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De glauconiarum origine 总被引：4，自引：0，他引：4
The glauconitic facies is widespread on present-day continental shelves from 50° S to 65° N and at water depths between 50 and 500 m, and is in particularly great abundance on the upper slope and outer shelf between 200 and 300 m. It is also common in many ancient rocks of post-late Precambrian age. It occurs as sand- to pebble-sized, essentially green particles (granular facies) but also as a surface coating on particles and hardgrounds and as a diffuse impregnation (film and diffuse facies). We suggest the replacement of the term ‘glauconite’, which has been interchangeably used to designate a morphological form and a specific mineral, by glaucony (facies) and glauconitic smectite and glauconitic mica as end members of the glauconitic mineral family. The widely accepted model of Burst and Hower for glauconitization requires a degraded, micaceous (2: 1 layer lattice structure) parent clay mineral. However, detailed analysis of numerous samples of Recent glaucony reveals that such a parent substrate is exceptional. The model therefore requires modification. Generally the parent material is carbonate particles, argillaceous (kaolinitic) faecal pellets, infillings of foraminiferal tests, various mineral grains and rock fragments, that pass gradually into the commonly occurring green grains. We show that the process of glauconitization is achieved by de novo authigenic growth of automorphous crystallites in the pores of the substrate, accompanied by progressive alteration and replacement of the substrate. It is this two-fold evolution that causes the ‘verdissement’of granular substrates, macrofossils and hardgrounds. The authigenic mineral is an iron-rich and potassium-poor glauconitic smectite. While new smectites are growing into the remaining pore space the earlier smectites are modified by incorporation of potassium, producing decreasingly expandable minerals with a non-expandable glauconitic mica as the end member. This mineralogical diversity of the glauconitic mineral family explains the highly variable physical and chemical properties of glaucony. Four categories, nascent, little-evolved, evolved and highly-evolved glaucony are distinguished. Glauconitization appears to be controlled by a delicate balance between degree of physical confinement of a particle and the amount of ionic exchange between the micro-environment and ambient open marine sea water. The optimum conditions for glauconitization are those of semi-confinement. As a result the interior of a grain is more glauconitized than its less confined periphery. Similarly, for identical substrate types, large grains (500μm) provide more favourable substrates for glauconitization than lesser confined small grains. On a larger scale the formation of glaucony is governed by the availability of iron and potassium and the balance between detrital influx and winnowing. Low accumulation rates expose grains to the open marine environment for sufficiently long times (105-106 years for highly-evolved glaucony). 相似文献
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Time series data of phytoplanktonic and bacterial biomass during the ice retreat period at different latitudes in the Weddell Sea and Prydz Bay areas show a distinct delay in the development of bacteria with respect to phy'oplankton. Use of a general ecophysiological model of bacterial growth, along with direct in situ measurements of growth and mortality rates, allowed the simulation of the observed timing of bacterial development. It is suggested that the uncoupling between phytoplanktonic and bacterial development at the earliest stage of the spring ice-edge related algal bloom is not the result of the low temperatures occurring in the Southern Ocean but rather is due to the macromolecular nature of the dissolved organic matter released from phytoplankton. 相似文献
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In the Causses platform (south‐east France), Late Hettangian to Sinemurian deposits were interpreted previously as shallow‐water carbonate ramp deposits. A new look at these deposits has shown a fault‐controlled mosaic carbonate platform that is different from the carbonate ramp models. Within the platform mosaic, 15 lithofacies have been recognized, which are organized in four facies associations, including peritidal, restricted shallow sub‐tidal, sand dunes and sub‐tidal shelf facies associations. The rapid lateral and vertical facies changes, and the lack of consistent landward or seaward direction indicated by the pattern of facies changes, question the existence of a shoreline suggested by the traditional models for this region. Instead, the facies organization