Collisional excitation of interstellar cyclopropenylidene     

Green S  DeFrees DJ  McLean AD 《The Astrophysical journal. Supplement series》1987,65(1):175-191

Theoretical rotational excitation rates were computed for C3H2 in collisions with He atoms at temperatures from 30 to 120 K. The intermolecular forces were obtained from accurate self-consistent field and perturbation theory calculations, and collision dynamics were treated within the infinite-order sudden approximation. The accuracy of the latter was examined by comparing with the more exact coupled states approximation.  相似文献   

Deducing the spatial variability of exchange within a longitudinal channel water balance          下载免费PDF全文

Noah M. Schmadel  Bethany T. Neilson  Tamao Kasahara 《水文研究》2014,28(7):3088-3103

Developing an appropriate data collection scheme to infer stream–subsurface interactions is not trivial due to the spatial and temporal variability of exchange flowpaths. Within the context of a case study, this paper presents the results from a number of common data collection techniques ranging from point to reach scales used in combination to better understand the spatial complexity of subsurface exchanges, infer the hydrologic conditions where individual influences of hyporheic and groundwater exchange components on stream water can be characterized, and determine where gaps in information arise. We start with a tracer‐based, longitudinal channel water balance to quantify hydrologic gains and losses at a sub‐reach scale nested within two consecutive reaches. Next, we look at groundwater and stream water surface levels, shallow streambed vertical head gradients, streambed and aquifer hydraulic conductivities, water chemistry, and vertical flux rates estimated from streambed temperatures to provide more spatially explicit information. As a result, a clearer spatial understanding of gains and losses was provided, but some limitations in interpreting results were identified even when combining information collected over various scales. Due to spatial variability of exchanges and areas of mixing, each technique frequently captured a combination of groundwater and hyporheic exchange components. Ultimately, this study provides information regarding technique selection, emphasizes that care must be taken when interpreting results, and identifies the need to apply or develop more advanced methods for understanding subsurface exchanges. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

What is the source of baseflow in agriculturally fragmented catchments? Complex groundwater/surface‐water interactions in three tributary catchments of the Wabash River,Indiana, USA          下载免费PDF全文

Marty D. Frisbee  Zachary P. Meyers  Noah S. Stewart‐Maddox  Marc W. Caffee  Philine Bogeholz  Madison N. Hughes 《水文研究》2017,31(22):4019-4038

Some conceptual models suggest that baseflow in agriculturally fragmented watersheds may contain little, if any, groundwater. This has critical implications for stream quality and ecosystem functioning. Here, we (a) identify the sources and flowpaths contributing to baseflow using ²²²Rn and ⁸⁷Sr/⁸⁶Sr and (b) quantify mean apparent ages of groundwater and baseflow using multiple isotopic tracers (CFC, SF₆, ³⁶Cl, and ³H) in 4 small (0.08 to 0.64 km²) tributary catchments to the Wabash River in Indiana, USA. ²²²Rn activities and ⁸⁷Sr/⁸⁶Sr ratios indicate that baseflow in 3 catchments is sourced primarily from groundwater; baseflow in the fourth is dominated by a source similar to agricultural run‐off. CFC‐12 data indicate that springs in 1 catchment are discharging significant proportions of water that recharged between 1974 (42 ± 2 years) and 1961 (55 ± 2 years). Those same springs have ³⁶Cl/Cl ratios between 1,381.08 ± 29.37 (×10^?15) and 1,530.64 ± 27.65 (×10^?15) indicating that a substantial proportion of the discharge likely recharged between 1975 (41 years) and 1950 (66 years). Groundwater samples collected from streambed mini‐piezometers in a separate catchment have CFC‐12 concentrations indicating that a large proportion of the recharge occurred between 1948 (68 ± 2 years) and 1950 (66 ± 2 years). Repeat sampling conducted in September 2015 after above‐average summer rainfall did not show significant decreases in mean apparent age. The relatively old ages observed in 3 of the catchments can be explained by geological complexities that are likely present in all 4 catchments, but overwhelmed by flow from the shallow phreatic aquifer in the fourth catchment.  相似文献   

The impact of biofuel-induced food-price inflation on dietary energy demand and dietary greenhouse gas emissions     

Noah Scovronick  Paul Wilkinson 《Global Environmental Change》2013,23(6):1587-1593

Dramatic increases in liquid biofuel production have led to concerns about associated impacts on food prices, with many modeling studies showing significant biofuel-related price inflation. In turn, by changing patterns of food demand, biofuel production may indirectly influence greenhouse gas emissions. We estimated changes to dietary energy (calorie) demand and greenhouse gas emissions embodied in average diets under different biofuel-related food-price scenarios for Brazil, China and the United States, using food-price projections and food-price elasticities. Average energy demand decreased in all countries, from about 40 kcal per person per day in Brazil under a moderate price inflation scenario – a reduction of 1% relative to the (2009) reference scenario – to nearly 300 per day in the United States with high price inflation – almost 8% of reference levels. However, emissions per calorie increased slightly in all three countries. In terms of total greenhouse gas emissions, the results are suggestive of overall reductions only in the United States, where average reductions ranged from about 40 to 110 kg of carbon dioxide equivalent emissions per person per year. In China, the direction of impact is unclear, but the net change is likely to be small. Brazilian results were sensitive to parameter values and the direction and magnitude of impact is therefore uncertain. Despite the uncertainty, even small changes (positive or negative) in individual dietary emissions can produce large changes at the population level, arguing for the inclusion of the dietary pathway in greenhouse gas accounting of liquid biofuels.  相似文献   

