Statistical and geochemical assessment of groundwater quality in Teboursouk area (Northwestern Tunisian Atlas)     

Yosra Ayadi  Naziha Mokadem  Houda Besser  Belgacem Redhaounia  Faten Khelifi  Samia Harabi  Talel Nasri  Younes Hamed 《Environmental Earth Sciences》2018,77(9):349

Teboursouk region, Northwestern Tunisia, is characterized by the diversity of its natural resources (petroleum, groundwater and minerals). It constitutes a particular site widely studied, especially from a tectonic stand point as it exhibits a complex architecture dominated by multi-scale synclinals and Triassic extrusions. It has typical karst landform that constitutes important water resources devoted for human consumption and agriculture activities, besides to the exploitation of the Mio-Plio-Quaternary aquifer (MPQ). Thus, hydrogeological investigations play a significant role in the assessment of groundwater mineralization and the evaluation of the used water quality for different purposes. Hence, the current study based on a combined geochemical–statistical investigation of 50 groundwater samples from the multilayered aquifer system in the study area give crucial information about the principal factors and processes influencing groundwater chemistry. The chemical analysis of the water samples showed that Teboursouk groundwater is dominantly of Ca–Mg–Cl–SO₄ water type with little contribution of Ca–Mg–HCO₃, Na–K–Cl–SO₄ and Na–K–HCO₃. The total dissolved solids (TDS) values range from 0.37 to 3.58 g/l. The highest values are located near the Triassic outcrops. Furthermore, the hydrogeochemistry of the studied system was linked with various processes such as carbonates weathering, evaporites dissolution of Triassic outcrops and anthropogenic activities (nitrate contamination). Additionally, the main processes controlling Teboursouk water system were examined by means of multivariate statistical analysis (PCA and HCA) applied in this study based on 10 physicochemical parameters (TDS, pH, SO₄, HCO₃, pCO₂, Ca, Mg, Na, K, Cl and NO₃). Two principal components were extracted from PCA accounting 61% of total variance and revealing that the chemical characteristics of groundwater in the region were acquired through carbonates and evaporite dissolution besides to nitrate contamination. Similarly, according to Cluster analysis using Ward’s method and squared Euclidean distance, groundwater from the studied basin belongs to five different groups suggesting that the geochemical evolution of Teboursouk groundwater is controlled by dissolution of carbonates minerals, chemical weathering of Triassic evaporite outcrops, cation exchange and anthropogenic activities (nitrate contamination).  相似文献   

Atmospheric pollution in North Africa (ecosystems–atmosphere interactions): a case study in the mining basin of El Guettar–M’Dilla (southwestern Tunisia)     

Naziha Mokadem  Younes Hamed  Amina Ben Sâad  Imed Gargouri 《Arabian Journal of Geosciences》2014,7(5):2071-2079

Air quality transcends all scales with in the atmosphere from the local to the global with handovers and feedbacks at each scale interaction. Air quality has manifold effects on health, ecosystems, heritage and climate. New insights into the characterisation of both natural and anthropogenic emissions are reviewed looking at both natural (e.g. dust and lightning) as well as plant emissions. In the phosphate mining area (El Guettar–M’Dilla basin: Southwestern Tunisia), several diseases have been known as cancer, respiratory, allergies, cardiovascular, dental fluorosis, stress, etc. These diseases are directly related with the installation of the industrial sector of the CPG (from 1896) and the deforestation and the ecosystem degradation (fauna and flora).  相似文献   

GIS-based evaluation of groundwater quality and estimation of soil salinization and land degradation risks in an arid Mediterranean site (SW Tunisia)     

Besser  Houda  Mokadem  Naziha  Redhouania  Belgacem  Rhimi  Nacira  Khlifi  Faten  Ayadi  Yosra  Omar  Zohra  Bouajila  Abdelhakim  Hamed  Younes 《Arabian Journal of Geosciences》2017,10(16):1-18

Arabian Journal of Geosciences - The present work is concerned with the valorization of clay minerals of the Aleg formation (Coniacian-middle Campanian) in the clinker manufacturing. The studied...  相似文献   

Comparison of the effectiveness of different binders in solidification/stabilization of a contaminated soil     

Naziha Bougharraf  Dhouha Louati  Mohamed Mosbahi  Mohamed Jamel Rouis  Hafedh Rigane 《Arabian Journal of Geosciences》2018,11(13):348

In the current research, solidification/stabilization (S/S) treatment of the contaminated soil using hydraulic binders and additives was used to (1) reduce the mobility of organic and inorganic contaminants and (2) compare the ability of various binders in fixing contaminants. The samples were collected from Franco-Tunisian Petroleum Company, located in Sidi Litayem, Sfax (Southern Tunisia). Leaching tests were performed on contaminated soil, containing metallic elements, and hydrocarbons. Calcium aluminate cement (CAC), ordinary Portland cement (OPC), and ground-granulated blast-furnace slag (GGBFS), additives especially the bentonite and water, were used for S/S treatment. The obtained standard specimens were subjected for treating after treatment the leachability of pollutants, compressive strength (CS), and XRD analysis. The results of analysis conducted on contaminated soils showed that concentrations of metallic elements were in the range of 9.08–427 mg/kg and 15,520 mg/kg of organic compound. Next, 10% of the used binder improved the immobilization of pollutants and gave a satisfactory CS exceeding 1 MPa. Thus, the CAC is more effective in reducing the leachability of metal contaminants than OPC + GGBFS and produces much higher strength, which was of the order of 2.41 MPa. The mechanical characterization was confirmed by XRD analysis. The lowest values of organic compounds are presented in mixtures treated by 10% of used binder, indicating the effectiveness of those with the presence of 10% of bentonite. This work shows that 10% (OPC + GGBFS) +?10% bentonite improved the immobilization of metallic elements and hydrocarbons, thus proving its efficiency due to its low cost.  相似文献   

Hydrochemical characterization of groundwater using multivariate statistical analysis: the Maritime Djeffara shallow aquifer (Southeastern Tunisia)     

Bachaer Ayed  Ikram Jmal  Samir Sahal  Naziha Mokadem  Salwa Saidi  Emna Boughariou  Salem Bouri 《Environmental Earth Sciences》2017,76(24):821

Worldwide, groundwater resources have been considered as the main sources of drinking, domestic uses, industrial and agriculture water demands, especially in arid and semiarid regions. Accordingly, the monitoring of the groundwater quality based on different tools and methods becomes a necessity. The aim of this study was to apply several approaches to assess the water quality and to define the main hydrochemical process which affect groundwater of the Maritime Djeffara shallow aquifer. In addition to the hydrochemical approach, two multivariate statistical analyses, hierarchical clusters analysis (HCA) and principal component analysis (PCA), were carried out to identify the natural and the anthropogenic processes affecting groundwater chemistry. Hydrochemical approach, based on 47 analyzed groundwater samples, shows that most of samples present a sulfate to mixed chloride, with sodi-potassic tendency facies. According to their chemically composition, the HCA revealed three different groups (C1, C2 and C3) according to their electrical conductivity (EC) values: C1 (average EC = 4500 µS/cm), C2 (average EC = 7040 µS/cm) and C3 (average EC = 9767 µS/cm). Furthermore, PCA results show two principal factors account 84.05% of the total variance: (1) F1 represents the natural component, and (2) F2 symbolizes the anthropic component. Moreover, the groundwater quality map of the Maritime Djeffara shows three categories: suitable, doubtful and unsuitable water for irrigation. These different results should be taken to protect water resources in arid and semiarid regions, especially at the alluvial coastal regions. Also, they help to make a suitable planning to manage and protect the groundwater resources.  相似文献