and cycle stacking pattern suggest deposition in a mosaic of intertidal islands between which sub‐tidal restricted or open conditions could coexist in very close proximity. Such a platform mosaic would have been defined by tectonic activities along normal faults which segmented the shallow‐water Causses platform. The facies and facies associations are arranged into metre‐scale, peritidal and sub‐tidal cycles that are also variable. Certain cycles show the same stacking pattern in all the sections and seem to be traceable over tens of kilometres. On the contrary, other cycles cannot be correlated; they are present only in specific sections and have a maximum lateral extension of 1 or 2 km. These metre‐scale cycles stack to form four medium‐scale cycles bounded by surfaces that display sub‐aerial exposure features. Medium‐scale cycles stack into two larger‐scale cycles (tens of metres thick) and are bounded by well‐defined karstic surfaces. Based on their lateral continuity and their stacking pattern, the metre‐scale cycles are controlled probably by high frequency eustatic variations overprinting the topographic irregularities formed by differential subsidence of fault‐bounded blocks. Episodic fault activities may reorganize the topography so that, even if eustatic changes may still be the major control of cycles, the expression and number of cycles could be different. Cycles of medium and large‐scale are interpreted as being allogenic, controlled by changes in eustasy and/or subsidence rates as evidenced by their lateral continuity and the correlations of the large‐scale cycles with third‐order depositional sequences. 相似文献
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Mingling of Immiscible Dolomite Carbonatite and Trachyte in Tuffs from the Massif Central, France 总被引：1，自引：0，他引：1
CHAZOT GILLES; BERTRAND HERVE; MERGOIL JULIETTE; SHEPPARD SIMON M. F. 《Journal of Petrology》2003,44(10):1917-1936
A pyroclastic tuff from the Velay volcanic province in the FrenchMassif Central contains blocks up to 30 cm long of local basementrocks, lava clasts, coarse-grained cumulates and pyroclasticfragments, with more or less diffuse boundaries with the hosttuff, which probably represent more consolidated parts of thetuff. All of the pyroclastics examined and approximately 10%of the cumulate xenoliths contain carbonates in variable amounts,textures and mineralogy. In some of the tuff samples, dolomiteoccurs in large amounts (up to 57%), principally as immiscibleglobules in trachytic melt (now glass), and represents the firstoccurrence of carbonatite reported from the Massif Central.The other carbonates, magnesiosiderite in the mafic cumulatesor occasionally in some tuffs, and calcite in the felsic cumulates,are always associated with a silicate glass of trachytic composition.Coexisting feldspars and carbonates in the various types ofsample are approximately in Sr isotopic equilibrium with aninitial ratio of about 0·7042. C- and O-isotopic compositionsof the carbonates covary and cover a very wide range of compositionfrom -2·9 to 3·9 相似文献
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Lithospheric Mantle Evolution during Continental Break-Up: The West Iberia Non-Volcanic Passive Margin 总被引：6，自引：0，他引：6
CHAZOT GILLES; CHARPENTIER SOPHIE; KORNPROBST JACQUES; VANNUCCI RICCARDO; LUAIS BEATRICE 《Journal of Petrology》2005,46(12):2527-2568
Ultramafic (lherzolites, metasomatized peridotites, harzburgites,websterites and clinopyroxenites) and mafic igneous (basalts,dolerites, diorites and gabbros) rocks exposed at the sea-flooralong the West Iberia continental margin represent a rare opportunityto study the transition zone between continental and oceaniclithosphere. The igneous rocks are enriched in LREE, unlikeNorth Atlantic MORB. A correlation between their 143Nd/144Ndisotopic composition and Ce/Yb ratio suggests that they originatefrom mixing between partial melts of a depleted mantle sourcesimilar to DMM and of an enriched mantle source which may residewithin the continental lithosphere. Clinopyroxenes and amphibolesin the ultramafic rocks are LREE depleted and have flat HREEpatterns with concentrations higher than those of abyssal peridotites.Clinopyroxenes in the harzburgites are less LREE depleted buthave lower HREE concentrations. The clinopyroxenes in the GaliciaBank (GB) lherzolites have radiogenic Nd (143Nd/144Nd rangingfrom 0·512937 to 0·513402) and unradiogenic Sr(87Sr/86Sr ranging from 0·702100 to 0·702311)isotopic ratios similar to, or higher than, DMM (Depleted MORBMantle) whereas the clinopyroxenes in the Iberia Abyssal Plainwebsterites have low-Nd isotopic compositions (143Nd/144Nd rangingfrom 0·512283 to 0·512553) with high-Sr isotopicratios (87Sr/86Sr ranging from 0·704170 to 