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1.
Calciclastic submarine fans are rare in the stratigraphic record and no bona fide present-day analogue has been described to date. Possibly because of that, and although calciclastic submarine fans have long intrigued deep-water carbonate sedimentologists, they have largely been overlooked by the academic and industrial communities. To fill this gap we have compiled and critically reviewed the existing sedimentological literature on calciclastic submarine fans, thus offering an updated view of this type of carbonate slope sedimentary system.Calciclastic submarine fans range in length from just a few to more than 100 km. Three different types can be distinguished: (1) Coarse-grained, small-sized (< 10 km) fans, which are characterized by the abundance of calcirudites and the scarcity of mud. They have relatively long leveed channels and small radial lobes. (2) Medium-grained, medium-sized fans are typified by the abundance of calcarenites and lesser amounts of calcirudites and mud. They have a tributary network of slope gullies, which merge to form a leveed channel that opens to the main depositional site, characterized by extensive lobes and/or sheets, which eventually pass into basinal deposits through a narrow fan-fringe area. These fans are between 10 and 35 km in length. (3) Fine-grained, large-sized fans are rich in calcarenites and mud, but poor in calcirudites. They have wide and long slope channels that feed very extensive calciturbiditic sheets, the total length always exceeding 50 km and generally being close to 100 km. In terms of grain-size distribution the three fan types compare well with sand/gravel-rich, mud/sand-rich and mud-rich siliciclastic submarine fans, respectively. However, they show notable differences in terms of size and sedimentary architecture, a reflection of the different behaviour of their respective sediment gravity flows.Most calciclastic submarine fans were formed on low-angle slopes and were sourced from distally steepened carbonate ramps subjected to high-energy currents. Under these conditions shallow-water loose grainy sediments were transferred to the ramp slope and eventually funnelled into the submarine fan by sediment gravity flows. These conditions seem to have been more easily met on leeward margins in which the formation of reefs was hampered by cool waters, nutrient enrichment or oligophoty. Another circumstance that contributes to the transfer of shallow-water sediments to the distal ramp slope is a low sea level, forcing the carbonate factory closer to the slope break and destabilizing sediments by increased pore-water pressure. However, the most important factor controlling the development of calciclastic submarine fans was the existence of an efficient funnelling mechanism forcing sediment gravity flows to merge downslope and build up a point-sourced sedimentary accumulation. In most cases this occurred through a major slope depression associated with tectonic structures, an inherited topography, or large-scale mass failures.  相似文献   
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Levels of imposex (superimposition of male characters, upon females) and the presence of sterile females are assessed in the gastropod Nassarius reticulatus (L.), at 35 locations in the Basque Country. At 18 of these localities, organotin bioaccumulation (tributyltin (TBT); dibutyltin; monobutyltin) was evaluated, using isotope dilution GC–ICP–MS. Higher imposex levels and TBT body burden were found in confined harbours, with large vessel traffic or the presence of an offshore fleet. The highest values were found for the port of Pasaia, near to a shipyard (a relative penis size index of up to 92%, and TBT body burden up to 405 ng g?1 – given on a dry weight basis as Sn). Imposex effects were evaluated also in parasitized females, at some of the sampling sites. The percentage of presence of c-type Vas Deferens sequence stages (i.e., with vas deferens beginning at the oviduct opening) was higher in parasitized females. In turn, there was an absence of highly convoluted oviduct in parasitized females.  相似文献   
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According to Water Framework Directive requirements, Member States must identify and analyze effects derived from human pressures in aquatic systems. As different kind of pressures can impact water bodies at different scales, analyses of spatio-temporal evolution of water bodies becomes essential in order to understand ecosystem responses. In this investigation, an analysis of spatio-temporal evolution of sedimentary metal pollution (Cd, Cr, Cu, Hg, Ni, Pb, Zn) in 12 Basque estuaries (Bay of Biscay) is presented. Data collected in extensive sampling surveys is the basis for the GIS-based statistical approach used. The implementation of pollution abatement measures is reflected in a long-term decontamination process, mostly evident in estuaries with highest historical sediment pollution levels. Spatial evolution is determined by either naturally occurring or human driven processes. Such spatial processes are more obviously being reflected in estuaries with lower historical sediment pollution levels.  相似文献   
