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The Okchon black shale in Korea provides a typical example of natural geological materials enriched with potentially toxic elements. The Chung-Joo, Duk-Pyung, Geum-Kwan, I-Won, Bo-Eun and Chu-Bu areas are underlain by these black shales and slates of the Guryongsan Formation or the Changri Formation, which are parts of the Okchon Group in the central part of the southern Korean Peninsula. In order to investigate the enrichment levels and dispersion patterns of potentially toxic elements in the rock–soil–plant system, environmental geochemical surveys were undertaken in the above six study areas in the Okchon Zone. After appropriate preparation, rock and soil samples were analyzed for potentially toxic elements by instrumental neutron activation analysis (INAA) and inductively coupled plasma atomic emission spectrometry (ICP-AES), and plant samples by atomic absorption spectrometry (AAS). In particular, Ba, Cd, Mo, V and U in Okchon black shales are highly enriched, and their mean concentrations are significantly higher than those in black slates. These elements are geochemically associated, and might be enriched simultaneously. The highest mean concentrations of 42.0 μg g−1 As, 2100 μg g−1 Ba, 10.9 μg g−1 Cd, 213 μg g−1 Mo, 83 μg g−1 U, 938 μg g−1 V and 394 μg g−1 Zn are found in black shales from the Duk-Pyung area. Mean concentrations of As, Mo and U in soils overlying black shales occurring in the Duk-Pyung area (30 μg g−1 As, 24 μg g−1 Mo and 50 μg g−1 U) and Chu-Bu area (39 μg g−1 As, 15 μg g−1 Mo and 27 μg g−1 U) are higher than the permissible level. Enrichment index values of the six study areas decrease in the order of Duk-Pyung > Chu-Bu > Bo-Eun > Chung-Joo > Geum-Kwan = I-Won areas. Relationships between trace element concentrations in soils and plants are significantly correlated, and the biological absorption coefficients (BAC) in plants are in the order of Cd > Zn = Cu > Pb, which suggests that Cd is more bioavailable to plants than the other elements. Cadmium concentrations in plant species decrease in the order of chinese cabbage > red pepper > soybean = sesame > rice stalk > corn > rice grain. From the result of sequential extraction analysis of soils, relatively high proportions of Cu, Pb and Zn are present as residual fractions, and that of Cd as non-residual fractions. Cadmium occurs predominantly as exchangeable/water-acid soluble phase in soils, and this is in agreement with the findings of high Cd concentrations in plants. 相似文献
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Simultaneous stabilization of arsenic, lead, and copper in contaminated soil using mixed waste resources 总被引：1，自引：0，他引：1
Keun-Young Lee Deok Hyun Moon Sang-Ho Lee Kyoung-Woong Kim Kyung-Hoon Cheong Jeong-Hun Park Yong Sik Ok Yoon-Young Chang 《Environmental Earth Sciences》2013,69(6):1813-1820
In the present study, stabilization treatment using waste resource stabilizers was performed for soil contaminated with As and heavy metals (Pb and Cu). Calcined oyster shell (COS) and coal mine drainage sludge (CMDS) were used as a mixed stabilizing agent for a wet-curing duration of 28 days. After the stabilization treatment, the treatment process efficiency was evaluated by the results of various batch- and column-leaching tests. Neutral and weak acid extraction methods, such as water-soluble extraction and SPLP, did not exhibit satisfactory results for heavy metal stabilization, even if they showed very low leachability. On the other hand, TCLP and 0.1 M HCl extraction showed that the stabilizers significantly reduced the amount of heavy metals leached from the soil, which strongly supports the thesis that the stabilization treatment is efficient in the acidic leaching conditions that were explored. Specifically, in the 0.1 M HCl extraction, the reduction efficiencies of As, Pb, and Cu leachings were more than 90 %, compared with control experiments. This study demonstrates that the application of waste resources for the stabilization of As and heavy metals is feasible. However, some limitations observed in the experiments should be considered in future studies, such as the mobilization of alkali-soluble elements, and in particular, exchangeable fractions of Cu. In addition, the treatment efficiency can be evaluated by different leaching methods, which suggests that multidirectional approaches are required for the proper evaluation of stabilization treatment. 相似文献