0·705919).Amphiboles in Galicia Bank lherzolites and diorites have Nd–Srisotopic compositions (143Nd/144Nd from 0·512804 to 0·512938and 87Sr/86Sr from 0·703243 to 0·703887) intermediatebetween those of the clinopyroxenes from the Galicia Bank andthe Iberia Abyssal Plain, but similar to the clinopyroxenesin the 5100 Hill harzburgite (143Nd/144Nd = 0·512865and 87Sr/86Sr = 0·703591) and to the igneous rocks (143Nd/144Ndranging from 0·512729 to 0·513121 and 87Sr/86Srranging from 0·702255 to 0·705109). The majorand trace element compositions of cpx in the Galicia Bank spinellherzolites provide evidence for large-scale refertilizationof the lithospheric upper mantle by MORB-like tholeiitic melts.The associated harzburgites did not undergo partial meltingduring the rifting stage, but, in earlier times, probably during,or even before, the Hercynian orogeny. Iberia Abyssal Plainwebsterites are interpreted as high-pressure cumulates formedin the mantle. Their high Sm/Nd ratios (from 0·43 to0·67) coupled with very low-Nd isotopic compositionsare best explained by a two-stage history: formation of thecumulates from the percolation of enriched melts long beforethe rifting, followed by low-degree partial melting of the pyroxenites,accounting for their LREE depletion. This last event probablyoccurs during the rifting episode, 122 Myr ago. The isotopicheterogeneities observed in the ultramafic rocks of the Iberiamargin were already present at the time of the rifting event.They reflect a long and complex history of depletion and enrichmentevents in an old part of the mantle, and provide strong argumentsfor a sub-continental origin of this part of the upper mantle. KEY WORDS: Iberia margin; mantle peridotites; igneous rocks; petrology; geochemistry 相似文献
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The detailed analysis of pellets deposited on the continental shelf off Congo and Gabon (Gulf of Guinea) reveals the present formation of goethite and berthierine-granules, as well as that of glauconite. The goethite is being formed in the most oxygenized zones, independently of the initial nature of the granular support and, sometimes, takes the form of pseudooolites. The berthierine is being formed in the Ogooue delta zone. To us the deltaic environment, rather than the temperature factor, seems determinant. Principally, this berthierine is found in the form of coprolites, of initial kaolinic composition. Incrustations of calcareous debris and fillings of animalculae tests are present. This genesis is recent (post-Flandrian) and is still continuing. The glauconite exists practically uniquely in the form of coprolites, from the medium-depth zones of the continental shelf (—50 m) down to the upper continental slope (—300 m). The sèdiment in which it was formed, and is probably still being formed, is older (ante-Flandrian). The actual rate of sedimention is null when glauconite is forming. The glauconite formation may be broken down into several stages, which are found at different sampling depths and, sometimes, in the same samples. The pellets are formed first. These original pellets, of kaolinic nature, gradually become smectitic. The evolution continues, becoming a component with diffractometric behaviour identical with that of an interlayered material (illite-vermiculite) with the illite dominant. Correlatively, the K2O percentage increases from 2–3% in the smectites to 5–6% in the most evolved component. The mineralogical composition of these last pellets is identical with that of certain fossil glauconites, the evolution of which could be followed up to the best crystallized glauconite mineral. Thus, we were able to reconstitute the formation history of the glauconite from any mineralogical support up to the typical glauconite mineral (Table l). Two conditions necessary for this formation are detected here: the time factor, as has often been pointed out, is important. However, it is, above all, the environment factor which has attracted our attention. The forming of pellets favours and determines the geo-chemical evolution through the creation of a semi-confined environment. Reactions take place there in a more concentrated environment than in the open sea, this environment is characterized by a large surface of reaction, since the granule is porous. Sedimentologically, it is possible to distinguish two groups of glauconites: one, monomineral, corresponds to more or less crystallized glauconite mineral; the other, plurimineral, consists of various TOT minerals. Only the first has the significance generally attributed to all glauconites : open epicontinental marine environment, free of sedimentation for a long time. The various cases of evolution encountered here are summarized below (Table 1). 相似文献
