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1.
Periáñez R 《Marine environmental research》2005,60(1):35-49
The presence and temporal evolution (1990-2001) of (226)Ra in a tidal estuary affected by the phosphate industry has been investigated. Water samples collected in the course of four separate sampling campaigns were analysed for (226)Ra content using a gas flow proportional counter following Ba coprecipitation. Two (226)Ra sources have been identified: direct discharges from the industrial complex and run-off from a phosphogypsum pile. Although activity levels are similar, or even higher, than those found in other environments affected by the phosphate industry, there has been a general decrease in contamination since direct discharges ceased in 1998 due to new regulations from the EU. However, sediments are now acting as a source of Ra to the water column due to redissolution processes. A numerical model of the estuary has been developed to describe quantitatively the experimental results. The model solves the hydrodynamics and the dispersion equation of (226)Ra including interactions with sediments. Model results are, in general, in good agreement with observations. 相似文献
2.
Peri COLEMAN 《《地质学报》英文版》2014,(Z1)
正Seagull Lake is an unusual saline lake,having a marine spring connected to a large continental ecosystem.With climate change the balance between marine,meteoric and groundwater inputs to,and evaporitic and groundwater 相似文献
3.
The alpine-type peridotite at Burro Mountain is a partiallyserpentinized harzburgite-dunite body approximately 2 km indiameter. It lies in a chaotic mélange derived from theFranciscan Formation (Upper Jurassic to Upper Cretaceous) ofthe southern Coast Ranges of California. The peridotite is boundedon the east by a vertical fault in the Nacimiento fault zonethat brings sedimentary rocks of Taliaferro's (1943b) AsuncionGroup (Upper Cretaceous) into contact with the peridotite. Theperidotite appears to be one of a number of tectonic lenses,having a wide range in size, that make up the mélange.These lenses include metagraywacke, metachert, greenstone, amphibolite,and blueschist, as well as ultramafic rocks, and represent awide range of pressure-temperature environments. The outer shell of the peridotite is a sheared serpentinitezone 10–15 m thick. The peridotite was tectonically emplacedat its present level as a cold solid mass and had little effecton the mineral assemblages of the Franciscan Formation. Localdevelopment of lawsonite and aragonite in shear zones may berelated to the peridotite emplacement. Foliated harzburgite forms approximately 60 per cent of theperidotite. It is a lithologically uniform rock that has anolivine: orthopyroxene ratio of approximately 75:25. Accessoryclinopyroxene and chromian spinel generally make up less than5 per cent of the harzburgite. Dunite, composed of olivine,accessory chromian spinel (< 5 per cent), and trace amountsof pyroxene, makes up approximately 40 per cent of the peridotiteand occurs as dikes, sills, and irregular bodies in the harzburgite. Olivine and pyroxene show small but significant compositionalvariations and chromian spinel shows a large range in the cationratio Cr/(Cr+Al+ Fe3+). The compositional variations in theseminerals are related to original differences in bulk chemicalcomposition. The following compositional ranges were determinedfor minerals in the harzburgite: olivine, Fo91.1–Fo91.4;orthopyroxene, En89.8–En91.1; clinopyroxene, Ca47.0Mg50.0Fe3.0–Ca48.7Mg48.2Fe3.1;chromian spinel, Cr/(Cr+Al+Fe3+) 0.37–0.55. The pyroxeneshave a range in A12O3 content of 1.3–3.0 wt per cent.Olivine from dunite ranges from Fo91 to Fo92 7 and the chromianspinel has a range in the Cr/(Cr+Al+Fe3+) ratio of 0.30–0.75.Although all the dunites are lithologically similar, three distincttypes are recognized on the basis of composition of coexistingolivine and chromian spinel. Structural relations between thethree types of dunite suggest three periods of emplacement (possiblyoverlapping) of dunite into harzburgite. The evidence indicatesthat the dunite, and probably also the harzburgite crystallizedfrom an ultramafic magma, probably in the upper mantle. After the magmatic episode and crystallization, the peridotitewas subjected to a deep-seated plastic deformation and recrystallization.The first phase of the deformation produced a pervasive, planarstructural element (S1) that crosscuts many harzburgite-dunitecontacts. It is probable that some of the dunite sills wereemplaced during this deformation. The foliation, S1, is definedby layers of different orthopyroxene content in harzburgite,and by discontinuous layers of chromian spinel in dunite. Flowor slip along S1 produced slip folds in harzburgite—dunitecontacts with axial planes parallel to S1. At a later