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1.
Anthropogenic eutrophication and spreading anoxia in freshwater systems is a global concern. Little is known about anoxia in earlier historic times under weaker human impact, or under prehistoric natural conditions with different trophic, land cover and climatic regimes. We use a novel approach that combines high-resolution hyperspectral imaging with µ-XRF and HPLC-pigment data, which allows us to assess chloropigments (productivity) and bacteriopigments (anoxia) at seasonal subvarve-scale resolution. Our ~9700 cal a bp varved sediment record from NE Poland suggests that productivity increased stepwise from oligotrophic Early Holocene conditions (until ~9200 cal a bp ) to mesotrophic conditions in the Mid- and Late Holocene. Natural eutrophication was mainly a function of progressing landscape evolution with intense weathering under dense forest and warm-moist climatic conditions. Generally, anoxia increased with increasing productivity. Seasonal anoxia and some multi-decadal periods of meromixis were the common mixing patterns throughout the Holocene except for a period of persisting meromixis between ~5200 and 2000 cal a bp. Anthropogenic deforestation around 400 cal a bp resulted in substantially better lake oxygenation despite high productivity. In this small lake, aquatic productivity and lakeshore forest cover (wind shield) were more important factors controlling oxic/anoxic conditions than Holocene temperature variability.  相似文献   
2.
Using a combination of geophysical and geotechnical data from Storfjorden Trough Mouth Fan off southern Svalbard, we investigate the hydrogeology of the continental margin and how this is affected by Quaternary glacial advances and retreats over the continental shelf. The geotechnical results show that plumites, deposited during the deglaciation, have high porosities, permeabilities and compressibilities with respect to glacigenic debris flows and tills. These results together with margin stratigraphic models obtained from seismic reflection data were used as input for numerical finite element models to understand focusing of interstitial fluids on glaciated continental margins. The modelled evolution of the Storfjorden TMF shows that tills formed on the shelf following the onset of glacial sedimentation (ca. 1.5 Ma) acted as aquitards and therefore played a significant role in decreasing the vertical fluid flow towards the sea floor and diverting it towards the slope. The model shows that high overpressure ratios (up to λ ca. 0.6) developed below the shelf edge and on the middle slope. A more detailed model for the last 220 kyrs accounting for ice loading during glacial maxima shows that the formation of these aquitards on the shelf focused fluid flow towards the most permeable plumite sediments on the slope. The less permeable glacigenic debris flows that were deposited during glacial maxima on the slope hinder fluid evacuation from plumites allowing high overpressure ratios (up to λ ca. 0.7) to develop in the shallowest plumite layers. These high overpressures likely persist to the Present and are a critical precondition for submarine slope failure.  相似文献   
3.
Franchthi Cave, bordering Kiladha Bay, in Greece, is a key archaeological site, due to its long occupation time, from?~?40,000 to?~?5000 year BP. To date, no clear evidence of Neolithic human dwellings in the cave was found, supporting the assumption that Neolithic people may have built a village where there is now Kiladha Bay. During the Neolithic period/Early Holocene, wide areas of the bay were indeed emerged above sea level. Bathymetric and seismic data identified a terrace incised by a valley in?~?1 to 2 m sediment depth. Eight sediment cores, up to 6.3-m-long, were retrieved and analysed using petrophysical, sedimentological, geochemical, and chronostratigraphic methods. The longest core extends into the exposure surface, consisting of a layer of carbonate rubble in a finer matrix, representing weathering processes. Dated organic remains place this unit at?~?8500 cal year BP. It is overlain by stiff silty mud representing an estuarine environment. This mud is capped by reduced sediments with roots marking an exposure surface. A shell-layer, dated to?~?6300 cal year BP, overlies this terrestrial sequence, reflecting the marine transgression. This layer occurs at 10.8 mbsl, 7.7 m deeper than the global sea level at that time, suggesting tectonic subsidence in the area. It is overlain by finer-grained marine carbonate-rich sediments. The top of the core shows traces of eutrophication, pebbles and marine shells, all likely a result of modern anthropogenic processes. These results are interpreted in the context of human occupation: the exposed surface contains pottery sherds, one dating to the Early to Middle Neolithic period, indicating that Neolithic people were present in this dynamic landscape interacting with a migrating coastline. Even if the artefacts are isolated, future investigations of the submerged landscape off Franchthi Cave might lead to the discovery of a Neolithic village, which eventually became buried under marine sediments.  相似文献   
4.