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VALENTINA FLORES‐AQUEVEQUE STEPHANE C. ALFARO SANDRINE CAQUINEAU GILLES FORET GABRIEL VARGAS JOSE A. RUTLLANT 《Sedimentology》2012,59(3):990-1000
The analysis of the aeolian content of marine cores collected off the coast of the Atacama Desert (Mejillones Bay, Chile) suggests that marine sediments can record inter‐annual to inter‐decadal variations in the regional southerly winds responsible for particle entrainment at the surface of the nearby desert. However, the establishment of a simple and direct correlation between the sediment and wind records is complicated by the difference of time scales between the erosion and accumulation processes. The aim of this work is to: (i) assess the inter‐annual variability of the surface winds responsible for the sand movements; and (ii) determine whether the integration over periods of several months completely smoothes the rapid changes in characteristics of the transported and deposited aeolian material. To accomplish this aim, 14 years of 10 m hourly wind speed, measured at the Cerro Moreno (Antofagasta) Airport between 1991 and 2003 and at the Orica Station between 2000 and 2004, were analyzed. For each year, the wind speed statistical distribution can be represented by a combination of two to three Weibull functions. Winds of the lowest Weibull mode are too weak to move the sand grains at the surface of the pampa; this is not the case for the intermediate mode and especially for the highest speed mode which are able to erode the arid surface and transport particles to the bay. In each individual year of the period of study, the highest speed mode only accounted for a limited number of strong erosion events. Quantitative analysis of the distribution of the friction velocities and of their impact on erosion using a saltation model suggests that, although all wind speeds above threshold produce erosion events, values around 0·45 m sec?1 contribute less to the erosion flux. This gap allows separation of the erosion events into low and high saltation modes. The correlation (r = 0·997) between the importance of the third Weibull mode and the extent of higher rate saltation indicates that the inter‐annual variability of the erosion at the surface of the pampa, as well as the transport of coarse particles (>100 μm), are directly related to inter‐annual variations in the prevalence of the strongest winds. Finally, a transport and deposition model is used to assess the possible impact of the wind inter‐annual variability on the deposition flux of mineral particles in the bay. The results suggest that inter‐annual differences in the wind speed distributions have a quantifiable effect on the intensity and size‐distribution of this deposition flux. This observation suggests that a detailed analysis of the sediment cores collected from the bay could be used for reconstructing the inter‐annual variability of past winds. 相似文献
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The origin of Antarctic precipitation: a modelling approach 总被引：3，自引：0，他引：3
GILLES DELAYGUE VALÉRIE MASSON JEAN JOUZEL RANDAL D. KOSTER RICHARD J. HEALY 《Tellus. Series B, Chemical and physical meteorology》2000,52(1):19-36
The contribution of different moisture sources to Antarctic precipitation for present‐day and glacial conditions is estimated with the NASA/GISS Atmospheric General Circulation Model. Despite its low horizontal resolution (8°×10°), this model simulates reasonably well the broad features of the observed present‐day hydrological cycle. Simulated present‐day Antarctic precipitation is dominated throughout the year by moisture from a subtropical/midlatitude band (30°S−60°S). The moisture supplied to a given coastal area of Antarctica originates mostly in the adjacent oceanic basin; closer to the pole, other oceanic basins can also contribute significantly. Replacing the present‐day sea surface temperatures (SSTs) and sea ice cover in the GCM with those from the CLIMAP oceanic reconstruction for the last glacial maximum (LGM), greatly increases the simulated latitudinal temperature gradient, with the consequence of slightly enhancing the contribution of low latitude moisture to Antarctic precipitation. It also changes the seasonality of the different contributions and thus their budget, particularly in coastal regions. Because the nature of LGM tropical SSTs is still under debate, we performed an additional LGM simulation in which the tropical SSTs are reduced relative to those of CLIMAP. The resulting decrease in the latitudinal gradient brings the relative contributions to Antarctic precipitation more in line with those of the present‐day simulation. 相似文献
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