stage,isoclinal folds developed in S1, and the present olivine microfabricwas probably formed by recrystallization in the stress fieldthat produced the isoclinal folding. In the olivine microfabric,X tends to be perpendicular to the axial planes (S2) of theisoclinal folds and Y and Z tend to form double maxima in S2approximately 90° apart. Mg–Fe2+ distribution betweencoexisting mineral pairs yields a calculated temperature offormation of approximately 1200 °C. Although this temperatureis only a nominal value, it indicates that the mineral pairsequilibrated at a significantly high temperature. In view ofthe deformation and recrystallization, the calculated temperaturepossibly represents subsolidus re-equilibration of the mineralsduring this event. The deformation and recrystallization probablyoccurred shortly after crystallization while the peridotitewas still at a high temperature. A later deep-seated deformation produced small scattered kinkfolds in S1 that tend to disrupt the major olivine microfabric.The kink folding was accompanied or followed by the developmentof kink bands in olivine that reflect intragranular glidingon the system T = [Okl], t = [100]. The kink bands probablyformed at a minimum temperature of 1000 °C. Following the deep-seated deformation, which probably took placein the mantle, the peridotite mass was tectonically detachedand moved upward to its present level in the crust. Cleavages,joints, and faults provided channels for water to pervade theperidotite and allow alteration of the primary minerals. 相似文献
4.
Peri S.J. Coleman 《International Journal of Salt Lake Research》1998,7(1):25-40
Trials conducted at Dry Creek, a solar saltfield north of Adelaide, Australia, indicate that manganese, as manganous sulphate,
can increase both the purity and strength of salt crystals grown at an ambient or neutral-slightly acid pH range resulting
in a salt suitable for high purity uses. The improved load bearing strength of the crystals indicates that manganous sulphate
could also be useful in salt floor maintenance. However, the impact of an apparently slight rise in pH to 8.5 was significant.
Crystals produced at the higher pH from the manganese enriched brine were opaque with many tiny, almost colloidal crystals.
The salt did not drain well, had low load bearing strength and was notably impure. 相似文献
5.
The calcite fossils of the Derbyhaven Beds, Isle of Man, have δ13C values (+ 1·8 PDB) similar to modern, shallow-water marine skeletons, but the δ18O values (?6·1 PDB) are much lighter than modern skeletons. The light oxygen values indicate either re-equilibration with isotopically light water before cementation started, or Carboniferous sea water with δ18O of ?6‰. Aragonite dissolution was followed by precipitation of zoned calcite cement. In this cement, up to six intracrystalline zones, recognized in stained thin sections, show isotopic variation. Carbon varies from + 3-8 to + 1-2‰. and oxygen from ? 2-6 to ? 12-4‰. with decreasing age of the cement. This trend is attributed to increasing temperature and to isotopic evolution of the pore waters during burial. The zoned calcite is sequentially followed by dolomite and kaolinite cements which continue the trend towards light isotopic values. This trend is continued with younger, fault-controlled dolomite, and is terminated by vein-filling calcite and dolomite. The younger calcite, interpreted as a near-surface precipitate from meteoric waters, is unrelated to the older sequence of carbonates and has distinctly different carbon isotope ratios: δ13C ? 6-8‰. 相似文献
6.
M. Perišić D. Maletić S. S. Stojić S. Rajšić A. Stojić 《International Journal of Environmental Science and Technology》2017,14(5):1047-1054
In this study, several multivariate methods were used for forecasting hourly PM10 concentrations at four locations based on SO2 and meteorological data from the previous period. According to the results, boosted decision trees and multi-layer perceptrons yielded the best predictions. The forecasting performances were similar for all examined locations, despite the additional PM10 spatio-temporal analysis showed that the sites were affected by different emission sources, topographic and microclimatic conditions. The best prediction of PM10 concentrations was obtained for industrial sites, probably due to the simplicity and regularity of dominant pollutant emissions on a daily basis. Conversely, somewhat weaker forecast accuracy was achieved at urban canyon avenue, which can be attributed to the specific urban morphology and most diverse emission sources. In conclusion to this, the integration of advanced multivariate methods in air quality forecasting systems could enhance accuracy and provide the basis for efficient decision-making in environmental regulatory management. 相似文献
7.
