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1.
An unusual feature of the saline stratified lakes that were formed due to ongoing postglacial uplift on the White Sea coast is the presence of several differently colored thin layers in the zone with sharp gradients. Colored layers in five lakes at various stages of separation from the sea were investigated using optical microscopy, spectrophotometry, spectrofluorimetry, and photobiology. The upper greenish colored layer located in the aerobic strata of all lakes near the compensation depth of 1% light penetration contains green algae. In the chemocline, another layer, brightly green, red or pink, is dominated by mixotrophic flagellates. Despite the very low light intensities and the presence of H 2 S, active photosynthesis by these algae appears to be occurring, as indicated by high values of the maximum quantum yield of primary photochemistry, electron transport activity, photosynthetic activity of photosystem II, the fraction of active centers, and low values of heat dissipation. In the reduced zone of the chemocline, a dense green or brown suspension of anoxygenic phototrophs(green sulfur bacteria) is located.  相似文献   
2.
The primary scientific goal of studying salt lakes is to better understand the formation of small continental-type hydrogeochemical systems. Many scientists have attributed the metamorphism of the chemical composition of salt lakes to the evaporative concentration of water. However, the formation of soda water is inconsistent with this hypothesis. Thus, analyzing intrabasinal biochemical processes and water—rocks interactions during the evaporative concentration of water allows us to understand the major mechanisms of the formation and evolution of water compositions. Therefore, the aim of this paper is to identify the key processes involved in the formation of the chemical composition of the water in Lake Doroninskoye. An analysis of the distribution of major components shows that Na+, HCO3 ?, CO3 2?, and Cl? are dominant in this water. High concentrations of these elements are the result of evaporative water concentration. Calcium, magnesium, and potassium are not accumulated because the water is saturated in minerals containing these elements. The main barrier to the growth of the sulfate content of water is sulfate reduction. This process also contributes to the additional reproduction of carbon dioxide, which reacts with the products of the hydrolysis of aluminosilicates OH? to form HCO3 ? and CO3 2?, thus further contributing to the natural processes of soda formation.  相似文献   
3.
Atom probe microscopy (APM) is a relatively new in situ tool for measuring isotope fractions from nanoscale volumes (< 0.01 μm3). We calculate the theoretical detectable difference of an isotope ratio measurement result from APM using counting statistics of a hypothetical data set to be ± 4δ or 0.4% (2s). However, challenges associated with APM measurements (e.g., peak ranging, hydride formation and isobaric interferences), result in larger uncertainties if not properly accounted for. We evaluate these factors for Re‐Os isotope ratio measurements by comparing APM and negative thermal ionisation mass spectrometry (N‐TIMS) measurement results of pure Os, pure Re, and two synthetic Re‐Os‐bearing alloys from Schwander et al. (2015, Meteoritics and Planetary Science, 50, 893) [the original metal alloy (HSE) and alloys produced by heating HSE within silicate liquid (SYN)]. From this, we propose a current best practice for APM Re‐Os isotope ratio measurements. Using this refined approach, mean APM and N‐TIMS 187Os/189Os measurement results agree within 0.05% and 2s (pure Os), 0.6–2% and 2s (SYN) and 5–10% (HSE). The good agreement of N‐TIMS and APM 187Os/189Os measurements confirms that APM can extract robust isotope ratios. Therefore, this approach permits nanoscale isotope measurements of Os‐bearing alloys using the Re‐Os geochronometer that could not be measured by conventional measurement principles.  相似文献   
4.
5.
This article presents a new comprehensive assessment of the Holocene hydrological variability of Lake Ladoga, northwest Russia. The reconstruction is based on oxygen isotopes of lacustrine diatom silica (δ18Odiatom) preserved in sediment core Co 1309, and is complemented by a diatom assemblage analysis and a survey of modern isotope hydrology. The data indicate that Lake Ladoga has existed as a freshwater reservoir since at least 10.8 cal. ka BP. The δ18Odiatom values range from +29.8 to +35.0‰, and relatively higher δ18Odiatom values around +34.7‰ between c. 7.1 and 5.7 cal. ka BP are considered to reflect the Holocene Thermal Maximum. A continuous depletion in δ18Odiatom since c. 6.1 cal. ka BP accelerates after c. 4 cal. ka BP, indicating Middle to Late Holocene cooling that culminates during the interval 0.8–0.2 cal. ka BP, corresponding to the Little Ice Age. Lake‐level rises result in lower δ18Odiatom values, whereas lower lake levels cause higher δ18Odiatom values. The diatom isotope record gives an indication for a rather early opening of the Neva River outflow at c. 4.4–4.0 cal. ka BP. Generally, overall high δ18Odiatom values around +33.5‰ characterize a persistent evaporative lake system throughout the Holocene. As the Lake Ladoga δ18Odiatom record is roughly in line with the 60°N summer insolation, a linkage to broader‐scale climate change is likely.  相似文献   
6.
