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1.
Partition coefficients (D) for Nb and Ta between rutile and haplogranite melts in the K2O-Al2O3-SiO2 system have been measured as functions of the K2O/Al2O3 ratio, the concentrations of Nb2O5 and Ta2O5, the temperature, in air and at 1 atmosphere pressure. The Ds increase in value as the K* [K2O/(K2O + Al2O3)] molar ratio continuously decreases from highly peralkaline [K* ∼ 0.9] to highly peraluminous [K* ∼ 0.35] melts. The D values increase more dramatically with a unit decrease in K* in peraluminous melts than in peralkaline melts. This compositional dependence of Ds can be explained by the high activity
of NbAlO4 species in peraluminous melts and the high activity of KONb species (or low activity of NbAlO4 species) in peralkaline melts. A coupled substitution, Al+3 + Nb+5 (or Ta+5) = 2Ti+4, accounts for the Ds of Nb (Ta) being much greater in peraluminous melts than in peralkaline melts because this substitution
allows Nb (Ta) to enter into the rutile structure more easily. The Ds of Ta between rutile and melt are greater than those
of Nb at comparable concentrations because the molecular electronic polarizability of Ta is weaker than that of Nb. The Nb+5 with a large polarizing power forms a stronger covalent bond with oxygen than Ta+5 with a small polarizing power. The formation of the strong bond, Nb-O, distorts the rutile structure more severely than the
weak bond, Ta-O; therefore, it is easier for Ta to partition into rutile than for Nb. These results imply that the utilization
of the Nb/Ta ratio in liquid as a petrogenetic indicator in granitic melts must be done with caution if rutile (or other TiO2-rich phases) is a liquidus phase. The crystallization of rutile will increase the Nb/Ta ratio of the residual liquid because
the Ds of Ta between rutile and melts are greater than those of Nb.
Received: 28 December 1998 / Accepted 27 September 1999 相似文献
2.
In view of water pollutants becoming more complex, both anionic and cationic pollutants need to be removed. The multi‐pollutants simultaneous removal is paid more and more attention. Hence, development composite materials for treatment complex wastewater are the aim of this study. In this research, iron–nickel nanoparticles deposited onto aluminum oxide (α‐Al2O3) and carbon nanotubes (CNTs) to form nanocomposite materials Fe–Ni/Al2O3 and Fe–Ni/CNTs, respectively, were used as adsorbents. The adsorption capacities of Fe–Ni/Al2O3 and Fe–Ni/CNTs for AO7, HSeO, and Pb2+ were observed to be 5.46, 8.28, 27.02, and 25.6 mg/g, 15.29 and 17.12 mg/g, separately. The composite materials with negative charges were superior in adsorption of anionic pollutants. Using orthogonal experimental design and analysis of variance to co‐treat dye AO7, HSeO and Pb2+ in aqueous solutions, seven testing factors were included: (1) adsorbent types, (2) amount of iron, (3) solution pHs, (4) AO7 concentrations, (5) Pb2+ concentrations, (6) HSeO concentrations and (7) reaction time. The experimental results showed that the removal of complex pollutants AO7, HSeO, and Pb2+ on Fe–Ni/CNTs could reach up to 90% in the optimal treatment conditions. When using Fe–Ni/CNTs as the adsorbent, the sorption isothermals were well fitted in the Freundlich isotherm, and R2 could reach up to 0.98. 相似文献
3.
近海漂流轨迹观测系统,采用全球定位系统GPS进行漂流瓶体的定位,通过移动通讯网络GPRS进行瓶体与服务器之间的数据和指令传递,服务器上存储的瓶体运动轨迹即可用于近海环流研究。2011年9月14～18日期间在浙江象山港内段海区进行了近海GPS-GPRS漂流轨迹观测系统的现场应用。本文首先介绍了该观测系统的基本构造和工作原理,而后对首次现场布放试验过程进行说明,最后给出了轨迹追踪的现场观测结果。研究表明基于GPS-GPRS技术的漂流轨迹观测系统可辅助近海潮致余环流的研究工作,具有一定的科学应用前景。 相似文献
4.
