with vertical profiles of CO2 and  Δ14C  analysed in whole air flask samples collected above Colorado, USA in May and July 2004. Comparison of lower tropospheric composition to cleaner air at higher altitudes (>5 km) revealed considerable additions from respiration in the morning in both urban and rural locations. Afternoon concentrations were mainly governed by fossil fuel emissions and boundary layer depth, also showing net biospheric CO2 uptake in some cases. We estimate local industrial CO2:CO emission ratios using in situ measurements of CO concentration. Ratios are found to vary by 100% and average 57 mole CO2:1 mole CO, higher than expected from emissions inventories. Uncertainty in CO2 from different sources was ±1.1 to ±4.1 ppm for addition or uptake of −4.6 to 55.8 ppm, limited by  Δ14C  measurement precision and uncertainty in background  Δ14C  and CO2 levels.  相似文献   
3.
Aragonitic chlorophyte (green) algae, typical of the warm seas of the Tethyan area, reached as far north as the present Cotswolds of Southern England in mid-Jurassic times, when conditions made colonisation possible. Few in numbers and species, they appear to show features similar to those of their living descendants found today in warm seas marginal to the tropics, so confirming the Jurassic palaeolatitude arrived at independently from palaeogeographical studies.  相似文献   
4.
Oxygen Isotope Geochemistry of Oceanic-Arc Lavas   总被引:19,自引:11,他引:8  
Variations of oxygen isotope ratios in arc-related lavas canconstrain the contributions of subducted crustal igneous rocks,sediments, and fluids to the sub-arc mantle. We have measuredoxygen isotope ratios in 72 arc and back-arc lavas from fiveocean–ocean subduction zone systems using laser-fluorinationanalyses of olivine and other phenocrysts and glass. Eightypercent of our samples have  相似文献   
5.
Post-kinematic granitoids of the Central Finland Granitoid Complex(CFGC) were emplaced into the Palaeoproterozoic crust of centralFinland shortly after the  相似文献   
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A review of some recent studies on rock weathering in Antarctica has revealed that Antarctic weathering research has a significant contribution to make to the ongoing debate about rock weathering in cold climates. Largely conducted in the field rather than the laboratory as in the Northern Hemisphere, it demonstrates that whilst all weathering processes can occur in Antarctica this is highly localised and dependent on the particular micro‐environment. Freeze‐thaw, for example, is not the most dominant process in many parts of Antarctica. The right combination of rock temperature and moisture can mean that salt, insolation, hydration or even chemical weathering can predominate.  相似文献   
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Electrolytic model tank experiments to study resistivity and time domain induced polarization (IP) response over layered earth models were initiated primarily to facilitate the understanding of field results. Alternate layers of clay and sand (or clay-coated sand) with, in some cases, a surficial layer of water were assembled in the tank and resistivity and IP measurements made for a range of electrode spacings using the Wenner configuration. Graphite and silver-silver chloride electrodes were used as current and potential electrodes respectively. Clay-coated (3% by weight) sand was found to generate stronger polarization than either clay or sand alone. Apparent chargeability ma was observed to be positive for a nonpolarizable surface layer. For a polarizable surface layer, the sign of IP was controlled by the polarizability, the thickness of the second layer, and the spacing of the electrode spreads. The apparent chargeability ma can theoretically change sign from positive to negative and vice versa with a gradual increase in electrode spacing, and such negative IP effects were obtained in a few observations. A simultaneous decrease in IP and an increase in resistivity, which is a qualitative diagnostic feature for the occurrence of clean freshwater sand aquifers, could also be generated in the model tank experiment. Combined resistivity and IP soundings were carried out near Fredericton Junction and Tracy, New Brunswick, Canada. Field curves are presented along with the model curves for qualitative comparison and understanding of IP behaviour over a layered earth. Twenty-five out of twenty-seven soundings show only positive apparent chargeabilities, whereas two show chargeability sign changes (positive/negative/positive). The model study gives reason to believe that surface soils and Quaternary gravel boulder deposits near Fredericton Junction are relatively non-polarizable. As an auxiliary experiment, sand and clay were taken in different proportions by weight and mixed thoroughly with water in a cement mixer. The mixtures were then compressed with a suitable die and plunger under 3.6 Pa pressure to prepare cylindrical samples of height 18 cm and diameter 15.5 cm. IP measurements were done on the flat faces using the Wenner configuration with a= 2 cm. Chargeability was found to be negative for 100 and 90% clay mixtures. It reached a positive maximum for an 80% clay-20% sand mixture and then decreased gradually with increasing sand and decreasing clay content.  相似文献   
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