Real-time gas monitoring at the Tekke Hamam geothermal field (Western Anatolia,Turkey): an assessment in relation to local seismicity     

Süer  Selin  Wiersberg  Thomas  Güleç  Nilgün  Erzinger  Jörg  Parlaktuna  Mahmut 《Natural Hazards》2020,104(2):1655-1678

Natural Hazards - This study presents the results of a real-time gas monitoring experiment conducted, via the use of a quadrupole mass spectrometer, in a mofette field within the Tekke Hamam...  相似文献   

Real-time drilling mud gas monitoring for qualitative evaluation of hydrocarbon gas composition during deep sea drilling in the Nankai Trough Kumano Basin     

Hammerschmidt  Sebastian B  Wiersberg  Thomas  Heuer  Verena B  Wendt  Jenny  Erzinger  Jörg  Kopf  Achim 《Geochemical transactions》2014,15(1):1-9

Background

Riverine particles undergo a rapid transformation when they reach estuaries. The rapid succession of hydrodynamic and biogeochemical regimes forces the particles to flocculate, settle and enter the sediment pool. The rates and magnitudes of flocculation depend on the nature of the particles which are primarily affected by the types and quantities of organic matter (OM). Meanwhile, the OM characteristics vary widely between environments, as well as within a single environment due to seasonal climate and land use variability. We investigated the effect of the OM types and quantities through laboratory experiments using natural estuarine particles from the Mississippi Sound and Atchafalaya Bay as well as model mixtures of montmorillonite and organic molecules (i.e., biopolymers (guar/xanthan gums) and humic acid).

Results

Biopolymers promote flocculation but the magnitude depends on the types and quantities. Nonionic guar gum yields much larger flocs than anionic xanthan gum, while both of them exhibit a nonlinear behavior in which the flocculation is the most pronounced at the intermediate OM loading. Moreover, the effect of guar gum is independent of salinity whereas the effect of xanthan gum is pronounced at higher salinity. Meanwhile, humic acid does not affect flocculation at all salinity values tested in this study. These results are echoed in the laboratory manipulation of the natural estuarine particles. Flocculation of the humic acid-rich Mississippi Sound particles is unaffected by the OM, whereas that of biopolymer-rich Atchafalaya Bay particles is enhanced by the OM.

Conclusions

Flocculation is positively influenced by the presence of biopolymers that are produced as the result of marine primary production. Meanwhile, humic acid, which is abundant in the rivers that drain the agricultural soils of Southeastern United States, has little influence on flocculation. Thus, it is expected that humic acid-poor riverine particles (e.g., Mississippi River, and Atchafalaya River, to a lesser degree) may be prone to rapid flocculation and settling in the immediate vicinity of the river mouths when mixed with biopolymer-rich coastal waters. It is also expected that humic acid-rich riverine particles (e.g., Pearl River) may resist immediate flocculation and be transported further away from the river mouth.  相似文献   

Origin and spatial distribution of gas at seismogenic depths of the San Andreas Fault from drill-mud gas analysis   总被引：1，自引：0，他引：1  

Thomas Wiersberg  Jörg Erzinger 《Applied Geochemistry》2008

Data are presented on the molecular composition of drill-mud gas from the lower sedimentary section (1800–3987 m) of the SAFOD (San Andreas Fault Observatory at Depth) Main Hole measured on-line during drilling, as well as C and H isotope data from off-line mud gas samples. Hydrocarbons, H₂ and CO₂ are the most abundant non-atmospheric gases in drill-mud when drilling seismogenic zones. Gas influx into the well at depth is related to the lithology and permeability of the drilled strata: larger formation gas influx was detected when drilling through organic-rich shales and permeable sandstones. The SAF (San Andreas Fault), encountered between approximately 3100 m and 3450 m borehole depth, is generally low in gas, but is encompassed by two gas-rich zones (2700–2900 m and below 3550 m) at the fault margins with enhanced ²²²Rn activities and distinct gas compositions. Within the fault, two interstratified gas-rich lenses (3150–3200 m and 3310–3340 m) consist of CO₂ and hydrocarbons (upper zone), but almost exclusively of hydrocarbons (lower zone).  相似文献   

On the interaction of pure and impure supercritical CO₂ with rock forming minerals in saline aquifers: An experimental geochemical approach     

Franziska D.H. Wilke  Mónica Vásquez  Thomas Wiersberg  Rudolf Naumann  Jörg Erzinger 《Applied Geochemistry》2012

The aim of this experimental study was to evaluate and compare the geochemical impact of pure and impure CO₂ on rock forming minerals of possible CO₂ storage reservoirs. This geochemical approach takes into account the incomplete purification of industrial captured CO₂ and the related effects during injection, and provides relevant data for long-term storage simulations of this specific greenhouse gas. Batch experiments were conducted to investigate the interactions of supercritical CO₂, brine and rock-forming mineral concentrates (albite, microcline, kaolinite, biotite, muscovite, calcite, dolomite and anhydrite) using a newly developed experimental setup. After up to 42 day (1000 h) experiments using pure and impure supercritical CO₂ the dissolution and solution characteristics were examined by XRD, XRF, SEM and EDS for the solid, and ICP–MS and IC for the fluid reactants, respectively. Experiments with mixtures of supercritical CO₂ (99.5 vol.%) and SO₂ or NO₂ impurities (0.5 vol.%) suggest the formation of H₂SO₄ and HNO₃, reflected in pH values between 1 and 4 for experiments with silicates and anhydrite and between 5 and 6 for experiments with carbonates. These acids should be responsible for the general larger amount of cations dissolved from the mineral phases compared to experiments using pure CO₂. For pure CO₂ a pH of around 4 was obtained using silicates and anhydrite, and 7–8 for carbonates. Dissolution of carbonates was observed after both pure and impure CO₂ experiments. Anhydrite was corroded by approximately 50 wt.% and gypsum precipitated during experiments with supercritical CO₂ + NO₂. Silicates do not exhibit visible alterations during all experiments but released an increasing amount of cations in the reaction fluid during experiments with impure CO₂. Nonetheless, precipitated secondary carbonates could not be identified.  相似文献