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1.
Abstract— The Monahans H‐chondrite is a regolith breccia containing light and dark phases and the first reported presence of small grains of halite. We made detailed noble gas analyses of each of these phases. The 39Ar‐40Ar age of Monahans light is 4.533 ± 0.006 Ma. Monahans dark and halite samples show greater amounts of diffusive loss of 40Ar and the maximum ages are 4.50 and 4.33 Ga, respectively. Monahans dark phase contains significant concentrations of He, Ne and Ar implanted by the solar wind when this material was extant in a parent body regolith. Monahans light contains no solar gases. From the cosmogenic 3He, 21Ne, and 38Ar in Monahans light we calculate a probable cosmic‐ray, space exposure age of 6.0 ± 0.5 Ma. Monahans dark contains twice as much cosmogenic 21Ne and 38Ar as does the light and indicates early near‐surface exposure of 13–18 Ma in a H‐chondrite regolith. The existence of fragile halite grains in H‐chondrites suggests that this regolith irradiation occurred very early. Large concentrations of 36Ar in the halite were produced during regolith exposure by neutron capture on 35Cl, followed by decay to 36Ar. The thermal neutron fluence seen by the halite was (2–4) × 1014 n/cm2. The thermal neutron flux during regolith exposure was ~0.4‐0.7 n/cm2/s. The Monahans neutron fluence is more than an order of magnitude less than that acquired during space exposure of several large meteorites and of lunar soils, but the neutron flux is lower by a factor of ≤5. Comparison of the 36Arn/21Necos ratio in Monahans halite and silicate with the theoretically calculated ratio as a function of shielding depth in an H‐chondrite regolith suggests that irradiation of Monahans dark occurred under low shielding in a regolith that may have been relatively shallow. Late addition of halite to the regolith can be ruled out. However, irradiation of halite and silicate for different times at different depths in an extensive regolith cannot be excluded.  相似文献   
2.
A new method to determine semi-analytical solutions of one-dimensional contaminant transport problem with nonlinear sorption is described. This method is based on operator splitting approach where the convective transport is solved exactly and the diffusive transport by finite volume method. The exact solutions for all sorption isotherms of Freundlich and Langmuir type are presented for the case of piecewise constant initial profile and zero diffusion. Very precise numerical results for transport with small diffusion can be obtained even for larger time steps (e.g., when the Courant-Friedrichs-Lewy (CFL) condition failed).  相似文献   
3.
Many Vertisols in Tigray, Ethiopia, typically carry a discontinuous rock fragment (RF, size 0.5–> 40 · 10− 2 m) cover with 10 to 100 RFs m− 2. Such RF mulches are of agricultural and environmental significance because they influence the water balance in the underlying soils and the crop yield. Natural RF concentrations are mostly considered as eolian or hydraulic lag deposits, or as the result of lateral transport over the soil surface from a rock outcrop, upslope. In cultivated areas RF mulches can develop by tillage.This paper presents the case of a natural RF mulch whose lithology indicates that the RFs are up-squeezed by the local Vertisol. The study site is located in the pass of Enda Maryam, Tigray, Northern Ethiopia (39°8′ E and 13°36′ N). A circular area of 10 m diameter, about 200 m away from the water divide in the valley has been cleared annually between 01/1999 and 05/2003. During this period, 625 RFs, 17 being > 7.5 · 10− 2 m in size, totalling a mass of nearly 62 kg, have been collected. After correction for measurement procedures, the rate of RF up-warping by the Vertisol at Enda Maryam is assessed at 5 RFs m− 2 in 3 years. At this rate of appearance, the formation of current RF concentrations on top of active valley Vertisols is only a matter of 101–2 years, provided the availability of RFs below the soil surface.Although important underground displacements were measured in the Vertisol between 01/1999 and 05/2002, the supposed link between up-squeezing of RFs and plastic deformations of ‘chimney’, ‘diapir’ or ‘intrusion’-like type in the Vertisol could not be evidenced. Instead, RFs are clearly concentrated on the soil surface as well as in depth, along the existing vertical desiccation cracks, often > 1 m deep which display polygonal configurations at the soil surface. Further, bundles of slickensides containing some RFs, have been mapped at the base of the Vertisol. The slickenside configuration suggests that the RF-bearing substrate is being scraped off.While the underground displacement of RFs along active slickensides seems normal, the process of RFs ascending in ‘upright’ position in the edge of desiccation cracks needs explanation. The closure of a desiccation crack is a peristaltic-like movement, following ascent or descent of the capillary fringe. It is hypothesized that this movement gradually pushes the RF to the surface or to another place or level in the soil profile where the crack closes in last instance.The apparent young age of the valley Vertisol mulches in Ethiopia might indicate the very recent formation of yearly recurrent desiccation cracks of Vertisols in the area. Available information confirms that most valleys in the study area used to be perennially marshy. Under these conditions no movements of RFs in the soil profile are expected to occur. Gullying, leading to pronounced seasonal desiccation of the Vertisols, started in several cases not more than 50 years ago.  相似文献   
4.