Permafrost records, accessible at outcrops along the coast of Oyogos Yar at the Dmitry Laptev Strait, NE-Siberia, provide unique insights into the environmental history of Western Beringia during the Last Interglacial. The remains of terrestrial and freshwater organisms, including plants, coleopterans, chironomids, cladocerans, ostracods and molluscs, have been preserved in the frozen deposits of a shallow paleo-lake and indicate a boreal climate at the present-day arctic mainland coast during the Last Interglacial. Terrestrial beetle and plant remains suggest the former existence of open forest-tundra with larch (Larix dahurica), tree alder (Alnus incana), birch and alder shrubs (Duschekia fruticosa, Betula fruticosa, Betula divaricata, Betula nana), interspersed with patches of steppe and meadows. Consequently, the tree line was shifted to at least 270 km north of its current position. Aquatic organisms, such as chironomids, cladocerans, ostracods, molluscs and hydrophytes, indicate the formation of a shallow lake as the result of thermokarst processes. Steppe plants and beetles suggest low net precipitation. Littoral pioneer plants and chironomids indicate intense lake level fluctuations due to high evaporation. Many of the organisms are thermophilous, indicating a mean air temperature of the warmest month that was greater than 13 °C, which is above the minimum requirements for tree growth. These temperatures are in contrast to the modern values of less than 4 °C in the study area. The terrestrial and freshwater organism remains were found at a coastal exposure that was only 3.5 m above sea level and in a position where they should have been under sea during the Last Interglacial when the global sea level was 6–10 m higher than the current levels. The results suggest that during the last warm stage, the site was inland, and its modern coastal situation is the result of tectonic subsidence.  相似文献   
7.
Data on the mineral and chemical composition of samples of sulfide deposits from the Broken Spur and TAG (Mid-Atlantic Ridge) are presented. The main minerals in the Broken Spur field are marcasite, pyrrhotite, pyrite, chalcopyrite, and sphalerite; in sample from TAG: chalcopyrite, pyrite, and marcasite. It has been established that these sulfide minerals of Fe, Cu, and Zn are natural ion exchangers and belong to the class of adsorbents. Exchange capacity of sulfide minerals in terms of heavy metal cations (Ni2+, Co2+, Cd2+, and Pb2+) is 0.022–0.32 mg-equiv/g. In the exchange reaction products, the mineral composition of sulfide deposits is retained, and new phases do not appear. It is suggested that the adsorbed heavy metal cations populate either vacant cationic or interstitial defect sites in the structures of sulfide minerals. Bond strength of the adsorbed heavy metal cations with the main structural elements of minerals is low, which is confirmed by their high extraction in an acid medium. The results of adsorption-desorption experiments indicate two forms of heavy metal cations in sulfide minerals: adsorbed (basic) and chemically bound.  相似文献   
8.
9.
90 Sr concentrations,resulting from the Chernobyl NPP accident,were determined in the salt lakes of the Crimea(Lakes Kiyatskoe,Kirleutskoe,Kizil-Yar,Bakalskoe and Donuzlav),together with the redistribution between the components of the ecosystems.The content of mercury in the waters of the studied reservoirs was also established.Vertical distributions of natural radionuclide activities( 238 U,232 Th,226 Ra,210 Pb,40 K) and anthropogenic 137 Cs concentrations(as radiotracers) were determined in the bottom sediments of the Koyashskoe salt lake(located in the south-eastern Crimea) to evaluate the longterm dynamics and biogeochemical processes.Radiochemical and chemical analysis was undertaken and radiotracer and statistical methods were applied to the analytical data.The highest concentrations of 90 Sr in the water of Lake Kiyatskoe(350.5 and 98.0 Bq/m 3) and Lake Kirleutskoe(121.3 Bq/m 3) were due to the discharge of the Dnieper water from the North-Crimean Canal.The high content of mercury in Lake Kiyatskoe(363.2 ng/L) and in seawater near Lake Kizil-Yar(364 ng/L) exceeded the maximum permissible concentration(3.5 times the maximum).Natural radionuclides provide the main contribution to the total radioactivity(artificial and natural combined) in the bottom sediments of Lake Koyashskoe.The significant concentration of 210 Pb in the upper layer of bottom sediments of the lake indicates an active inflow of its parent radionuclide—gaseous 222 Rn from the lower layers of the bottom sediment.The average sedimentation rates in Lake Koyashskoe,determined using 210 Pb and 137 Cs data,were 0.117 and 0.109 cm per year,respectively.  相似文献   
10.
Detailed lithological, biogeochemical and molecular biological analyses of core sediments collected in 2002–2006 from the vicinity of the Malenky mud volcano, Lake Baikal, reveal considerable spatial variations in pore water chemical composition, with total concentrations of dissolved salts varying from 0.1 to 1.8‰. Values of methane δ13С in the sediments suggest a biogenic origin (δ13Сmin. ?61.3‰, δ13Сmax. ?72.9‰). Rates of sulphate reduction varied from 0.001 to 0.7 nmol cm?3 day?1, of autotrophic methanogenesis from 0.01 to 2.98 nmol CH4 cm?3 day?1, and of anaerobic oxidation of methane from 0 to 12.3 nmol cm?3 day?1. These results indicate that methanogenic processes dominate in gas hydrate-bearing sediments of Lake Baikal. Based on clone libraries of 16S rRNA genes amplified with Bacteria- and Archaea-specific primers, investigation of microbial diversity in gas hydrate-bearing sediments revealed bacterial 16S rRNA clones classified as Deltaproteobacteria, Gammaproteobacteria, Chloroflexi and OP11. Archaeal clone sequences are related to the Crenarchaeota and Euryarchaeota. Baikal sequences of Archaea form a distinct cluster occupying an intermediate position between the marine groups ANME-2 and ANME-3 of anaerobic methanotrophs.  相似文献   
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