Kinetics of Mn(II) oxidation by Leptothrix discophora SS1     

Jinghao ZhangLeonard W Lion  Yarrow M Nelson  Michael L ShulerWilliam C Ghiorse 《Geochimica et cosmochimica acta》2002,66(5):773-781

The kinetics of Mn(II) oxidation by the bacterium Leptothrix discophora SS1 was investigated in this research. Cells were grown in a minimal mineral salts medium in which chemical speciation was well defined. Mn(II) oxidation was observed in a bioreactor under controlled conditions with pH, O₂, and temperature regulation. Mn(II) oxidation experiments were performed at cell concentrations between 24 mg/L and 35 mg/L, over a pH range from 6 to 8.5, between temperatures of 10°C and 40°C, over a dissolved oxygen range of 0 to 8.05 mg/L, and with L. discophora SS1 cells that were grown in the presence of Cu concentrations ranging from zero to 0.1 μM. Mn(II) oxidation rates were determined when the cultures grew to stationary phase and were found to be directly proportional to O₂ and cell concentrations over the ranges investigated. The optimum pH for Mn(II) oxidation was approximately 7.5, and the optimum temperature was 30°C. A Cu level as low as 0.02 μM was found to inhibit the growth rate and yield of L. discophora SS1 observed in shake flasks, while Cu levels between 0.02 and 0.1 μM stimulated the Mn(II) oxidation rate observed in bioreactors. An overall rate law for Mn(II) oxidation by L. discophora as a function of pH, temperature, dissolved oxygen concentration (D.O.), and Cu concentration is proposed. At circumneutral pH, the rate of biologically mediated Mn(II) oxidation is likely to exceed homogeneous abiotic Mn(II) oxidation at relatively low (≈μg/L) concentrations of Mn oxidizing bacteria.  相似文献   

Integrating isolated and riparian wetland modules in the PHYSITEL/HYDROTEL modelling platform: model performance and diagnosis          下载免费PDF全文

Maxime Fossey  Alain N. Rousseau  Fatima Bensalma  Stéphane Savary  Alain Royer 《水文研究》2015,29(22):4683-4702

Mathematical modelling is a well‐accepted framework to evaluate the effects of wetlands on stream flow and watershed hydrology in general. Although the integration of wetland modules into a distributed hydrological model represents a cost‐effective way to make this assessment, the added value brought by landscape‐specific modules to a model's ability to replicate basic hydrograph characteristics remains unclear. The objectives of this paper were the following: (i) to present the adaptation of PHYSITEL (a geographic information system) to parameterize isolated and riparian wetlands; (ii) to describe the integration of specific isolated wetland and riparian wetland modules into HYDROTEL, a distributed hydrological model; and (iii) to evaluate the performance of the updated modelling platform with respect to the capacity of replicating various hydrograph characteristics. To achieve this, two sets of simulations were performed (with and without wetland modules), and the added value was assessed at three river segments of the Becancour River watershed, Quebec, Canada, using six general goodness‐of‐fit indicators and 14 water flow criteria. A sensitivity analysis of the wetland module parameters was performed to characterize their impact on stream flows of the modelled watershed. Results of this study indicate the following: (i) integration of specific wetland modules can slightly increase the capacity of HYDROTEL to replicate basic hydrograph characteristics; and (ii) the updated modelling platform allows for the explicit assessment of the impact of wetlands (e.g. typology and location) on watershed hydrology. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

Computer-aided design of bus route maps     

Yukio Sadahiro  Takahito Tanabe  Maxime Pierre  Koichi Fujii 《制图学和地理信息科学》2016,43(4):361-376

The bus route map is a diagram that aims to convey necessary information for map readers to find an appropriate way of moving from an origin to a destination. Design of bus route map is a complicated and time-consuming task that requires careful consideration of readability and aesthetics. This paper proposes a new computational method for designing bus route maps. The method helps us to reduce six types of undesirable elements in bus route maps, i.e., gap, shift, crossing, overlap, misalignment, and acute bend. The method consists of two phases: line layout phase determines the relative order of bus routes on each road segment and map layout phase calculates the actual position of bus routes drawn on a map. This paper applies the method to the design of bus route maps of Chiba City, Japan. The result supports the effectiveness of the method as well as reveals open topics for future research.  相似文献   

