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Using a Rayleigh distillation fractionation model, we calculate that the maximum isotope fractionation potentially achievable is less than 5% during the early stages of gas release from a sample. Our calculation corrects the erroneous conclusions of Gautheron and Moreira (2003), who re‐interpreted the plume‐like neon isotopic compositions found in metasomatic apatite from a south‐eastern Australian xenolith (Matsumoto et al., 1997) to be the result of Rayleigh‐type isotope fractionation of originally MORB‐type neon during stepheating gas extraction. We stress that the modelling of neon isotopic fractionation by Gautheron and Moreira (2003) is incorrect, and that the finding of a plume‐like neon isotopic composition in the apatite by Matsumoto et al. (1997) remains a quite valid and robust conclusion.  相似文献   
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Abstract— Characterization of the microstructural features of the metal of the Santa Catharina meteorite was performed using a variety of electron optical techniques. Sample USNM#6293 is chemically homogeneous on the micron scale and has a Ni content of 28.2 wt.%. Its microstructure is similar to that of the Twin City ataxite and contains clear taenite II, i.e., fcc taenite with domains of tetrataenite, < 10 nm in size. Sample USNM#3043 is a more typical Santa Catharina specimen with dark and light regions as observed with the light optical microscope. The dark regions are inhomogeneous and contain 45–50 wt.% Ni and 7–12 wt.% O. The light regions are homogeneous and contain 35 wt.% Ni and no detectable oxygen. The microstructure is that of cloudy zone, i.e., islands of tetrataenite, ~20 nm in size, in a honeycomb matrix. The honeycomb phase contains Ni rich oxide in the dark regions and contains metal, fcc taenite, in the light regions. The original metal structure of USNM#3043 is cloudy zone which formed during cooling into the low temperature miscibility gap of the Fe-Ni phase diagram. The dark regions were developed from the metal by selective corrosion of the honeycomb structure, transforming it into Ni containing oxides, possibly non-stoichiometric Fe2NiO4 while retaining the tetrataenite islands. Using the results of this study, many of the existing discrepancies concerning the microstructure of Santa Catharina can be explained.  相似文献   
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The Bloomington meteorite, a 67.8 gram veined, brecciated chondrite, fell during the summer of 1938 in Bloomington, Illinois. Its olivine, orthopyroxene and metal compositions (fo69, en74 and Fe52 Ni48 respectively) and its texture identify it as a brecciated LL6 chondrite of shock facies d. Shock melt glasses occur in Bloomington as sparse melt pockets and veins in clasts and as isolated masses in the black, clast-rich matrix. The vein glasses chemically resemble bulk LL-group chondrites and thus appear to reflect total melting of the host meteorite. The melt pocket and matrix glasses, like those described previously in L-group chondrites, have more varied compositions and are typically enriched in normative plagioclase. All glasses that we analyzed in Bloomington have FeO/MgO and Na/Al ratios similar to those of LL-group chondrites, indicating that melting of this meteorite involved neither a significant change in the oxidation state of iron nor loss of sodium to a vapor phase. Bloomington is a monomict breccia whose components formed in place as a result of a single episode of shock and attendant melting.  相似文献   
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SHRIMP dating of xenotime overgrowths on detrital zircon grains can constrain maximum durations since diagenesis and therefore provide minimum dates of sediment deposition. Thus, xenotime dating has significant economic application to Precambrian sediment-hosted ore deposits, such as Witwatersrand Au–U, for which there are no precise depositional ages. The growth history of xenotime in the Witwatersrand Supergroup is texturally complex, with several phases evident. The oldest authigenic xenotime 207Pb/206Pb age obtained in sandstone underlying the Vaal Reef is 2764 ± 5 Myr (1 σ), and most likely represents a mixture of diagenetic and hydrothermal growth. Nevertheless, this represents the oldest authigenic mineral age yet recorded in the sequence and provides a minimum age of deposition. Other xenotime data record a spread of ages that correspond to numerous post-diagenetic thermotectonic events (including a Ventersdorp event at ≈ 2720 Ma) up to the ≈2020 Ma Vredefort event.  相似文献   
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Kenai, located on the west coast of the Kenai Peninsula, Alaska, subsided during the great earthquake of AD 1964. Regional land subsidence is recorded within the estuarine stratigraphy as peat overlain by tidal silt and clay. Reconstructions using quantitative diatom transfer functions estimate co‐seismic subsidence (relative sea‐level rise) between 0.28±0.28 m and 0.70±0.28 m followed by rapid post‐seismic recovery. Stratigraphy records an earlier co‐seismic event as a second peat‐silt couplet, dated to ~1500–1400 cal. yr BP with 1.14±0.28 m subsidence. Two decimetre‐scale relative sea‐level rises are more likely the result of glacio‐isostatic responses to late Holocene and Little Ice Age glacier expansions rather than to co‐seismic subsidence during great earthquakes. Comparison with other sites around Cook Inlet, at Girdwood and Ocean View, helps in constructing regional patterns of land‐level change associated with three great earthquakes, AD 1964, ~950–850 cal. yr BP and ~1500–1400 cal. yr BP. Each earthquake has a different spatial pattern of co‐seismic subsidence which indicates that assessment of seismic hazard in southern Alaska requires an understanding of multiple great earthquakes, not only the most recent. All three earthquakes show a pre‐seismic phase of gradual land subsidence that marked the end of relative land uplift caused by inter‐seismic strain accumulation. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   
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 Satellite data offer a means of supplementing ground-based monitoring during volcanic eruptions, especially at times or locations where ground-based monitoring is difficult. Being directly and freely available several times a day, data from the advanced very high resolution radiometer (AVHRR) offers great potential for near real-time monitoring of all volcanoes across large (3000×3000 km) areas. Herein we describe techniques to detect and locate activity; estimate lava area, thermal flux, effusion rates and cumulative volume; and distinguish types of activity. Application is demonstrated using data for active lavas at Krafla, Etna, Fogo, Cerro Negro and Erebus; a pyroclastic flow at Lascar; and open vent systems at Etna and Stromboli. Automated near real-time analysis of AVHRR data could be achieved at existing, or cheap to install, receiving stations, offering a supplement to conventional monitoring methods. Received: 21 January 1997 / Accepted: 3 April 1997  相似文献   
9.
Parameters for ion exchange selectivity and aluminium hydroxide dissolution in the soil chemical submodels used in applications of the Birkenes model and of MAGIC are compared and several discrepancies identified for organic soils. A laboratory column simulation of the soil chemical submodels is proposed and applied to soils from the Loch Dee area in Galloway. Experimental results were well predicted by a simplified version of MAGIC, with ion exchange selectivity parameters similar to those used in a previous simulation of one subcatchment of Loch Dee. The aluminium hydroxide dissolution parameter used previously was found to be too low for the organic soil materials, where a value of 106 predicted the experimental results more closely. The model developed also included a simple silicate weathering reaction to release base cations into the system. It is concluded that such simple laboratory simulations are useful for independent calibration of the soil chemical submodel of catchment models.  相似文献   
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