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Kitirote Wantala Eakkachai Khongkasem Nuthakarn Khlongkarnpanich Suthipong Sthiannopkao Kyoung-Woong Kim 《Applied Geochemistry》2012
This work focused on the removal from water of arsenate in the 100 to 500 μg/L range using Fe-RH-MCM-41 immobilized on GAC by a colloidal impregnation method. A Response Surface Method (RSM) based on the Box–Behnken Design (BBD) was used to evaluate the effects of pH, adsorbent loading, and initial arsenate concentrations. The thermal stability of Fe-RH-MCM-41/GAC was greater than 460 °C because Fe-RH-MCM-41 and epoxy resin covered the GAC, preventing GAC weight loss. The rate and capacity for arsenate adsorption on Fe-RH-MCM-41/GAC were higher than for GAC. The effects of pH, adsorbent loading, and initial arsenate concentration showed significant effects on efficiency, in terms of percent arsenate removal. Significant interaction occurred as positive effects between arsenate and arsenate concentrations, and pH and arsenate concentrations, and as negative effects between pH and pH, adsorbent loading and adsorbent loading, and adsorbent loading and arsenate concentrations. 相似文献
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Stabilization of arsenic-contaminated mine tailings using natural and calcined oyster shells 总被引：1，自引：0，他引：1
Deok Hyun Moon Kyoung-Woong Kim In-Ho Yoon Dennis G. Grubb Dae-Yewn Shin Kyung Hoon Cheong Hyung-Il Choi Yong Sik Ok Jeong-Hun Park 《Environmental Earth Sciences》2011,64(3):597-605
Natural oyster shells (NOS) and calcined oyster shells (COS) were used to immobilize arsenic (As) from contaminated mine tailings.
In addition, a blend of Portland cement (PC)/cement kiln dust (CKD) was used as a stabilizing agent. The Korean Standard Test
(KST) method (1 N HCl extraction) was used to evaluate the effectiveness of the treatment. The experimental results showed
that COS effectively immobilized As in treated mine tailings. Specifically, an As concentration less than 1 mg L−1 was obtained following COS treatment at 25 and 30 wt%. However, all the samples subjected to NOS treatments failed the Korean
warning standard of 1.2 mg L−1 after 28 days of curing. All of the COS-PC treatments were successful meeting the Korean warning standard after 7 days of
curing. However, the PC-only treatment failed to meet the Korean warning standard. Similarly, the CKD-only treatment was failed
to meet the Korean warning standard after 7 days of curing. However, the COS-CKD treatment showed that when the COS content
was greater than 20 wt%, less than 1 mg L−1 of As leachability was obtained. Scanning electron microscopy–energy dispersive X-ray spectroscopy (SEM–EDX) showed needle-like
and torpedo-like Ca–As phases in the COS-treated samples suggesting that As was strongly associated with Ca and O. X-ray absorption
near edge structure (XANES) analyses confirmed that As(V) was prevalent in the tailings and that there were no changes in
As speciation following NOS or COS treatment. 相似文献
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Edu Inam Inemesid Etuk Nnanake-Abasi Offiong Kyoung-Woong Kim Seo-Young Kang Joseph Essien 《Environmental Earth Sciences》2018,77(5):216
Sediments are considered as suitable matrices to study the contamination levels of aquatic environment since they represent a sink for multiple contaminant sources. In this study, the influence of sediment characteristics on the distribution of polycyclic aromatic hydrocarbons (PAHs) and its potential risk in euryhaline, freshwater and humic aquatic bodies of Douglas/Stubbs creek, Ikpa River and Eniong River, respectively, were investigated. The level of PAHs in sediment was quantified using GC–MS, while sediment properties including total organic carbon (TOC) content and grain size were determined by the wet oxidation and hydrometer methods, respectively. The results revealed that the total levels of PAHs in sediment varied significantly between the euryhaline, freshwater and humic freshwater ecosystems. In Ikpa River freshwater ecosystem, a total PAHs load of 1055.2 ng/g was recorded with the suites concentration ranging from 13.0 ng/g (for acenaphthylene) to 161 ng/g (for pyrene). The humic ecosystem of Eniong River had a total PAH load of 11.06 ng/g, while the suites level recorded ranged from 0.04 ng/g for acenaphthene to 2.65 ng/g for chrysene. The total level of PAHs detected in the euryhaline Douglas/Stubbs creek was 14.47 ng/g, and suite concentrations varied between 