Community‐Derived Standards for LA‐ICP‐MS U‐(Th‐)Pb Geochronology – Uncertainty Propagation,Age Interpretation and Data Reporting          下载免费PDF全文

Matthew S. A. Horstwood  George Gehrels  Simon E. Jackson  Noah M. McLean  Chad Paton  Norman J. Pearson  Keith Sircombe  Paul Sylvester  Pieter Vermeesch  James F. Bowring  Daniel J. Condon  Blair Schoene 《Geostandards and Geoanalytical Research》2016,40(3):311-332

The LA‐ICP‐MS U‐(Th‐)Pb geochronology international community has defined new standards for the determination of U‐(Th‐)Pb ages. A new workflow defines the appropriate propagation of uncertainties for these data, identifying random and systematic components. Only data with uncertainties relating to random error should be used in weighted mean calculations of population ages; uncertainty components for systematic errors are propagated after this stage, preventing their erroneous reduction. Following this improved uncertainty propagation protocol, data can be compared at different uncertainty levels to better resolve age differences. New reference values for commonly used zircon, monazite and titanite reference materials are defined (based on ID‐TIMS) after removing corrections for common lead and the effects of excess ²³⁰Th. These values more accurately reflect the material sampled during the determination of calibration factors by LA‐ICP‐MS analysis. Recommendations are made to graphically represent data only with uncertainty ellipses at 2s and to submit or cite validation data with sample data when submitting data for publication. New data‐reporting standards are defined to help improve the peer‐review process. With these improvements, LA‐ICP‐MS U‐(Th‐)Pb data can be considered more robust, accurate, better documented and quantified, directly contributing to their improved scientific interpretation.  相似文献   

A damped train of regular metre-wave pulses from the sun     

D. J. McLean  K. V. Sheridan 《Solar physics》1973,32(2):485-489

The metre-wave observations presented here of a damped train of regular pulses from the Sun appear much simpler than other similar events previously described. The interpretations so far proposed for such phenomena do not adequately explain the asymmetry observed in this case.Radiophysics Publication RPP 1645, March, 1973.  相似文献   

Spectroscopic Study of a Large Sample of Galaxies Discovered in the Second Byurakan Survey Fields     

M. V. Gyulzadyan  J. A. Stepanian  A. R. Petrosian  D. Kunth  B. McLean  G. Comte 《Astrophysics》2003,46(2):131-143

The Second Byurakan Survey (SBS) is a well known combined survey, which uses the presence of UV-excess radiation in the continuum, or the presence of emission-lines in the spectra for the identification of active and star-forming galaxies. This paper reports on a comparative study of 77 galaxies identified with UV-excess, and 34 galaxies identified via emission-line techniques in the fields of the SBS. The spectroscopic parameters used for the comparison are the [OII]3727/H and [OIII]5007/H emission-lines ratios, the equivalent widths of [OII]3727, [OIII]5007 and H emission-lines, and the C _[OII]-C _H index. Spectroscopic parameters as well as new redshifts were determined from the spectra obtained with the 6m telescope of the Special Astrophysical Observatory (Russia). The main results are: 1) Galaxies discovered via UV-excess technique are preferably more active. 2) Galaxies discovered via emission-line technique are preferably high-excitation low-luminosity star-forming galaxies. 3) UV-excess galaxies with faintest UV-excess radiation are likely candidates to be LINER or Sy2 type objects.  相似文献   

Changes in an urban water resource,an example from Sydney,Australia     

R. F. Warner  E. J. McLean  G. Pickup 《地球表面变化过程与地形》1977,2(1):29-38

This paper examines present and future resource utilization in the tidal section of the Georges River in the southern part of Sydney. Over the last 30 years, the physical characteristics of the river have changed as a result of urbanization, changed hydrologic regime and sand dredging. Urbanization has resulted in an increase in population from 190,000 in 1947 to 550,000. This has resulted in an increase in runoff, sediment input to the river and waste disposal. The change in hydrologic regime has resulted in a substantial increase in the magnitude and frequency of flooding which has increased erosion. Sand dredging has increased the channel capacity, enlarged the tidal prism and increased water turbidity. It has also resulted in extensive bank erosion in the upper part of the river and extensive deposition lower down as tailings are deposited. Although most of these changes have resulted in the deterioration of environmental quality, use of the river for recreation and as an urban amenity has increased.  相似文献   