The effects of soil water content (SWC) on the formation of run‐off in grass swales draining into a storm sewer system were studied in two 30‐m test swales with trapezoidal cross sections. Swale 1 was built in a loamy fine‐sand soil, on a slope of 1.5%, and Swale 2 was built in a sandy loam soil, on a slope of 0.7%. In experimental runs, the swales were irrigated with 2 flow rates reproducing run‐off from block rainfalls with intensities approximately corresponding to 2‐month and 3‐year events. Run‐off experiments were conducted for initial SWC (SWCini) ranging from 0.18 to 0.43 m3/m3. For low SWCini, the run‐off volume was greatly reduced by up to 82%, but at high SWCini, the volume reduction was as low as 15%. The relative swale flow volume reductions decreased with increasing SWCini and, for the conditions studied, indicated a transition of the dominating swale functions from run‐off dissipation to conveyance. Run‐off flow peaks were reduced proportionally to the flow volume reductions, in the range from 4% to 55%. The swale outflow hydrograph lag times varied from 5 to 15 min, with the high values corresponding to low SWCini. Analysis of swale inflow/outflow hydrographs for high SWCini allowed estimations of the saturated hydraulic conductivities as 3.27 and 4.84 cm/hr in Swales 1 and 2, respectively. Such estimates differed from averages (N = 9) of double‐ring infiltrometer measurements (9.41 and 1.78 cm/hr). Irregularities in swale bottom slopes created bottom surface depression storage of 0.35 and 0.61 m3 for Swales 1 and 2, respectively, and functioned similarly as check berms contributing to run‐off attenuation. The experimental findings offer implications for drainage swale planning and design: (a) SWCini strongly affect swale functioning in run‐off dissipation and conveyance during the early phase of run‐off, which is particularly important for design storms and their antecedent moisture conditions, and (b) concerning the longevity of swale operation, Swale 1 remains fully functional even after almost 60 years of operation, as judged from its attractive appearance, good infiltration rates (3.27 cm/hr), and high flow capacity.  相似文献   
5.
Since 1994, the Rumuruti (R) chondrites have been recognized as a new, well-established chondrite group differing from carbonaceous, ordinary, and enstatite chondrites. The first R chondrite, Carlisle Lakes, was found in Australia in 1977. Meanwhile, the number has increased to 107 (December, 2010). This group is named after the Rumuruti meteorite, the first and so far the only R chondrite fall. Most of the R chondrites are breccias containing a variety of different clasts embedded in a clastic matrix. Some textural and mineralogical characteristics can be summarized as follows: (a) the chondrule abundance in large fragments and in unbrecciated rocks is ∼35–50 vol%; (b) Ca,Al-rich inclusions are rare; (c) the olivine abundance is typically 65–78 vol%; (d) the mean chondrule diameter is ∼400 μm; (e) in unequilibrated R chondrites, low-Ca pyroxene is dominating, whereas in equilibrated R chondrites it is Ca-rich pyroxene; (f) the typical olivine in a metamorphosed lithology is ∼Fa38–40; (g) matrix olivine in unequilibrated, type 3 fragments and rocks has much higher Fa (∼45–60 mol%) compared to matrix olivines in type 4–6 lithologies (∼Fa38–41); (h) spinels have a high TiO2 of ∼5 wt%; (i) abundant different noble metal-bearing phases (metals, sulfides, tellurides, arsenides) occur. The exception is the metamorphosed, type 5/6 R chondrite La Paz Icefield 04840 which contains