4.27 ng/g for naphthalene and 5.13 ng/g for acenaphthylene. This shows variation in quantity and quality of PAH contaminants with the nature of ecosystems. It implies complex and diverse contamination sources as well as different capabilities to recover from PAH contamination. Correlation analysis has shown that sediment particle and TOC content influenced PAHs burden in bottom sediments, but the effects varied with the molecular weight of PAHs and the nature of the ecosystems. The TOC was the most significant determinant of PAHs load and distribution in sediment of the freshwater Ikpa River and euryhaline Douglas/Stubbs but had little or no influence in the humic sediment of Eniong River, while the influence of particle size was generally indefinite but slightly associated with PAHs accumulation in the euryhaline sediment. Generally, the total PAH levels (11.0–1055.2 ng/g) recorded were low and below the allowable limit for aquatic sediments. The ecological risk assessment revealed that these levels were lower than the effects range low and effects range medium values. This indicates no acute adverse biological effect although the accumulation of PAHs in freshwater ecosystem of Ikpa River may pose ecological risks as most of the carcinogenic PAH suites had relatively high pollution indices compared to other ecosystem types studied. 相似文献
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Eunyoung Choe Kyoung-Woong Kim Sunbaek Bang In-Ho Yoon Keun-Young Lee 《Environmental Geology》2009,58(3):477-482
Reflectance spectroscopy covering the visible and near-infrared ranges (400–2,400 nm) is known as a rapid and nondestructive
method in the characterization and quantitative analysis of many components of interest. In this study, the potential use
of spectral absorption feature parameters (SAFPs) in the range of 400–2,400 nm was investigated in terms of the prediction
of heavy metals and mapping of their distribution. Parameters such as absorption depth, area, and peak ratio were derived
from variations in spectral absorption shape associated with concentrations of heavy metals. Heavy metals were quantified
from SAFPs using stepwise multiple linear regression (SMLR) and enter multiple linear regression (EMLR). The EMLR model showed
qualitative prediction performance for As and Cu, with R
2 values of 0.60 and 0.81, respectively. A contour map of As and Cu concentrations based on EMLR-derived values showed similar
spatial patterns to a map based on measured values. 相似文献
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Suthipong Sthiannopkao Kyoung-Woong Kim Kyung Hwa Cho Kitirote Wantala Sieng Sotham Choup Sokuntheara Joon Ha Kim 《Applied Geochemistry》2010
This study focused on the analysis of As levels in human hair samples collected from six villages in the Kandal Province of Cambodia. Of interest were the influence of, and interactions among, certain factors affecting As intake into the human body: As concentrations in groundwater, period of groundwater consumption, age and gender. The results revealed As levels in human hair ranging from 0.06 to 30 μg g−1 with median and arithmetic mean values of 0.61 and 3.20 μg g−1 (n = 68), respectively. Furthermore, a linear relationship was found between As concentrations in human hair and in the local groundwater. Arsenic (III) is the dominant species in Kandal groundwater, constituting in most cases at least 60% of the total As. Arsenic concentration ranged from 5 to 1543 μg L−1, with the median value 348 μg L−1 and arithmetic mean 454 μg L−1. In large rural, poor areas holding most of Kandal’s 1.1 million people, up to 2 in 1000 people are believed to be at risk of cancer through the As-enriched water they drink. A toxicity risk assessment provides a hazard quotient (HQ) equaling 5.12, also a clear indication of non-carcinogenic exposure risk. On the authors’ visit to Kampong Kong commune, Kandal Province, cases of arsenicosis were diagnosed in patients as a result of drinking As-enriched groundwater. 相似文献
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在试验室通过使用多种碳源（包括醋酸盐、乳酸盐和葡萄糖），对采于朝鲜废弃金银矿地区的受砷污染的沉积物样品（339毫克／千克）中固有细菌生物激化后，就沉积物样品中固有细菌对砷物种形成和活动性的影响，进行了研究。通过连续提取分析来确定砷的形式，结果表明，沉积物中40％和47％的砷分别以铁伴生物和残留组分的形式存在。通过使用醋酸盐和乳酸盐对沉积物样品进行培育22天后，固有细菌增加了沉积物样品中铁伴生物和残留组分中溶解砷的总量。当与消过毒的沉积物样品（总溶解砷浓度低于50％）对比时发现，生物悬浮液中超过99％的溶解砷以砷（V）的形式存在，这表明，固有细菌将部分溶解的砷（III）转换成了砷（V）。在实际环境中，依据pH值的不同，微生物引起的水成砷（V）既可以通过吸附而固定不动，也可以在向地下缺氧区迁移后被还原成（III）。 相似文献
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