Early solar system aqueous activity: K isotope evidence from Allende     

Yun Jiang  Piers Koefoed  Olga Pravdivtseva  Heng Chen  Chun‐Hui Li  Fang Huang  Li‐Ping Qin  Jia Liu  Kun Wang 《Meteoritics & planetary science》2021,56(1):61-76

The alkali element K is moderately volatile and fluid mobile; thus, it can be influenced by both primary processes (evaporation and recondensation) in the solar nebula and secondary processes (thermal and aqueous alteration) in the parent body. Since these primary and secondary processes would induce different isotopic fractionations, K isotopes could become a potential tracer to distinguish them. Using recently developed methods with improved precision (0.05‰, 95% confidence interval), we systematically measured the K isotopic compositions and major/trace elemental compositions of chondritic components (18 chondrules, 3 CAIs, 2 matrices, and 5 bulks) in the carbonaceous chondrite fall Allende. Among all the components analyzed in this study, CAIs, which formed initially under high‐temperature conditions in the solar nebula and were dominated by nominally K‐free refractory minerals, have the highest K₂O content (average 0.53 wt%) and have K isotope compositions most enriched in heavy isotopes (δ⁴¹K: ?0.30 to ?0.25‰). Such an observation is consistent with previous petrologic studies that show CAIs in Allende have undergone alkali enrichment during metasomatism. In contrast, chondrules contain lower K₂O content (0.003–0.17 wt%) and generally lighter K isotope compositions (δ⁴¹K: ?0.87‰ to ?0.24‰). The matrix and bulks are nearly identical in K₂O content and K isotope compositions (0.02–0.05 wt%; δ⁴¹K: ?0.62 to ? 0.46‰), which are, as expected, right in the middle of CAIs and chondrules. This strongly indicates that most of the chondritic components of Allende suffered aqueous alteration and their K isotopic compositions are the ramification of Allende parent‐body processing instead of primary nebular signatures. Nevertheless, we propose the small K isotope fractionations observed (< 1‰) among Allende components are likely similar to the overall range of K isotopic fractionation that occurred in nebular environment. Furthermore, the K isotope compositions seen in the components of Allende in this study are consistent with MC‐ICP‐MS analyses of the components in ordinary chondrites, which also show an absence of large (10‰) isotope fractionations. This is not expected as evaporation experiments in nebular conditions suggest there should be large K isotopic fractionations. Nevertheless, possible nebular processes such as chondrules back exchanging with ambient gas when they formed could explain this lack of large K isotopic variation.  相似文献   

基于LocaSpaceViewer的地理信息技术应用教学设计与反思     

陶佳  李青 《地理教学》2020,(2):53-55

本文基于笔者运用LocaSpaceViewer软件完成人教版地理必修3“地理信息技术在区域地理环境研究中的应用”的教学内容,总结反思教学过程中出现的问题,并提出改进的建议和措施。  相似文献   

贵州夜郎湖表层水体地球化学昼夜变化及其影响因素     

王家录  任娟  王勇  李维杰  娄昭  陈佳 《热带地理》2020,40(2):335-345

为探究岩溶水库水文地球化学行为过程,对贵州普定夜郎湖表层水体进行了为期3 d的高分辨率昼夜监测。结果表明：1）多变的天气和水文条件叠加导致水体离子指标昼夜变化不显著,规律性较差。而水温、DO、pH值、SpC、SIc、pCO₂等常规理化指标受水温变化和生物作用表现出明显的昼夜波动。2）利用亨利常数和主成分分析,得到温度变化、生物作用、人类活动、水库的蓄水与放水对夜郎湖水库水文地球化学特征变化的贡献率分别为21.66%、17.28%、14.08%和10.22%,说明作用于水库水文地球化学行为的因子具有多元性。3）δ ¹⁸O表现出与DO一致的波动趋势,即白天上升,晚上下降,反映在短时间尺度上,氢氧稳定同位素变化受控于生物过程（主要是呼吸作用过程）;而对比水库水体和大气降水的d-excess（d值）发现,水库水体的d值（8.21‰）显著偏低于当地大气降水的d值（9.64‰）,说明在长时间尺度上,主要受蒸发效应引起的不平衡分馏影响。  相似文献   

三元插层材料的合成及其在聚丙烯老化中的应用          下载免费PDF全文

郭凡  刘志启  王庭胜  李丽娟  李娜 《盐湖研究》2020,28(3)

