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GUILLAUME CAILLEAU ERIC P. VERRECCHIA OLIVIER BRAISSANT† LAURENT EMMANUEL‡ 《Sedimentology》2009,56(6):1858-1875
Needle fibre calcite is one of the most ubiquitous habits of calcite in vadose environments (caves deposits, soil pores, etc.). Its origin, either through inorganic, indirect or direct biological processes, has long been debated. In this study, investigations at 11 sites in Europe, Africa and Central America support arguments for its biogenic origin. The wide range of needle morphologies is the result of a gradual evolution of the simplest type, a rod. This rod is the elementary brick which, by aggregation and welding, builds more complex needles. The absence of cross‐welded needles implies that they are welded in a mould, or under a longitudinal and unidirectional constraint, before being released inside the soil pores. The difference between the lengthening of the needles and the c axis can be explained by the existence of needles observed under a scanning electron microscope in organic sleeves, which can act as a mould during rod growth. Complex morphologies with epitaxial outgrowths on straight rods cannot have grown entirely inside organic microtubes; they must result from soil diagenesis after the release of straight rods in a soil‐free medium. Whisker crystals are interpreted as the result of growth and coalescence of euhedral crystals on a rod. Rhomb chains are considered to be the consequence of successive epitaxial growth steps on a needle during variations in growth conditions. Isotopic signatures for needle fibre calcite vary from ?16·63‰ to +1·10‰ and from ?8·63‰ to ?2·25‰ for δ13C and δ18O, respectively. The absence of high δ18O values for needle fibre calcite precludes a purely physicochemical origin (evaporative) for this particular habit of calcite. As epitaxial growth cannot precipitate in the same conditions as initial needles, needle fibre calcite stable isotopic signatures should be used with caution as a proxy for palaeoenvironmental reconstructions. In addition, it is suggested that the term needle fibre calcite should be kept for the original biogenic form. The other habit should be referred to as epitaxial forms of needle fibre calcite. 相似文献
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DARIO HARAZIM BAS VAN DE SCHOOTBRUGGE KATRIN SORICHTER JENS FIEBIG ANDRIES WEUG GUILLAUME SUAN WOLFGANG OSCHMANN 《Sedimentology》2013,60(2):359-390
In order to constrain spatial variability in watermass conditions within the European Epicontinental Seaway prior to, during and after the Toarcian Oceanic Anoxic Event, carbon (δ13Cbel, δ13Ccarb) and oxygen (δ18Obel, δ18Ocarb) isotope records were obtained from three sections in the Grands Causses Basin (southern France). These data were then compared with similar records along a north–south transect across the European Epicontinental Seaway. As the conclusions reached here strongly depend on the reliability of belemnite calcites as archives of palaeoceanographic changes, an attempt was made to improve the understanding of isotope signals recorded in belemnite calcite. Intra‐rostral carbon and oxygen‐isotope data from six belemnite specimens belonging to the genus Passaloteuthis were collected. Intra‐rostral carbon‐isotopes are influenced by vital effects, whereas oxygen‐isotopes reflect relative changes in temperature and salinity. Palaeotemperatures calculated from δ18Obel‐isotope records from the Grands Causses Basin confirm relatively low temperatures throughout the Late Pliensbachian. Similar cool water conditions have previously been shown in Germany, England, Spain and Portugal. A temperature increase of up to 6 °C is observed across the Pliensbachian–Toarcian boundary. A pronounced negative shift of at least ?3‰ (Vienna‐Pee Dee Belemnite) is recorded in bulk carbonate carbon during the lower Harpoceras serpentinum zone, typical of the Toarcian Oceanic Anoxic Event. Before and after the Toarcian Oceanic Anoxic Event, a good correlation between δ13Ccarb and δ13Cbel exists, indicating well‐ventilated bottom‐waters and normal marine conditions. Instead, data for the Toarcian Oceanic Anoxic Event indicate the development of a strong north–south gradient in salinity stratification and surface‐water productivity for the Western Tethyan realm. This study thus lends further support to a pronounced regional overprint on carbon and oxygen‐isotope records in epicontinental seaways. 相似文献
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