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Tributyltin (TBT), dibutyltin (DBT) and monobutyltin (MBT) were measured in surficial sediments at, the ports of Pasaia and Bilbao, together with other mid- and small-size harbours of the Basque Country (northern Spain), in 2007-2008. The highest values of the sum of the three measured butyltin species (3523-3640 ng g−1, as Sn) were found at sampling stations near to shipyards located within the port of Pasaia. The highest value of TBT concentration (3143 ng g−1, as Sn) was found at the marina of Getxo, in the port of Bilbao. The degree of TBT degradation varied greatly between sampling stations, being found to be generally higher in those sediments with higher values of redox potential and lower values of TBT concentration (normalized by organic matter content).  相似文献   
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Eutrophication in marine ecosystems is an important problem that requires an accurate assessment. Although Basque estuaries (northern Spain) have historically been under high anthropogenic pressure, no specific eutrophication assessment method had been applied in these waters. In this study, a method employed in the Basque Country (BC) to assess the ??risk of failing to achieve good ecological status?? under the requirements of the Water Framework Directive (WFD) was adapted to exclusively assess the risk of eutrophication. This method is based on the driver?Cpressure?Cstate?Cimpact?Cresponse approach. The results from this method (called WFD-BC method) were compared to the results from Assessment of Estuarine Trophic Status (ASSETS; a specific method developed in the US to assess estuarine trophic status in a pressure?Cstate?Cresponse approach). The nutrient pressure was better characterized with the WFD-BC method due to the local hydrographic conditions (i.e., small and river-influenced estuaries) that were not well accommodated by the ASSETS method. In contrast, the WFD-BC results for assessment of state generally reflected worse conditions than the results from the ASSETS method due to the different indicators employed and the way these are integrated in the WFD-BC method. Overall, the WFD-BC method showed a good potential to assess eutrophication. However, to improve it, a lower weight for the benthos and macroalgae is recommended for evaluating state.  相似文献   
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The European Water Framework Directive provides a challenge in the development of new and accurate methodologies. It addresses assessment of Ecological Quality Status within European rivers, lakes, groundwaters, estuaries and coasts. Although this directive is simple and flexible in its concept, it is necessary to develop an approach based upon scientific knowledge; however, at the same time it should be as simple as possible, in order to achieve both requirements and comparability of results throughout European waters. This contribution presents the first methodological approach to the problem, as used for estuaries and coasts of the Basque Country (northern Spain), in: selecting typologies and reference conditions; determining biological quality and ecological status; and identifying some problems in implementing the WFD. As such, the present paper could serve as the basis for a discussion document for other regions and countries, throughout Europe.  相似文献   
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The so-called Wealden sediments are no less than 2000 m thick in Santander and north Burgos (northern Spain). The succession rests on an extensive scoured and channeled surface over marine carbonates of Early Callovian age, and ends with the incoming of the Urgonian marine strata and equivalents (Lower Aptian). Two major sedimentary cycles (‘megacylothems’) and the beginning of a third are recognized. Following a widespread break in the succession, each megacyclothem opens with a coarse-grained clastic interval of fluviatile origin and then grades up into finer-grained clastics and carbonates recording fluviatile, lacustrine and shallow-marine conditions.The succession accumulated in an elongated fault-bounded basin trending E—W. Detritus came from source areas lying to the south and west of the depositional area, which was at times connected with the sea to the east and possibly to the north. The development of the basin was controlled by the reactivation of Late Hercynian faults acting contemporaneously with sedimentation. The frequency of faulting varied considerably, periods of relative calm alternating with periods of strong activity. These determined the characteristics of the successive megacyclothems.  相似文献   
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