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Yun Jiang Piers Koefoed Olga Pravdivtseva Heng Chen Chun‐Hui Li Fang Huang Li‐Ping Qin Jia Liu Kun Wang 《Meteoritics & planetary science》2021,56(1):61-76
The alkali element K is moderately volatile and fluid mobile; thus, it can be influenced by both primary processes (evaporation and recondensation) in the solar nebula and secondary processes (thermal and aqueous alteration) in the parent body. Since these primary and secondary processes would induce different isotopic fractionations, K isotopes could become a potential tracer to distinguish them. Using recently developed methods with improved precision (0.05‰, 95% confidence interval), we systematically measured the K isotopic compositions and major/trace elemental compositions of chondritic components (18 chondrules, 3 CAIs, 2 matrices, and 5 bulks) in the carbonaceous chondrite fall Allende. Among all the components analyzed in this study, CAIs, which formed initially under high‐temperature conditions in the solar nebula and were dominated by nominally K‐free refractory minerals, have the highest K2O content (average 0.53 wt%) and have K isotope compositions most enriched in heavy isotopes (δ41K: ?0.30 to ?0.25‰). Such an observation is consistent with previous petrologic studies that show CAIs in Allende have undergone alkali enrichment during metasomatism. In contrast, chondrules contain lower K2O content (0.003–0.17 wt%) and generally lighter K isotope compositions (δ41K: ?0.87‰ to ?0.24‰). The matrix and bulks are nearly identical in K2O content and K isotope compositions (0.02–0.05 wt%; δ41K: ?0.62 to ? 0.46‰), which are, as expected, right in the middle of CAIs and chondrules. This strongly indicates that most of the chondritic components of Allende suffered aqueous alteration and their K isotopic compositions are the ramification of Allende parent‐body processing instead of primary nebular signatures. Nevertheless, we propose the small K isotope fractionations observed (< 1‰) among Allende components are likely similar to the overall range of K isotopic fractionation that occurred in nebular environment. Furthermore, the K isotope compositions seen in the components of Allende in this study are consistent with MC‐ICP‐MS analyses of the components in ordinary chondrites, which also show an absence of large (10‰) isotope fractionations. This is not expected as evaporation experiments in nebular conditions suggest there should be large K isotopic fractionations. Nevertheless, possible nebular processes such as chondrules back exchanging with ambient gas when they formed could explain this lack of large K isotopic variation. 相似文献
3.
我国50多年的视电阻率连续观测结果表明,大地震前近震中区域的视电阻率呈现出与主压应力方位有关的各向异性变化,即:垂直于主压应力方向观测的变化幅度最大,平行方向最小或不明显,斜交方向介于二者之间.目前我国定点台站视电阻率观测的探测范围主要在浅层沉积层以内,通常含有较多的含水裂隙.本文将地下岩土介质简化为由固体基质和含流体/气体裂隙组成的固液气三相介质,且基质、流体和气体具有标量形式的电阻率,推导出了包含基质和流体电阻率、裂隙率、饱和度和裂隙面积率因子的电阻率张量表达式.以裂隙的扩展/闭合表示应力作用下裂隙的变化,得到了电阻率随裂隙变化的微分形式,电阻率变化对裂隙体积变化放大系数的表达式和裂隙横向变化对纵向电阻率影响的横向权系数的表达式.在此基础上得到了介质电阻率和视电阻率的各向异性变化特征:对于含水裂隙介质,无论裂隙如何变化,均是最小主轴方向电阻率的变化幅度大于其他方向;对于含水孔隙介质,沿孔隙主要变化方向的主轴电阻率变化幅度大于其他方向.对于各向异性变化,视电阻率和介质电阻率存在π/2的方向差异.相较于含水岩石,无水岩石介质电阻率的各向异性变化不显著.本文提出的电阻率表达式可以对实验室和野外实际观测的许多结果做出合理的解释. 相似文献
4.