Map-Based Web Tools Supporting Climate Change Adaptation     

Tina-Simone Neset  Tomasz Opach  Peter Lion  Anna Lilja  Jimmy Johansson 《The Professional geographer》2016,68(1):103-114

This article discusses the state of the art in geovisualization supporting climate change adaptation. We reviewed twenty selected map-based Web tools, classified by their content and functionality, and assessed them by visual representations, interactive functions, information type, target audience, and how vulnerability and adaptation to climate change are addressed. Our study concludes that the tools (1) can be classified as data viewers with basic functionality and data explorers offering more sophisticated interactive functions; (2) mostly feature moderate or high richness of data content; and (3) predominantly target expert users.  相似文献   

A diverse Pleistocene marsupial trackway assemblage from the Victorian Volcanic Plains,Australia     

Stephen P. Carey  Aaron B. Camens  Matthew L. Cupper  Rainer Grün  John C. Hellstrom  Stafford W. McKnight  Iain Mclennan  David A. Pickering  Peter Trusler  Maxime Aubert 《Quaternary Science Reviews》2011,30(5-6):591-610

A diverse assemblage of late Pleistocene marsupial trackways on a lake bed in south-western Victoria provides the first information relating to the gaits and morphology of several megafaunal species, and represents the most speciose and best preserved megafaunal footprint site in Australia. The 60–110 ka volcaniclastic lacustrine sedimentary rocks preserve trackways of the diprotodontid Diprotodon optatum, a macropodid (probably Protemnodon sp.) and a large vombatid (perhaps Ramsayia magna or ‘Phascolomys’ medius) and possible prints of the marsupial lion, Thylacoleo carnifex. The footprints were imprinted within a short time period, demonstrating the association of the taxa present, rather than the time-averaged accumulations usually observed in skeletal fossil deposits. Individual manus and pes prints are distinguishable in some trackways, and in many cases some digital pad morphology is also present. Several parameters traditionally used to differentiate ichnotaxa, including trackway gauge and the degree of print in-turning relative to the midline, are shown to be subject to significant intraspecific variation in marsupials. Sexual dimorphism in the trackway proportions of Diprotodon, and its potential for occurrence in all large bodied, quadrupedal marsupials, is identified here for the first time.  相似文献   

Practical method for drawing a VGP path     

Maxime Le Goff  Bernard Henry  Lucien Daly 《Physics of the Earth and Planetary Interiors》1992,70(3-4):201-204

A statistical method is proposed for the smoothing of polar wander paths and for giving their confidence limits by the mean of successive ellipses. The method is fully parametrical and is based on the relations between the inertia matrix and the parameters of the Fisher distribution, from which a bivariate form is deduced. An elementary tensorial calculation gives the parameters of the confidence ellipse around a vectorial weighted mean, for any unimodal set of vectors. This model can also be used for other statistical tests, wherever the rotational symmetry hypothesis is not consistent (i.e. the fold test).  相似文献   

Spectroscopic analysis (FTIR, Raman) of water in mafic and intermediate glasses and glass inclusions   总被引：1，自引：0，他引：1  

Maxime Mercier  Andrea Di Muro  Nicole Métrich  Olfa Belhadj 《Geochimica et cosmochimica acta》2010,74(19):5641-5656