本文将广东省银矿床厘定为5个矿床成矿系列、6个矿床成矿亚系列,即云开地区与加里东运动有关的银矿床成矿系列、华南与晚古生代沉积作用有关的银矿床成矿系列(包括华南中泥盆世至早石炭世与海相碳酸盐岩有关的银矿床成矿亚系列和粤东北中晚石炭世与火山-沉积作用有关的银矿床成矿亚系列),南岭及周边与燕山期构造-岩浆作用有关的银矿床成矿系列、东南沿海与燕山期火山-侵入活动有关的银矿床成矿系列(包括粤东北印支-燕山期与残余海相火山活动有关的银矿床成矿亚系列和粤东与燕山晚期侵入岩有关的银矿床成矿亚系列)和三水-罗定盆地与燕山-喜山期岩浆-流体有关的银矿床成矿系列(包括粤东北印支-燕山期与残余海相火山活动有关的银矿床成矿亚系列和三水盆地与晚白垩世-古近纪构造或火山活动有关的银矿床成矿亚系列)。分别论述了各成矿(亚)系列的基本特征,并根据广东省区域地质构造发展史,建立了银矿区域成矿谱系。 相似文献
5.
Estimation of land subsidence caused by loss of smectite-interlayer water in shallow aquifer systems
Traditionally, land subsidence that results from groundwater over-pumping has often been described by the theory of consolidation. The mechanism of land subsidence due to the dehydration of clay minerals is not well addressed. A model of the “hydration state of smectite”, and a “solid solution model of smectite dehydration”, incorporating a thermodynamic solid solution model and laboratory results concerning clay-water systems of swelling pressure, hydration state and basal spacing in smectite interlayer, are employed to examine the effect of the release of water from the smectite interlayer on land subsidence in the coastal area of the Chou-Shui River alluvial fan and the Yun Lin offshore industrial infrastructure complex in Taiwan. The results indicate that 9.56–22.80% of the total cumulative land subsidence to a depth of 300 m is consistent with smectite dehydration following the over-pumping of groundwater. This dehydration-related land subsidence occurred to a depth of 0–60 m, with subsidence due to smectite dehydration accounting for 6.20–13.32% of the primary consolidation. Additionally, the total amount of subsidence resulting from both smectite dehydration and primary consolidation is consistent with the subsidence observed in the field. This study reveals that smectite dehydration appears to be important in assessing and predicting land subsidence in shallow aquifer systems. 相似文献
6.
Jiann-Tsorng Horng 《Astrophysics and Space Science》1975,34(2):L1-L5
Cyclotron waves in the solar wind near 1 AU with frequencies well below the electron cyclotron frequency and wavelengths much larger than the electron cyclotron radius but less than the proton cyclotron radius are considered. The cyclotron radii are defined from parallel thermal velocity of electron component and proton component with respect to the interplanetary magnetic field. No LH cyclotron waves are found to propagate for
p
< 0, where
p
1 –T
p/T
p is the temperature anisotropy of the proton component with respect to the interplanetary magnetic field. The damping or growth of RH cyclotron waves is found to depend on the frequency range and the temperature anisotropy of the proton component. The RH cyclotron waves are damped in the frequency range
r
|
p
|
p
for
p
< 0, where
p
is the proton cyclotron frequency. RH cyclotron instabilities occur in the frequency range |
p
|
p
>
r
> |
p
|
p
/(1–
r
) for
p
< 0. The marginal state is at
r
=|
p
|
p
.Abstract presented at theInternational Symposium on Solar-Terrestrial, São Paulo, Brazil, 17–22 June, 1974 相似文献
7.