Rare Earth Element and yttrium compositions of Archean and Paleoproterozoic Fe formations revisited: New perspectives on the significance and mechanisms of deposition   总被引：12，自引：0，他引：12  

Noah Planavsky  Andrey Bekker  Balz Kamber  Andrew Knudsen 《Geochimica et cosmochimica acta》2010,74(22):6387-6405

The ocean and atmosphere were largely anoxic in the early Precambrian, resulting in an Fe cycle that was dramatically different than today’s. Extremely Fe-rich sedimentary deposits—i.e., Fe formations—are the most conspicuous manifestation of this distinct Fe cycle. Rare Earth Element (REE) systematics have long been used as a tool to understand the origin of Fe formations and the corresponding chemistry of the ancient ocean. However, many earlier REE studies of Fe formations have drawn ambiguous conclusions, partially due to analytical limitations and sampling from severely altered units. Here, we present new chemical analyses of Fe formation samples from 18 units, ranging in age from ca. 3.0 to 1.8 billion years old (Ga), which allow a reevaluation of the depositional mechanisms and significance of Precambrian Fe formations. There are several temporal trends in our REE and Y dataset that reflect shifts in marine redox conditions. In general, Archean Fe formations do not display significant shale-normalized negative Ce anomalies, and only Fe formations younger than 1.9 Ga display prominent positive Ce anomalies. Low Y/Ho ratios and high shale-normalized light to heavy REE (LREE/HREE) ratios are also present in ca. 1.9 Ga and younger Fe formations but are essentially absent in their Archean counterparts. These marked differences in Paleoproterozoic versus Archean REE + Y patterns can be explained in terms of varying REE cycling in the water column.Similar to modern redox-stratified basins, the REE + Y patterns in late Paleoproterozoic Fe formations record evidence of a shuttle of metal and Ce oxides across the redoxcline from oxic shallow seawater to deeper anoxic waters. Oxide dissolution—mainly of Mn oxides—in an anoxic water column lowers the dissolved Y/Ho ratio, raises the light to heavy REE ratio, and increases the concentration of Ce relative to the neighboring REE (La and Pr). Fe oxides precipitating at or near the chemocline will capture these REE anomalies and thus evidence for this oxide shuttle. In contrast, Archean Fe formations do not display REE + Y patterns indicative of an oxide shuttle, which implies an absence of a distinct Mn redoxcline prior to the rise of atmospheric oxygen in the early Paleoproterozoic. As further evidence for reducing conditions in shallow-water environments of the Archean ocean, REE data for carbonates deposited on shallow-water Archean carbonate platforms that stratigraphically underlie Fe formations also lack negative Ce anomalies. These results question classical models for deposition of Archean Fe formations that invoke oxidation by free oxygen at or above a redoxcline. In contrast, we add to growing evidence that metabolic Fe oxidation is a more likely oxidative mechanism for these Fe formations, implying that the Fe distribution in Archean oceans could have been controlled by microbial Fe uptake rather than the oxidative potential of shallow-marine environments.  相似文献   

Assessing the response of watersheds to catastrophic (logging) and possible secular (global temperature change) perturbations using sediment-chemical chronologies     

David T. Long  Matthew J. Parsons  Catherine H. Yansa  Sharon S. Yohn  Colleen E. McLean  Ryan G. Vannier 《Applied Geochemistry》2010

Geochemical profiles of sediment cores from two oligotrophic lakes (Elk and Mullett) in northern Lower Michigan were studied to examine the response and recovery of watersheds to large-scale logging that occurred between 1850 and 1920. Specific questions addressed were: can the impact of extensive clear-cutting of forests be recognized in the sediment-chemical chronologies, can states of system stability be identified prior to the logging, and are there indications that the systems are recovering and possibly returning to a stable state? To answer these questions, elements were put into four groups as proxies for watershed runoff or export (e.g., Al, Mg), pollution (e.g., Pb, Cu), redox (e.g., Fe, As), and productivity (e.g., Ca, P). It was observed that vertical patterns of all proxies were influenced by logging and the early increases in concentration of pollution proxies were due to increased watershed export, not pollution. System stability might be recognized by relatively symmetrical vertical patterns among all of the proxies or secular changes of slowly increasing or decreasing vertical concentration trajectories. Some pre-logging trajectories were punctuated by episodes of slightly elevated concentrations that appear to be related to comparatively warmer periods during the Little Ice Age. Iron and Mn enrichments caused by increased watershed runoff might be misinterpreted as paleo-redox horizons. Results are interpreted to indicate that (1) reference conditions may be better defined as the temporal trends among proxy groups and not individual concentrations, (2) simply assuming pre-1800 conditions as a reference may not be appropriate, (3) inter-proxy group comparisons are needed to help for interpretations of intra-proxy group patterns, (4) the possible regime shift identified here might be expected for other ecosystems because of the intensity of human disturbances and secular changes, and (5) without consideration of a possible regime shift, recovery from logging is estimated to be on the order of 75–130 a, but shorter if regime shifts are considered.  相似文献