Micro-Raman spectroscopy, even though a very promising technique, is not still routinely applied to analyse H₂O in silicate glasses. The accuracy of Raman water determinations critically depends on the capability to predict and take into account both the matrix effects (bulk glass composition) and the analytical conditions on band intensities. On the other hand, micro-Fourier transform infrared spectroscopy is commonly used to measure the hydrous absorbing species (e.g., hydroxyl OH⁻ and molecular H₂O) in natural glasses, but requires critical assumptions for the study of crystal-hosted glasses. Here, we quantify for the first time the matrix effect of Raman external calibration procedures for the quantification of the total H₂O content (H₂O_T = OH⁻ + H₂O_m) in natural silicate glasses. The procedures are based on the calibration of either the absolute (external calibration) or scaled (parameterisation) intensity of the 3550 cm⁻¹ band. A total of 67 mafic (basanite, basalt) and intermediate (andesite) glasses hosted in olivines, having between 0.2 and 4.8 wt% of H₂O, was analysed. Our new dataset demonstrates, for given water content, the height (intensity) of Raman H₂O_T band depends on glass density, reflectance and water environment. Hence this matrix effect must be considered in the quantification of H₂O by Raman spectroscopy irrespective of the procedure, whereas the parameterisation mainly helps to predict and verify the self-consistency of the Raman results. In addition, to validate the capability of the micro-Raman to accurately determine the H₂O content of multicomponent aluminosilicate glasses, a subset of 23 glasses was analysed by both micro-Raman and micro-FTIR spectroscopy using the band at 3550 cm⁻¹. We provide new FTIR absorptivity coefficients (ε₃₅₅₀) for basalt (62.80 ± 0.8 L mol⁻¹ cm⁻¹) and basanite (43.96 ± 0.6 L mol⁻¹ cm⁻¹). These values, together with an exhaustive review of literature data, confirm the non-linear decline of the FTIR absorptivity coefficient (ε₃₅₅₀) as the glass depolymerisation increases. We demonstrate the good agreement between micro-FTIR and micro-Raman determination of H₂O in silicate glasses when the matrix effects are properly considered.  相似文献   

The challenge of dating early pleistocene fossil teeth by the combined uranium series–electron spin resonance method: the Venta Micena palaeontological site (Orce,Spain)     

Mathieu Duval  Christophe Falguères  Jean‐Jacques Bahain  Rainer Grün  Qingfeng Shao  Maxime Aubert  John Hellstrom  Jean‐Michel Dolo  Jordi Agusti  Bienvenido Martínez‐Navarro  Paul Palmqvist  Isidro Toro‐Moyano 《第四纪科学杂志》2011,26(6):603-615

The palaeontological site of Venta Micena (Orce, Andalusia, Spain) lies in the eastern sector of the Guadix–Baza basin, one of the best documented areas in Europe for Plio‐Pleistocene biostratigraphy. The combination of biochronological and palaeomagnetic results, combined with the radiometric data obtained for Atapuerca Sima del Elefante, indicated that the Venta Micena stratum was formed between the Jaramillo and Olduvai palaeomagnetic events, most likely between 1.22 and 1.77 Ma. Five fossil teeth from two outcrops (sites A and B) were selected to assess the potential of combined uranium series–electron spin resonance (US‐ESR) dating of Early Pleistocene sites. Although the US‐ESR results of the first outcrop showed a large scatter between the three teeth, the mean age of 1.37 ± 0.24 Ma can be considered a reasonable age estimate for Venta Micena. The mean ESR age of 0.62 ± 0.03 Ma obtained for site B seems to be a severe underestimation when compared with the independent age control. This underestimation is attributed to a relative recent U‐mobilization event that led to some U‐leaching. The results show that any ESR age calculations of old samples are extremely sensitive to variations in the measured ²³⁰Th/²³⁴U ratios in dental tissues. Although the results demonstrate that ESR can in principle be applied to Early Pleistocene sites, they also reveal the complexity of dating such old teeth. It is necessary to continue research in several directions, such as study of the behaviour of ESR signals in old teeth and understanding recent U‐mobilization processes, to improve the reliability of the combined US‐ESR dating method applied to Early Pleistocene times, a period for which the number of available numerical dating techniques is very limited. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

Mineral Processing Symposium — Sociéte de l'Industrie Minerale — Nancy, 1974     

Maxime Brandela 《International Journal of Mineral Processing》1975,2(1):101-104

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Mechanisms for trace metal enrichment at the surface microlayer in an estuarine salt marsh     

Leonard W Lion  Ronald W Harvey  James O Leckie 《Marine Chemistry》1982,11(3):235-244

The relative contributions of adsorption to particulate surfaces, complexation with surface-active organic ligands and uptake by micro-organisms were evaluated with respect to their importance in the surface microlayer enrichment (‘partitioning’) of Cd, Pb and Cu. The contributions of each process were inferred from field data in which partitioning of the dissolved and particulate forms of Cd, Pb and Cu, total and dissolved organic carbon, particles and total bacteria were observed. In the South San Francisco Bay estuary, particle enrichment appears to control trace metal partitioning. Trace metal association with the particulate phase and the levels of partitioning observed were in the order Pb > Cu > Cd and reflect the calculated equilibrium chemical speciation of these metals in computer-simulated seawater matrices.  相似文献