Slobodan B. Marković Eric A. Oches Zoran M. Perić Tivadar Gaudenyi Mlađen Jovanović Györgi Sipos Christine Thiel Jan-Pieter Buylaert Stevan Savić William D. McCoy Milica G. Radaković Rastko S. Marković Milivoj B. Gavrilov 《第四纪科学杂志》2021,36(8):1436-1447
The loess sequence preserved in the Požarevac brickyard in north-eastern Serbia comprises eight loess units separated by seven paleosols. Geochronological investigation using amino acid racemization and luminescence dating support stratigraphic correlations of loess units L3, S2LL1 and L1 at the Požarevac section with loess of glacial cycles E [Marine Isotope Stage (MIS) 10], D (MIS 9–8), C (MIS 7–6) and B (MIS 5–2) across central Europe. Correlation with the marine oxygen-isotope stratigraphy and associated paleoclimatic inferences are further supported by magnetic susceptibility, particle size and carbonate content measured in Požarevac sediments. Malacological investigations at the Požarevac section reveal the continuous presence of the Chondrula tridens and Helicopsis striata faunal assemblages throughout the last 350 ka. The loess malacological fauna, which is characterized by the complete absence of cold-resistant and cold-preferring species, suggests a stable, dry and relatively warm glacial and interglacial climate, compared with other central European loess localities. Together these data suggest that the south-eastern part of the Carpathian (Pannonian, Middle Danube) Basin was a refugium for warm-preferring and xerophilous land-snails during the generally unfavorable glacial climates of the late Middle and Late Pleistocene. 相似文献
8.
Effect of bacteria on the elemental composition of early diagenetic siderite: implications for palaeoenvironmental interpretations 总被引：3，自引：0，他引：3
Many ancient early diagenetic siderite concretions are thought to have been precipitated by microbially-mediated reactions, and their trace element chemistry has been used to infer palaeoenvironments of formation (e.g. marine versus freshwater). In this study, pure cultures of the microorganism Geobacter metallireducens were used to precipitate siderite in the laboratory at a range of temperatures (18–40°C). Magnesium and calcium, in three different ratios (3:1, as in seawater, 1:1, and 1:3 as in freshwater), or manganese were added to some cultures at each incubation temperature to study trace element incorporation. The siderite produced exhibited the rhombohedral crystal form typical of concretionary siderite. However, this microbial siderite did not simply retain the trace element chemistry of the water from which it precipitated, as is assumed in palaeoenvironmental interpretations. Instead, manganese and calcium incorporation were found to be inversely proportional to the rate of microbial activity, which itself is dependent upon the nutritional status of the microorganisms. Magnesium incorporation was found to be rate-independent, and at high Mg/Ca ratios, it caused inhibition of calcium incorporation. In short, the influence of microorganisms on the trace element composition of early diagenetic siderite must be taken into account in order to produce valid palaeoenvironmental interpretations. 相似文献
9.
Grain-size analyses were performed on 84 samples from six environments in the Burdekin River Delta, NE Queensland, Australia. The data were subjected to a stepwise discriminant function analysis and canonical analysis which showed that the grain-size characteristics of the sediments are sufficiently distinctive to distinguish the six different environments of deposition. The resulting ‘reference set’ was then tested by plotting the grain-size characteristics of 66 samples from different environments of the Mississippi River Delta, Louisiana and Galveston Island, Texas. Seventy-four per cent of the North American samples were correctly classified. 相似文献
10.
A detailed field and laboratory study has been made of a well-exposedglaucophane schist sequence within the Jurassic and CretaceousFranciscan Formation of northern California. Three types ofglaucophane-bearing metamorphic rocks have been distinguishedin and around the area of the detailed study. Each is characterizedby distinctive textures and mineral assemblages that are interpretedto represent different grades of metamorphism within the glaucophaneschist facies. From the combination of small- and large-scale mapping in thearea described it is clear that coarsely schistose blocks, tensof feet in diameter, commonly rest directly upon and withinless intensely metamorphosed terrain. In the Cazadero area theseisolated blocks of coarsely crystalline rocks are concentratedin a band that is roughly concordant with some of the majorfaulting, and their metamorphic fabric shows no consistent relationto local or regional structures. It is tentatively suggestedthat these blocks have been transported upward tectonicallyand that they are not stratigraphically equivalent to the othertypes of glaucophane-bearing metamorphic rocks in the area. Chemical and petrographic evidence indicates that basalt andsediments have been converted to glaucophane-bearing rocks underconditions of metamorphism that were essentially isochemical,except for fugitive components and some minor elements. 相似文献