以FeCl3?6H2O、NiCl2?6H2O、MgCl2?6H2O为原料，以NaOH为沉淀剂采用水热法合成了镁镍铁水滑石 (MgNiFe-LDH)，通过X射线衍射 (XRD)、傅里叶变换红外光谱 (FTIR) 和扫描电镜 (SEM) 分析了MgNiFe-LDH结构及形貌，探讨了不同陈化时间和水热温度对MgNiFe-LDH合成的影响。将制得的MgNiFe-LDH添加至聚丙烯 (PP) 中，制备MgNiFe-LDH/PP复合材料，通过对材料的加速老化测其力学性能，研究了添加MgNiFe-LDH前后材料力学性能的差异。研究结果表明，当Mg2+:Ni2+:Fe3+=2:1:1，反应温度为140℃、陈化时间为24 h时，合成的MgNiFe-LDH为片状，形貌较为规整，颗粒粒径约为2μm；经加速老化后，填充MgNiFe-LDH 复合材料的抗老化性能优于纯PP，当MgNiFe-LDH的填充量为6 wt% 复合材料拉伸强度不变，可明显提高PP的抗老化性能。  相似文献   

云南曲靖刘家冲剖面关底组中的鱼类微体化石及其地层学意义     

王建华  赵文金  朱敏  李强  蔡家琛  张娜  彭礼健  罗彦超 《地学前缘》2020,27(6):329-340

云南曲靖地区的关底组产出世界闻名的潇湘脊椎动物群(Xiaoxiang Vertebate Fauna),但其地层的划分对比和时代归属一直存有争议,特别是其下部地层的划分及时代归属争议最大。通过在曲靖城南以关底组下段地层为主的刘家冲剖面上开展详细的野外及室内地层古生物学研究工作,文章厘清了该剖面上的志留纪地层,并依据采自数个层位样品中丰富的鱼类微体化石材料探讨了关底组下部的地质时代。研究结果表明:刘家冲剖面上出露的志留纪地层根据岩性变化特征可划分为关底组Ⅰ段(岳家山段)、Ⅱ段(崇家湾段)和Ⅲ段(彩莲段);Ⅰ段的下部以浅黄色、浅黄绿色含砾粉砂质泥岩、钙质粉砂岩为主,未见化石,而上部以深灰色、灰黑色页岩为主,含少量腕足类Lingula sp.及双壳类;Ⅱ段则以灰绿色、暗紫红色页岩互层、并夹薄层状灰岩为主,从下往上灰岩夹层逐渐增多,含丰富的腕足类、海百合茎等无脊椎动物化石及鱼类微体化石;在关底组Ⅲ段地层中首次发现的鱼类微体化石多样性高,门类比较齐全,包括无颌类、盾皮鱼类、棘鱼类和硬骨鱼类四大早期脊椎动物类群,从鱼群组成面貌上看隶属于潇湘脊椎动物群扬子鱼类组合(Yangtze Fish Assemblage)。笔者主要依据对其中棘鱼类的全球对比分析研究,并在结合牙形类等无脊椎动物化石研究进展及新认识的基础上,深入探讨了关底组下部Ⅰ段及Ⅱ段的地质时代。关底组Ⅱ段的时代应为志留纪罗德洛世高斯特晚期(late Gorstian, Ludlow),关底组Ⅰ段含砾岩层之上、含盾皮鱼类“王氏鱼”(Wangolepis)的地层,则应归入罗德洛世高斯特早期(early Gorstian, Ludlow),而在该剖面上尚未发现鱼类化石的关底组Ⅰ段下部,目前还不能确定全部归入高斯特阶(Gorstian),有可能会下延到温洛克统(Wenlock)之中。文章中相关工作的开展,不仅为中国志留纪生物地层的精深研究提供了古鱼类学方面的可靠证据,而且为探讨早期脊椎动物演化提供了新的地质年代意见。  相似文献   

The evolution of the spatial-temporal patterns of global energy security since the 1990s     

Wang  Qiang  Xu  Linglin  Li  Na  Du  Xue  Wu  Shidai  Tian  Lanlan  Wu  Chenlu 《地理学报(英文版)》2019,29(8):1245-1260

Journal of Geographical Sciences - In this study, we developed an energy security evaluation model (ESEM) from three dimensions, energy supply-transport security, safety of energy utilization, and...  相似文献   

