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2017年6月在珠江口及近岸海域61个站位采集了悬浮颗粒物生物硅(BSi,biogenic silica)和叶绿素a(Chl a)。利用RAGUENEAU et al(2005)提出的碱提取法测定了悬浮颗粒物生物硅,探讨不同环境条件下BSi浓度以及碱性提取液中岩源硅(LSi,lithogenic silica)的干扰程度。结果显示,Chl a质量浓度范围为0.06~8.64 μg·L-1,悬浮颗粒物BSi浓度从低于检测限到14.3 μmol·L-1,LSi浓度范围为0.00~9.56 μmol·L-1;LSi/(LSi+BSi)比均值为0.38 mol·mol-1。提取液中测得的Si/Al比均值为2.42 mol·mol-1,与RAGUENEAU et al(2005)报道值接近。研究区域内的表层BSi反映了硅藻的生物量,与Chl a存在显著线性相关。LSi对BSi测量的干扰程度存在明显的空间差异,总体上近岸BSi和LSi高,LSi/(LSi+BSi)比低;外海BSi和LSi低,LSi/(LSi+BSi)比高;河口内BSi低,LSi高,LSi/(LSi+BSi)比高;上升流区BSi和LSi高,LSi/(LSi+BSi)比高;底层较表层具有更高的LSi和LSi/(LSi+BSi)比。最后,对常用的几种碱提取法在应用时存在的问题作了探讨。 相似文献
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Chlorophyll a(Chl a),particulate organic carbon(POC)and biogenic silica(BSi)were determined in coastal waters adjacent to the Zhujiang(Pearl)River Estuary(ZRE)during summer,in order to examine the C:Chl a ratio of phytoplankton and phytoplankton carbon in the plume-impacted coastal waters during summer,as well as to assess the relative contribution of diatoms to the phytoplankton biomass,by the regression between Chl a,POC and BSi.Our results showed that the C:Chl a ratio(g/g)of phytoplankton was high(up to 142),likely due to high light intensity and nutrient limitation.The river plume input stimulated phytoplankton growth,especially diatoms,resulting in higher relative contribution of phytoplankton carbon(55%)and diatoms(34%)to POC in the plume-impacted region than those(33%and 13%)in high salinity area,respectively.Phytoplankton carbon(up to 538μg/L)in the plume-impacted region was much higher than that(<166μg/L)in high salinity area.Our findings were helpful to improve the biogeochemical model in coastal waters adjacent to the ZRE. 相似文献
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