初至拾取是起伏地表地震资料处理的关键环节,直接影响近地表建模的精度及静校正效果,但起伏地表资料极低的信噪比使传统的自动初至拾取算法几乎失效,而手动拾取要耗费巨大的人工和时间成本。本文研究了改进超虚干涉法,结合多道多域初至质量监控技术,实现起伏地表资料初至波自动拾取。改进超虚干涉法首次将近地表散射波纳入干涉法提高信噪比的范围,并通过折射波和散射波的线性组合使干涉法适用于起伏地表条件下任意复杂射线路径的初至波类型;提出反向干涉和多域干涉的概念,显著增强了所估计的虚源信号;使用波形反褶积滤波器较好地抑制了干涉导致的"假事件"的形成;采用多道多域初至质量监控技术,实现错误"假事件"初至的自动归位,提高了拾取初至的稳定性。本文研究的初至波自动拾取理论与技术具有突出的鲁棒性和稳定批量处理大量实际三维地震数据的能力,在中国西部山区三维地震勘探数据处理的应用效果显著,质量优于某常用商业软件。 相似文献
8.
This study develops a novel approach for modelling and examining the impacts of time–space land‐use changes on hydrological components. The approach uses an empirical land‐use change allocation model (CLUE‐s) and a distributed hydrological model (DHSVM) to examine various land‐use change scenarios in the Wu‐Tu watershed in northern Taiwan. The study also uses a generalized likelihood uncertainty estimation approach to quantify the parameter uncertainty of the distributed hydrological model. The results indicate that various land‐use policies—such as no change, dynamic change and simultaneous change—have different levels of impact on simulating the spatial distributions of hydrological components in the watershed study. Peak flow rates under simultaneous and dynamic land‐use changes are 5·71% and 2·77%, respectively, greater than the rate under the no land‐use change scenario. Using dynamic land‐use changes to assess the effect of land‐use changes on hydrological components is more practical and feasible than using simultaneous land‐use change and no land‐use change scenarios. Furthermore, land‐use change is a spatial dynamic process that can lead to significant changes in the distributions of ground water and soil moisture. The spatial distributions of land‐use changes influence hydrological processes, such as the ground water level of whole areas, particularly in the downstream watershed. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
9.
研究各种地层和井眼环境因素对碳氧比C/O测井长、短源距探测器的影响规律，可以为C/O测井仪器的刻度方法提供指导，为解释模型的建立和数据处理提供依据.本文用Monte Carlo方法，计算了C/O值随井眼直径、水泥环厚度、套管直径、孔隙度、含油饱和度、地层岩性和油密度的变化规律.从中看出，当井内流体为油时，井径或套管直径增大，C/O值增大，井眼影响增大；当井内流体为水时，井径或套管直径的增大，C/O值减小；水泥环厚度增加时C/O值减小；当井眼条件不变时，地层孔隙度越大，含油饱和度越大，C/O值越大，对测井越有利；反之，地层孔隙度越小，含油饱和度越小，C/O值越小，对测井不利；地层岩性对C/O值的影响显著，相同条件下，碳酸盐岩比砂岩的C/O值高；油密度越大，C/O值越大.文中还提出了一种消除这些因素影响的数据处理方法 相似文献
10.
在传统上,浮游有孔虫Ｇｌｏｂｏｒｏｔａｌｉａｔｒｕｎｃａｔｕｌｉｎｏｉｄｅｓ的初现面一直被用来作为划定海相地层更新统下界的可靠依据。然而,此一初现面（２．０ＭａＢ．Ｐ．）所界定的更新统下界与超微化石Ｇａｐｈｙｒｏｃｏｐｓａｏｃｅａｎｉｃａｓ．ｌ．初现面（１．６７～１．７ＭａＢ．Ｐ．）所界定的并不一致。这一现象对大陆边缘的沉积地层尤为显著。其主要原因是,大陆边缘的高沉积速率会导致两个基面有很的层位间距。本研究证明台湾西南部二仁溪剖面之浮游有孔虫Ｐｕｌｌｅｎｉａｔｉｎａ最后一次的旋向变化（由左至右）,几乎与超微化石Ｇ．ｏｃｅａｎｉｃａｓ．ｌ．的初现面同一时间。因此,就浮游有孔虫生物地层的观点看,此一族向变化是辨识更新统下界的一个非常有用的基面。 相似文献