Genesis and evolution of hydrocarbons entrapped in the fluorite deposit of Koh-i-Maran, (North Kirthar Range, Pakistan)     

N. Guilhaumou  N. Ellouz  T. M. Jaswal  P. Mougin 《Marine and Petroleum Geology》2000,17(10)

The exceptional development of coeval hydrocarbon and aqueous fluid inclusions (FI) in fluorite from the MVT-type ore deposit of Koh-i-Maran, Baluchistan (North Kirthar range, Pakistan), provides samples which are representative of the ore-forming fluid and which support the hypothesis of petroleum migration in the province. Primary brines at 125°C (10 wt% equ. NaCl) and secondary CH₄-rich brines at 135°C (7 wt% equ. NaCl), are recognised to be associated with oil migration in the fluid inclusions. They support the model of a per ascensum MVT (Mississippi Valley Type) stratabound hydrothermal deposit. A pressure–temperature path of 120–125°C to 165–200 bars is calculated from microthermometric data and PVT modelling of hydrocarbon FI using the modified Peng–Robinson Equation of State (IFP software) from primary cogenetic inclusions (oil and brines).The composition of gas and oil fractions is obtained by a combination of Synchrotron FTIR microanalysis and gas chromatography performed on individual fluid inclusions. The oil entrapped as a coeval primary fluid phase is a light aliphatic normal oil in the range C₈–C₃₅ with a high CO₂ content. The brown solid phase found systematically in the oil is probably asphaltene resulting from precipitation after trapping of the heavy fraction, which commonly occurs by decreasing pressure and temperature and\or by CO₂ injection. Later CH₄-rich brine influx probably modified part of the oil in the primary fluid inclusions because degraded oil is observed within such inclusions. Biomarkers obtained by GC-MS analysis indicate a terpane distribution quite similar to the nearest oil seepage in the Gokurt area. This result and the high CO₂ content of organic fluid inclusions indicate a restricted/confined sedimentary environment for the source rock, which could correspond to the Eocene Carbonate formation with type-II organic matter. A possible additional input of gas from the Sambar formation is suggested as feasible. The link between the fluid inclusion data and the geodynamic evolution lead us to propose a circulation of basinal fluids driven mainly by the fault system during dewatering in the foredeep. In Pakistan, they are coeval to major compressional NW–SE Oligocene episode in the thrust belt. The origin of the fluorine may be found in the basin sediments as well as near the basement. The brines originated in salt structures recognized in eocambrian at the decollement level, the source rock was already mature.  相似文献   

A multiplex imaging spectrometer for low energyX-ray astronomy     

R. Rocchia  M. Arnaud  C. Blondel  M. Cantin  B. Mougin  R. Rothenflug  A. Tarrius 《Astrophysics and Space Science》1983,96(2):361-374

A multiplexX-ray image analyser is described. It consists in a time-modulated coded aperture associated with a solid state detector. The system combines the high efficiency and good spectral resolution of solid state spectrometers with the spatial resolution of the coded aperture (200 ).The device can be installed at the focus of a grazing incidence telescope to make images and spectra of faint astronomicalX-ray sources.  相似文献   

Long lasting interactions between tectonic loading, unroofing, post-rift thermal subsidence and sedimentary transfers along the western margin of the Gulf of Mexico: Some insights from integrated quantitative studies     

François Roure  Humberto Alzaga-Ruiz  Jean-Paul Callot  Didier Granjeon  Nicole Guilhaumou  Pascal Mougin  Michel Séranne 《Tectonophysics》2009,475(1):169-189

After Jurassic rifting, numerous carbonate platforms (i.e., the Orizaba, Cordoba and Golden Lane-Tuxpan platforms) developed during the Lower and Middle Cretaceous episode of thermal subsidence along the western passive margin of the Gulf of Mexico, with intervening basinal domains (i.e., the Tampico-Misantla, Zongolica, Veracruz and Deep Gulf of Mexico - DGM - basins).During the Late Cretaceous-Paleocene, the east-verging Sierra Madre Oriental thrust belt developed, resulting in tectonic uplift and unroofing of the allochthonous units (i.e. tectonic units made up of former Orizaba and Cordoba platforms and Zongolica Basin series). This new topography provided also an important source of clastics to feed the adjacent foredeep, where coeval tectonic loading accounted for the bending of the foreland lithosphere. However, shallow water facies or even emersion persisted until the Eocene in the forebulge area (at the present location of the Golden Lane), preventing locally the clastics to reach the DGM. This topographic barrier was ultimately bypassed by the clastics only during the Oligocene and Neogene, once (1) the prograding clastic wedge had exceeded accommodation, and (2) the long lasting thermal subsidence of the passive margin could overpass the effect of the bending and force the former bulge to sink.Numerous paleo-thermo-meters (Tmax, Ro), paleo-thermo-barometers (fluid inclusions), PVT and coupled forward kinematic and thermal modeling have been used to calibrate and date the progressive unroofing of the thrust belt. Coupled tectonic and sedimentologic modeling was applied in the foreland to predict the distribution of sand versus shale ratios in the Oligocene to Plio-Quaternary clastic sedimentary wedge of the passive margin, where gravitational gliding of post-Eocene series occurred during the Neogene along major listric faults.Mantle dynamics are advocated as the main process accounting for post-orogenic uplift and regional tilting of the basement, which initiated a massive transfer of sediments from the Cordillera towards the Gulf of Mexico, from Oligocene onward, resulting in a destabilization and gravitational collapse of the western slope of the Gulf of Mexico in Neogene times.  相似文献   

MétéEAU Nappes: a real-time water-resource-management tool and its application to a sandy aquifer in a high-demand irrigation context     

Surdyk  Nicolas  Thiéry  Dominique  Nicolas  Jérome  Gutierrez  Alexis  Vigier  Yannick  Mougin  Bruno 《Hydrogeology Journal》2022,30(6):1737-1749

The MétéEAU Nappes water-resource-management tool is presented. It is usable on the aquifer or part-of-aquifer scale for real-time observation of the state of the groundwater resource, and it is already operating in France. This online decision support tool is also able to predict the state of the resource in the short- and mid-terms. The paper explains the use of the tool in a case study in the Authion Valley, in the north-west of France, chosen for its context of tension surrounding the groundwater resource resulting from high volumes of abstraction for irrigation. The results of the simulation highlight the advantages of MétéEAU Nappes as a tool for prediction and simulation of the state of the groundwater resource. The results also show the advantages of this type of tool for water resource management, such as supplying local actors with reliable and real-time observations of the aquifer and providing forecasts to anticipate possible water shortage.

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