南海盐致环流对台风降水的响应特征分析     

刘娜  王桂华  巩远发  刘磊 《热带海洋学报》2019,38(3):13-21

本文采用多源卫星遥感数据通过统计分析的方法研究了17年间(2000—2016年)南海夏季(6—9月)台风对该海域降水、淡水通量的贡献及其可能导致的环流异常。主要结论如下: 1) 台风是南海中北部降水的重要影响因子, 可导致日平均降水量增加12mm, 约占南海夏季日平均降水(25mm·d ^-1)的一半, 且西北太平洋台风和南海“土台风”产生的降水分布存在显著的区域和强度差异; 2) 夏季, 南海由淡水通量引起的盐致环流表现为以海南岛东南部海域为中心的弱气旋式, 其流量量级约为-0.15Sv, 约占同期风生环流流量(约为-1.5Sv)的10%; 3) 夏季, 台风带来的降水使得南海中北部的气旋式盐致环流增强, 且西北太平洋台风降水导致的淡水通量变化引起的盐致环流强度要强于南海“土台风”。  相似文献   

Hydrological management strategies for the control of algal blooms in regulated lowland rivers     

Jian Li  Wei Yin  Haiyan Jia  Xiaokang Xin 《水文研究》2021,35(6):e14171

Reservoirs of lowland floodplain rivers with eutrophic backgrounds cause variations in the hydrological and hydraulic conditions of estuaries and low-dam reservoir areas, which can promote planktonic algae to proliferate and algal bloom outbreaks. Understanding the ecological effects of variations in hydrological and hydraulic processes in lowland rivers is important for algal bloom control. In this study, the middle and lower reaches of the Han River, China, a typical regulated lowland river with a eutrophic background, are selected. Based on the effect of hydrological and hydraulic variability on algal blooms, a hydrological management strategy for river algal bloom control is proposed. The results showed that (a) differences in river morphology and background nutrient levels cause significant differences in the critical threshold flow velocities for algal bloom outbreaks between natural river and low-dam reservoir sections; there is no uniform threshold flow velocity for algal bloom control. (b) There are significant differences in the river hydrological/hydraulic conditions between years with and without algal blooms. The average river flow, water level and velocity in years with algal blooms are significantly lower than those in years without algal blooms. (c) For different river sections where algal blooms occur and to meet the threshold flow velocities, the joint operation of cascade reservoirs and diversion projects is an effective method to prevent and control algal blooms in regulated lowland rivers. This study is expected to deepen our understanding of the ecological significance of special hydrological processes and guide algal bloom management in regulated lowland rivers.  相似文献   

基于Sentinel-2的潮间红树林提取方法   总被引：1，自引：0，他引：1  

徐芳  张英  翟亮  刘佳  谷祥辉 《测绘通报》2020,(2):49-54

位于潮间带的红树林可能在高潮时被海水淹没的特点，使得传统的植被提取方法在红树林信息提取方面存在局限性。本文在对比分析了出露的红树林、高潮水位淹没的红树林、海水水体的光谱特征后，提出了一种利用归一化潮间红树林指数（NIMI）提取潮间带红树林的方法。该指数是由植被强吸收的红波段，强反射的两个红边波段和近红外波段组成的归一化表达式。利用该指数对福建省龙海九龙江口湿地的红树林进行了分类提取，提取结果与高分二号影像目视验证和现场调查结果进行了对照。结果显示，该方法提取红树林的用户精度达到93.98%，并显著优于利用归一化水体指数（NDWI）、归一化植被指数（NDVI）及随机森林的结果。  相似文献   

极端条件下心墙泥浆料的渗透反滤试验研究     

左永振  赵娜 《岩土力学》2020,41(2):520-526

高土石心墙坝的渗透稳定性在很大程度上依赖于反滤层对心墙料的反滤保护作用。心墙在大坝蓄水和长期运行的条件下，要经历复杂的填筑加载、浸水饱和与水荷载的作用，在差异沉降、复杂结构应力作用、水力劈裂和渗透水流作用下，心墙一旦出现裂缝，其渗透稳定性及反滤层的保护作用就将面临严峻的考验。针对这一问题，设计了专门非常规的抛填土料反滤试验和泥浆渗透反滤试验，模拟心墙裂缝条件下其颗粒被冲刷起动后，被反滤料阻挡和淤积过程。试验结果表明，心墙料和反滤料满足反滤准则条件下，心墙颗粒被拦截和淤积在反滤层上游表面，反滤料能有效防止心墙颗粒的流失，反滤层在极端条件下对心墙料仍能起到有效的反滤保护作用。  相似文献