High-pressure phase behavior of MnTiO<Subscript>3</Subscript>: decomposition of perovskite into MnO and MnTi<Subscript>2</Subscript>O<Subscript>5</Subscript>     

Taku Okada  Takehiko Yagi  Daisuke Nishio-Hamane 《Physics and Chemistry of Minerals》2011,38(4):251-258

The phase relations and compression behavior of MnTiO₃ perovskite were examined using a laser-heated diamond-anvil cell, X-ray diffraction, and analytical transmission electron microscopy. The results show that MnTiO₃ perovskite becomes unstable and decomposes into MnO and orthorhombic MnTi₂O₅ phases at above 38 GPa and high temperature. This is the first example of ABO₃ perovskite decomposing into AO + AB₂O₅ phases at high pressure. The compression behavior of volume, axes, and the tilting angle of TiO₆ octahedron of MnTiO₃ perovskite are consistent with those of other A²⁺B⁴⁺O₃ perovskites, although no such decomposition was observed in other perovskites. FeTiO₃ is also known to decompose into two phases, instead of transforming into the CaIrO₃-type post-perovskite phase and we argue that one of the reasons for the peculiar behavior of titanate is the weak covalency of the Ti–O chemical bonds.  相似文献   

Theoretical and experimental evidence for the post-cotunnite phase transition in zirconia at high pressure     

Daisuke Nishio-Hamane  Haruhiko Dekura  Yusuke Seto  Takehiko Yagi 《Physics and Chemistry of Minerals》2015,42(5):385-392

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Announcement     

K. Yagi  S. Akimoto 《Marine Geophysical Researches》1988,9(2):195-195

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The response of the mid-latitude thermospheric wind to magnetic activity     

T. Yagi  P.L. Dyson 《Planetary and Space Science》1985,33(4):461-467

Observations of the thermospheric wind at a mid-latitude station have been made using a Fabry-Perot interferometer to measure the Doppler shift of the nighttime OI emission at 630 nm. The results from 12 summer nights show that the zonal wind has a distinct feature associated with magnetic activity. The zonal wind first reverses and becomes westward. The maximum strength of the westward wind, its duration, and the maximum strength of the subsequent eastward wind all increase with increasing magnetic activity. The meridional wind is less consistent in its behaviour. It is normally equatorward but during magnetic activity it can increase, decrease, or even reverse, although it is consistently equatorward and of increased strength after 02.00 L.T. The initial reversal of the zonal wind is consistent with changes in the wind expected as a result of convective electric fields penetrating to mid-latitudes indicating that these electric fields modify the mid-latitude wind pattern before effects due to auroral heating reach mid-latitudes. The reversal of the zonal wind back to eastward may also be the result of electric field effects. The large variability of the meridional wind, to the extent that it becomes poleward at times, indicates the importance of wind sources equatorward of the observatory.  相似文献   

Elasticity of CaIrO<Subscript>3</Subscript> with perovskite and post-perovskite structure     

Ken?NiwaEmail author  Takehiko?Yagi  Kenya?Ohgushi 《Physics and Chemistry of Minerals》2011,38(1):21-31

Compression behaviors of CaIrO₃ with perovskite (Pv) and post-perovskite (pPv) structures have been investigated up to 31.0(1.0) and 35.3(1) GPa at room temperature, respectively, in a diamond-anvil cell with hydrostatic pressure media. CaIrO₃ Pv and pPv phases were compressed with the axial compressibility of β _a > β _c > β _b and β _b > β _a > β _c, respectively and no phase transition was observed in both phases up to the highest pressure in the present study. The order of axial compressibility for pPv phase is consistent with the crystallographic consideration for layer structured materials and previous experimental results. On the other hand, Pv phase shows anomalous compression behavior in b axis, which exhibit constant or slightly expanded above 13 GPa, although the applied pressure remained hydrostatic. Volume difference between Pv and pPv phases was gradually decreased with increasing pressure and this is consistent with the results of theoretical study based on the ab initio calculation. Present results, combined with theoretical study, suggest that these complicate compression behaviors in CaIrO₃ under high pressure might be caused by the partially filled electron of Ir⁴⁺. Special attention must be paid in case of using CaIrO₃ as analog materials to MgSiO₃, although CaIrO₃ exhibits interesting physical properties under high pressure.  相似文献   

Geological and geomorphological characteristics of landslides triggered by the 2004 Mid Niigta prefecture earthquake in Japan   总被引：8，自引：0，他引：8  