hornblende, phlogopite, and Ca-poor pyroxene, the latter phase typically occurring in low-grade metamorphosed R chondrites only.In bulk composition, R chondrites have some affinity to ordinary chondrites: (a) the absence of significant depletions in Mn and Na in R chondrites and ordinary chondrites is an important feature to distinguish these groups from carbonaceous chondrites; (b) total Fe (∼24 wt%) of R chondrites is between those of H and L chondrites (27.1 and 21.6 wt%, respectively); (c) the average CI/Mg-normalized lithophile element abundances are ∼0.95 × CI, which is lower than those for carbonaceous chondrites (≥1.0 × CI) and slightly higher than those for ordinary chondrites (∼0.9 × CI); (d) trace element concentrations such as Zn (∼150 ppm) and Se (∼15 ppm) are much higher than in ordinary chondrites; (e) the whole rock Δ17O of ∼2.7 for R chondrites is the highest among all meteorite groups, and the mean oxygen isotope composition is δ17O = 5.36 ± 0.43, δ18O = 5.07 ± 0.86, Δ17O = +2.72 ± 0.31; (f) noble gas cosmic ray exposure ages of R chondrites range between ∼0.1 and 70 Ma. More than half of the R chondrites analyzed for noble gases contain implanted solar wind and, thus, are regolith breccias. The 43 R chondrites from Northern Africa analyzed so far for noble gases seem to represent at least 16 falls. Although the data base is still scarce, the data hint at a major collision event on the R chondrite parent body between 15 and 25 Ma ago.  相似文献   
6.
A field and petro-chemical classification of felsic magmatic phases (FMPs) at the world-class Cantung W skarn deposit was undertaken to document the evolution of magmatism and the relationships between different FMPs, metasomatism, and mineralization. Early FMPs include moderately differentiated (Zr/Hf = 18–26, Ti/Zr = 14–15) biotite monzogranitic plutons and early biotite-rich granitic dykes, and compositionally similar quartz–feldspar porphyry dykes. Late, highly fractionated (Zr/Hf = 8–17, Ti/Zr = 3–13) FMPs sourced from a deeper monzogranitic intrusion include: (1) leucocratic biotite- or tourmaline-bearing dykes derived from localized entrapments of residual magma; and, (2) sub-vertical NE-trending aplitic dykes derived from a larger segregation of residual fluid- and incompatible element-enriched magma. The aplitic dykes have textures, morphologies, spatial associations, and a pervasive calcic metasomatic mineral assemblage (Ca-plagioclase + quartz or clinozoisite) indicative of syn-mineralization emplacement. Very late-stage overpressuring and initiation of sub-vertical fractures into the overlying plutonic carapace and country rocks by supercritical magmatic fluid led to an interaction with calcareous country rocks that resulted in an increased aCa2+ in the fluid and the concurrent precipitation of W skarn. Residual magma also ascended with, and quenched in equilibrium with the magmatic fluid to from the aplitic dykes, then was metasomatized by the fluid as it interacted with calcareous country rocks. Overall, highly fractionated and moderately to very highly undercooled FMPs at Cantung provide evidence for a large and evolving felsic magmatic system at depth that segregated and maintained a stable fluid- and incompatible element-enriched residual magma until the latest stages of crystallization. The detailed study of FMPs associated with magmatic-hydrothermal mineral deposits allow us to refine our understanding of these mineralizing systems and better define metallogenic and exploration models for intrusion-related mineralization.  相似文献   
7.
8.