5.
High-resolution spatial numerical models of metallurgical properties constrained by geological controls and more extensively by measured grade and geomechanical properties constitute an important part of geometallurgy. Geostatistical and other numerical techniques are adapted and developed to construct these high-resolution models accounting for all available data. Important issues that must be addressed include unequal sampling of the metallurgical properties versus grade assays, measurements at different scale, and complex nonlinear averaging of many metallurgical parameters. This paper establishes techniques to address each of these issues with the required implementation details and also demonstrates geometallurgical mineral deposit characterization for a copper–molybdenum deposit in South America. High-resolution models of grades and comminution indices are constructed, checked, and are rigorously validated. The workflow demonstrated in this case study is applicable to many other deposit types.  相似文献   
6.
Impact studies of catchment management in the developing world rarely include detailed hydrological components. Here, changes in the hydrological response of a 200‐ha catchment in north Ethiopia are investigated. The management included various soil and water conservation measures such as the construction of dry masonry stone bunds and check dams, the abandonment of post‐harvest grazing, and the establishment of woody vegetation. Measurements at the catchment outlet indicated a runoff depth of 5 mm or a runoff coefficient (RC) of 1·6% in the rainy season of 2006. Combined with runoff measurements at plot scale, this allowed calculating the runoff curve number (CN) for various land uses and land management techniques. The pre‐implementation runoff depth was then predicted using the CN values and a ponding adjustment factor, representing the abstraction of runoff induced by the 242 check dams in gullies. Using the 2006 rainfall depths, the runoff depth for the 2000 land management situation was predicted to be 26·5 mm (RC = 8%), in line with current RCs of nearby catchments. Monitoring of the ground water level indicated a rise after catchment management. The yearly rise in water table after the onset of the rains (ΔT) relative to the water surplus (WS) over the same period increased between 2002–2003 (ΔT/WS = 3·4) and 2006 (ΔT/WS >11·1). Emerging wells and irrigation are other indicators for improved water supply in the managed catchment. Cropped fields in the gullies indicate that farmers are less frightened for the destructive effects of flash floods. Due to increased soil water content, the crop growing period is prolonged. It can be concluded that this catchment management has resulted in a higher infiltration rate and a reduction of direct runoff volume by 81% which has had a positive influence on the catchment water balance. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   
7.
A total of 81 samples (244 specimens) from Upper Cretaceous Indus Molasse and Middle to Upper Cretaceous Dras Flyschoids of the Indus-Tsangpo suture zone in Ladakh (northwest Himalaya) has been studied by thermal demagnetization methods.Both formations showed a characteristic magnetization component indicative for equatorial to low northern palaeolatitudes of acquisition. Similar palaeolatitudes have been obtained before from secondary magnetization components of Early Tertiary age in the Ladakh Intrusives and in the Tibetan Sedimentary Series of central Nepal. The present characteristic components are interpreted likewise as secondary magnetizations which stabilized between 50 and 60 m.y. ago, during Greater India's collision with Asia's southern margin.The Dras Flyschoids show another magnetic component which, in case of primary origin, indicates acquisition at a low southern palaeolatitude. If correct, this interpretation supports recent suggestions for Late Cretaceous obduction of an island arc on Greater India's northern margin.  相似文献   
8.