以标准化降水蒸散指数(SPEI)作为评估指标,基于渭河流域28个气象站点1961—2017年实测降水量和气温数据,采用Mann-Kendall(M-K)趋势检验、经验正交函数以及小波变换等方法分析渭河流域干旱时空变化特征,并研究渭河流域干旱与6种大尺度气候因子之间的相关关系,进一步探讨主要气候因子对流域干旱时空分布特征的潜在影响。研究表明:渭河流域在1961—2017年间整体呈现出变旱的趋势。通过经验正交函数分解,渭河流域干旱分布场主要有3种典型模态类型,分别为全局型、西北—东南反向分布型以及东—西反向分布型;同时,大尺度气候因子南方涛动指数SOI与流域干旱分布场具有更好的相关关系,对该区域内干旱变化有较强的影响。 相似文献
5.
基于生态敏感性-生态恢复力-生态压力度(SRP)概念模型,从地形、气候、植被和社会经济 因子选取 8 个评价指标,利用遥感和 GIS 技术,采用主成分分析方法求取权重,对祁连山地区启动 水源涵养区生态环境保护和综合治理规划研究前后近 10 a 的生态脆弱性程度进行系统、定量地评 估,旨在揭示生态脆弱性的分布特征、时空演变及动因,为区域生态保护、资源利用和可持续发展 提供参考。结果表明:(1)从研究区生态脆弱性分布来看,祁连山地区主要以轻度和重度脆弱为 主,脆弱性程度从西北向东南地区逐渐减弱,西北地区植被覆盖度小,海拔高,生态环境较为恶劣 是导致脆弱性程度较高的原因;(2)祁连山地区 3 期生态脆弱程度呈逐渐下降趋势,综合指数分别 为 3.307、3.118 和 3.103;2005 年 生 态 脆 弱 性 较 高 ,极 度 脆 弱 面 积 为 28 610 km2,2010 年 下 降 为 11 723 km2,2015 年降低为 6 174 km2,极度脆弱面积逐渐减少;(3)从祁连山地区生态脆弱性演变动 因来看,8 个指标对生态脆弱性影响均较为显著,但在不同的时间影响程度各不相同,2005—2015 年 3 期数据中对生态脆弱性影响最大的均为植被指数,降水次之,地形因子影响最小。总体来看, 近年来祁连山地区生态脆弱性程度有所降低,但仍然需要加强保护力度,促进生态环境可持续 发展。 相似文献
6.
敦煌-格尔木铁路沿线地形复杂、起沙因素多变、沙源丰富,沙害问题日益严重。目前对其风沙活动规律还未有研究,不利于防沙工作的开展。为此,通过对自北向南的5个观测点(S1、S2、S3、S4、S5)风速和风向的观测、计算和分析,利用平均风速、起沙风况及输沙势对敦格铁路沿线的风动力环境特征进行研究。结果表明:S5、S4和S3的风况对铁路风沙灾害防治意义较大。S5年平均风速、起沙风频率和输沙势最大,春季风沙活动最为强烈,且风向单一、风力强劲,风沙运动方向基本与铁路垂直,沙粒易在铁路附近堆积。S4夏季风沙活动最为强烈;S3春季风沙活动最为强烈,且风向单一,S4和S3的风沙运动方向与铁路夹角小于90°,附近沙源广阔,铁路易受风沙侵蚀,阻碍交通运营。 相似文献
7.
深入探讨了柴达木盆地盐湖区土壤黑碳分布及土气交换特征。研究结果显示,研究区土壤总黑碳含量范围为0.50~6.79 g/kg,平均值达到1.64 g/kg;土壤烟炱组分黑碳含量范围为0.50~4.75 g/kg,平均值达到1.144 g/kg;气溶胶黑碳含量范围为0.34~4.92μg/m~3,平均值达到0.98μg/m~3。柴达木盆地盐湖区盐湖资源的大量开采和工业化生产等可能造成该地区黑碳大量排放。盐湖区土壤黑碳稳定碳同位素值(δ~(13)C_(BC))在-25.33‰~-23.46‰之间变化,平均值为-24.21‰,表明该地区土壤黑碳来源可能受C_3植物和化石燃料来源的共同影响。首次运用逃逸系数探讨了柴达木盆地盐湖区黑碳土气交换行为,结果表明研究区黑碳土气交换行为确实存在,但存在一定程度的模拟不确定性。 相似文献
8.