This work deals with a comparison of different numerical schemes for the simulation of contaminant transport in heterogeneous porous media. The numerical methods under consideration are Galerkin finite element (GFE), finite volume (FV), and mixed hybrid finite element (MHFE). Concerning the GFE we use linear and quadratic finite elements with and without upwind stabilization. Besides the classical MHFE a new and an upwind scheme are tested. We consider higher order finite volume schemes as well as two time discretization methods: backward Euler (BE) and the second order backward differentiation formula BDF (2). It is well known that numerical (or artificial) diffusion may cause large errors. Moreover, when the Péclet number is large, a numerical code without some stabilising techniques produces oscillating solutions. Upwind schemes increase the stability but show more numerical diffusion. In this paper we quantify the numerical diffusion for the different discretization schemes and its dependency on the Péclet number. We consider an academic example and a realistic simulation of solute transport in heterogeneous aquifer. In the latter case, the stochastic estimates used as reference were obtained with global random walk (GRW) simulations, free of numerical diffusion. The results presented can be used by researchers to test their numerical schemes and stabilization techniques for simulation of contaminant transport in groundwater.  相似文献   
9.
Biological structures exert a major influence on species diversity at both local and regional scales on deep continental margins. Some organisms use other species as substrates for attachment, shelter, feeding or parasitism, but there may also be mutual benefits from the association. Here, we highlight the structural attributes and biotic effects of the habitats that corals, sea pens, sponges and xenophyophores offer other organisms. The environmental setting of the biological structures influences their species composition. The importance of benthic species as substrates seems to increase with depth as the complexity of the surrounding geological substrate and food supply decline. There are marked differences in the degree of mutualistic relationships between habitat-forming taxa. This is especially evident for scleractinian corals, which have high numbers of facultative associates (commensals) and few obligate associates (mutualists), and gorgonians, with their few commensals and many obligate associates. Size, flexibility and architectural complexity of the habitat-forming organism are positively related to species diversity for both sessile and mobile species. This is mainly evident for commensal species sharing a facultative relationship with their host. Habitat complexity is enhanced by the architecture of biological structures, as well as by biological interactions. Colony morphology has a great influence on feeding efficiency for suspension feeders. Suspension feeding, habitat-forming organisms modify the environment to optimize their food uptake. This environmental advantage is also passed on to associated filter-feeding species. These effects are poorly understood but represent key points for understanding ecosystems and biodiversity on continental margins. In this paper we explore the contributions of organisms and the biotic structures they create (rather than physical modifications) to habitat heterogeneity and diversity on the deep continental margins.  相似文献   
10.
Mesozooplankton samples were collected between March 2005 and November 2008 in St Lucia, the largest estuarine lake system in South Africa. St Lucia experienced an extended period of drought before and during the present study. This drought led to natural closing of the estuary mouth as a result of flood-tide marine sediment deposition in 2002. In March 2007 the mouth was washed open by exceptionally high tidal and wave conditions. This resulted in an influx of a large volume of seawater. The mouth closed again in August 2007. Before opening of the mouth salinities in the Estuary were below 10 and large parts of North Lake dried up while South Lake retained a relatively stable waterbody with salinities between 10 and 30. When the mouth opened seawater flooded the system and salinities changed to about 35. After the mouth had closed again in August 2007 salinities increased in the lakes and decreased in the Estuary. The mesozooplankton community was dominated by copepods during all sampling sessions, especially by the estuarine calanoids Pseudodiaptomus stuhlmanni and Acartia natalensis. Mean mesozooplankton densities were significantly higher in South Lake before the mouth opened in March 2007. While zooplankton density decreased when the mouth opened species richness increased with the influx of coastal marine species, especially in the Estuary. Overall zooplankton densities declined progressively as salinity increased to hypersaline levels after mouth closure. Multivariate analyses supported significant differences between the lakes and the Estuary in terms of mesozooplankton community composition. Taxa mostly responsible for the similarities within and dissimilarity between sections of the system were the copepods P. stuhlmanni and A. natalensis with the meroplankton, crab zoeae and mollusc larvae, also contributing significantly after the mouth-opening event.  相似文献   
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