Masahiro Chigira  Hiroshi Yagi 《Engineering Geology》2006,82(4):202-221

The 2004 Mid Niigta prefecture earthquake (M_JMA 6.8) triggered more than one thousand landslides in the Miocene to Quaternary sedimentary rocks in Japan. The most common landslides were shallow disrupted landslides on steep slopes, which has been common in many previous disastrous earthquakes in the world. The Mid Niigta prefecture earthquake also triggered more than one hundred deep landslides, providing valuable information on the conditions for their occurrence. A field investigation and the interpretation of aerial photographs taken before and after the earthquake suggest that reactivation of existing landslides and undercutting of slopes are the most important factors for deep landslides to be triggered by earthquakes. In addition, planar sliding surfaces seem to be essential for the generation of catastrophic landslides triggered by this earthquake. Planar bedding–parallel sliding surfaces were formed at the boundary between the overlying permeable sandstone and underlying siltstone or along the bedding planes of alternating beds of sandstone and siltstone. Sliding surfaces along the slope-parallel oxidation front were formed in the area of black mudstone. New landslides (rockslide-avalanches) occurred with the sliding surfaces in a several-cm thick tuff interbedded in siltstone. One rockslide-avalanche occurred on a slope where buckling deformation preceded the earthquake. Gentle valley bottom sediments were mobilized in many locations, probably because they were saturated and partial liquefaction had occurred due to the earthquake shaking.  相似文献   

Raman spectra of methane hydrate up to 86 GPa     

Shin-Ichi Machida  Hisako Hirai  Taro Kawamura  Yoshitaka Yamamoto  Takehiko Yagi 《Physics and Chemistry of Minerals》2007,34(1):31-35

High-pressure Raman studies of methane hydrate were performed using a diamond anvil cell in the pressure range of 0.1–86 GPa at room temperature. Raman spectra of the methane molecules revealed that new softened intramolecular vibration mode of ν ₁ appeared at 17 GPa and that the splitting of vibration mode of ν ₃ occurred at 15 GPa. The appearance of these two modes indicates that an intermolecular attractive interaction increases between the methane molecules and the host water molecules and between the neighboring methane molecules. These interactions might result in the exceptional stability of a high-pressure structure, a filled ice Ih structure (FIIhS) for methane hydrate, up to 40 GPa. At 40 GPa, a clear change in the slope of the Raman shift versus pressure occurred, and above 40 GPa the Raman shift of the vibration modes increased monotonously up to 86 GPa. A previous XRD study showed that the FIIhS transformed into another new high-pressure structure at 40 GPa. The change in the Raman spectra at 40 GPa may be induced by the transition of the structure.  相似文献   

Slip-weakening distance in dynamic rupture of in-slab normal-faulting earthquakes   总被引：1，自引：0，他引：1  

Takeshi Mikumo  Yuji Yagi 《Geophysical Journal International》2003,155(2):443-455

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The bearing of the system CaMgSi₂O₆CaAl₂SiO₆CaFeAlSiO₆ on fassaitic pyroxene     

Kosuke Onuma  Masahide Akasaka  Kenzo Yagi 《Lithos》1981,14(3):173-182

The system CaMgSi₂O₆CaAl₂SiO₆CaFeAlSiO₆ has been studied in air at 1 atm. The phase assemblage at subsolidus temperatures in the CaMgSi₂O₆-rich portion is Cpx + An + Mel and that in the CaMgSi₂O₆-poor portion Cpx + An + Mel + Sp. At subsolidus temperatures the sigle-phase field of clinopyroxene increases with an increase in the CaFeAlSiO₆ component of the system. The Al₂O₃ content of clinopyroxene, however, continues to increase beyond the single-phase field and attains at least 16.04 wt.% Al₂O₃ with 3.9 wt.% Fe₂O₃. The stability field of fassaite in the system over a range of pressures and oxygen fugacities has been estimated from data in the literature as well as the present data. The CaFeAlSiO₆ content of fassaite is dependent on oxygen fugacity, but is not influenced by pressure. The stability field is strongly influenced by oxygen fugacity at low and high pressure, and decreases with decreasing oxygen fugacity. Clinopyroxenes in both volcanic and metamorphic rocks from various localities, when plotted on the CaMgSi₂O₆CaAl₂SiO₆CaFeAlSiO₆ triangle, show that there is no compositional gap between diopside and fassaitic pyroxene in metamorphic rocks, and that the fassaitic pyroxene in alkalic rocks becomes richer in both CaAl₂SiO₆ and CaFeAlSiO₅ components as crystallization proceeds. These results agree with those obtained in the experimental study.  相似文献   

Genesis and differentiation of nephelinitic magma     

Yagi  K.  Onuma  K. 《Bulletin of Volcanology》1978,41(4):466-472

Bulletin of Volcanology - The possibility of formation of nephelinite magma from picrite magma by separation of eclogitic fraction is discussed from experimental results on some picritic rocks....  相似文献