Charlotte Prud'homme Olivier Moine Jerome Mathieu Segolene Saulnier‐Copard Pierre Antoine 《Boreas: An International Journal of Quaternary Research》2019,48(1):257-268
High concentrations of calcite fossil granules produced by earthworms (ECG) have been identified in most of the stratigraphical units along the loess‐palaeosol reference sequence of Nussloch (Germany). They are particularly abundant in interstadial brown soils and in tundra gley horizons, the latter reflecting short‐term phases of aggradation then degradation of permafrost. These granules are characterized by a radial crystalline structure produced in the earthworms by specific bio‐mineralization processes. In our study, we used this biological indicator combined with 14C and OSL dating, and sedimentological parameters to characterize millennial‐time scale climatic variations recorded in loess sequences. The approach is based on high‐resolution counts of ECG throughout a 17‐m‐thick loess sequence (332 samples). Strong increases in granule and mollusc concentrations suggest warmer climate conditions during palaeosol formation phases, associated with increasing biodiversity, biological activity and vegetation cover. Decreased granule concentrations occur within primary loess deposits, indicating a strong correlation with palaeoenvironmental conditions and demonstrating the reliability of ECG concentration variations as a new palaeoenvironmental proxy. Finally, this pattern is also recorded in loess sequences located about 600 km westward in northern France demonstrating the large‐scale validity of this new palaeoclimatic proxy. 相似文献
9.
Samuel Ebert Addi Bischoff Dennis Harries Sarah Lentfort Jean‐Alix Barrat Andreas Pack Jrme Gattacceca Robbin Visser Peter Schmid‐Beurmann Stephan Kimpel 《Meteoritics & planetary science》2019,54(2):328-356
Based on the high abundance of fine‐grained material and its dark appearance, NWA 11024 was recognized as a CM chondrite, which is also confirmed by oxygen isotope measurements. But contrary to known CM chondrites, the typical phases indicating aqueous alteration (e.g., phyllosilicates, carbonates) are missing. Using multiple analytical techniques, this study reveals the differences and similarities to known CM chondrites and will discuss the possibility that NWA 11024 is the first type 3 CM chondrite. During the investigation, two texturally apparent tochilinite–cronstedtite intergrowths were identified within two thin sections. However, the former phyllosilicates were recrystallized to Fe‐rich olivine during a heating event without changing the textural appearance. A peak temperature of 400–600 °C is estimated, which is not high enough to destroy or recrystallize calcite grains. Thus, calcites were never constituents of the mineral paragenesis. Another remarkable feature of NWA 11024 is the occurrence of unknown clot‐like inclusions (UCLIs) within fine‐grained rims, which are unique in this clarity. Their density and S concentration are significantly higher than of the surrounding fine‐grained rim and UCLIs can be seen as primary objects that were not formed by secondary alteration processes inside the rims. Similarities to chondritic and cometary interplanetary dust particles suggest an ice‐rich first‐generation planetesimal for their origin. In the earliest evolution, NWA 11024 experienced the lowest degree of aqueous alteration of all known CM chondrites and subsequently, a heating event dehydrated the sample. We suggest to classify the meteorite NWA 11024 as the first type 3 CM chondrite similar to the classification of CV3 chondrites (like Allende) that could also have lost their matrix phyllosilicates by thermal dehydration. 相似文献
10.
pek elen‐Erdem 《洁净——土壤、空气、水》2020,48(3)
The aim of this study is to evaluate the feasibility of sludge digester effluent as feeding solution to enrich anaerobic ammonium oxidation (anammox) bacteria. The performance of the two parallel pilot scale‐upflow packed bed anammox reactors (UPBAn1 and UPBAn2) are examined in terms of the enrichment of anammox bacteria. The control experiment is set up conducting synthetic wastewater as feeding solution in the UPBAn1 reactor whereas, the sludge digester effluent is fed to the nitritation reactor and then the partially nitrated digester effluent to the UPBAn2 reactor. Anammox activities are evaluated by mass balances based on ammonium (NH4+), nitrite (NO2?), and nitrate (NO3?) analysis and NRR. Microbial community of anammox bacteria is analyzed using real‐time polymerase chain reaction (PCR). The results demonstrate that UPBAn 1 and UPBAn2 reactors are successfully enriched on days 64 and 40 with NRRs of 19.54 and 19.43 g N m?3 per day, respectively. This study reveals that both synthetic wastewater and digester effluent are suitable for the enrichment of anammox bacteria; however, digester effluent as feeding solution for enrichment of anammox bacteria based on the ease of process control and process stability is more advisable. 相似文献