Gullying has been widespread in the Ethiopian Highlands during the 20th century. It threatens the soil resource, lowers crop yields in intergully areas through enhanced drainage and desiccation, and aggravates flooding and reservoir siltation. Knowing the age and rates of gully development during the last few decades will help explain the reasons for current land degradation. In the absence of historical written or photographic documentation, the AGERTIM method (Assessment of Gully Erosion Rates Through Interviews and Measurements) has been developed. It comprises measurements of contemporary gully volumes, monitoring of gully evolution over several years and semi‐structured interview techniques. Gully erosion rates in the Dogu'a Tembien District, Tigray, Ethiopia, were estimated in three representative case‐study areas. In Dingilet, gullying started around 1965 after gradual environmental changes (removal of vegetation from cropland in the catchment and eucalyptus plantation in the valley bottom); rill‐like incisions grew into a gully, which increased rapidly in the drier period between 1977 and 1990. The estimated evolution of the total gully volume in the other areas show patterns similar to those of the Dingilet gully. Average gully erosion rate over the last 50 years is 6·2 t ha?1 a?1. Since 1995, no new gullies have developed in the study area. Area‐specific short‐term gully erosion rates are now on average 1·1 t ha?1 a?1. The successful application of the AGERTIM method requires an understanding of the geomorphology of the study area and an integration of the researchers with the rural society. It reveals that rapid gully development in the study area is some 50 years old and is mainly caused by human‐induced environmental degradation. Under the present‐day conditions of ‘normal’ rain and catchment‐wide soil and water conservation, gully erosion rates are decreasing. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   
9.
We report lightcurves for five asteroids from the inner main belt—(1703) Barry, (2590) Mourão, (4022) Nonna, (5171) Augustesen, (23031) 1999 XX7—and for two near-Earth asteroids—(100004) 1983 VA, (144922) 2005 CK38—obtained at Modra Observatory as a part of binary asteroid photometric campaign. Estimated synodic rotational periods and amplitudes of their composite lightcurves were as follows: 107.1 ± 0.5 h, 0.5 mag for (1703) Barry; 15.59 ± 0.01 h, 0.49 mag for (2590) Mourão; 2.5877 ± 0.0005 h, 0.08 mag for (4022) Nonna; 474 ± 10 h, 0.8 mag for (5171) Augustesen; 3.075 ± 0.001 h, 0.43 mag for (23031) 1999 XX7; 3.1643 ± 0.0009 h, 0.11 mag for (100004) 1983 VA; 4.7894 ± 0.0005 h, 0.27 mag for (144922) 2005 CK38. The slow rotator (5171) Augustesen and possibly also (1703) Barry appear to be tumblers, though their precession periods can not be estimated from the available data.  相似文献   
10.
Copper and Zn metals are produced in large quantities for different applications. During Cu production, large amounts of Cu and Zn can be released to the environment. Therefore, the surroundings of Cu smelters are frequently metal-polluted. We determined Cu and Zn concentrations and Cu and Zn stable isotope ratios (δ65Cu, δ66Zn) in three soils at distances of 1.1, 3.8, and 5.3 km from a Slovak Cu smelter and in smelter wastes (slag, sludge, ash) to trace sources and transport of Cu and Zn in soils. Stable isotope ratios were measured by multicollector inductively coupled plasma mass spectrometry (MC-ICP-MS) in total digests. Soils were heavily contaminated with concentrations up to 8087 μg g−1 Cu and 2084 μg g−1 Zn in the organic horizons. The δ65Cu values varied little (−0.12‰ to 0.36‰) in soils and most wastes and therefore no source identification was possible. In soils, Cu became isotopically lighter with increasing depth down to 0.4 m, likely because of equilibrium reactions between dissolved and adsorbed Cu species during transport of smelter-derived Cu through the soil. The δ66ZnIRMM values were isotopically lighter in ash (−0.41‰) and organic horizons (−0.85‰ to −0.47‰) than in bedrock (−0.28‰) and slag (0.18‰) likely mainly because of kinetic fractionation during evaporation and thus allowed for separation of smelter-Zn from native Zn in soil. In particular in the organic horizons large variations in δ66Zn values occur, probably caused by biogeochemical fractionation in the soil-plant system. In the mineral horizons, Zn isotopes showed only minor shifts to heavier δ66Zn values with depth mainly because of the mixing of smelter-derived Zn and native Zn in the soils. In contrast to Cu, Zn isotope fractionation between dissolved and adsorbed species was probably only a minor driver in producing the observed variations in δ66Zn values. Our results demonstrate that metal stable isotope ratios may serve as tracer of sources, vertical dislocation, and biogeochemical behavior in contaminated soil.  相似文献   
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