AN ANALYTICAL METHOD OF ULTRA-TRACE TELLURIUM FOR SAMPLES OF SEA-AND ENVIRONMENTAL-WATER     

安镜如  张清 《海洋学报(英文版)》1982,1(2):204-209

Tellurium is known to be a poisonous element to human health. In recent years,determination of trace tellurium has been attached great attention in connection with thewide application of its compounds and/or with environmental pollution. Literature citedreported the determination of ppb level tellurium in waste water and artificial watersamples by atomic-absorption spectrophotometry. As the tellurium content in naturalwater is extremely low, there is not yet any sensitive analytical method for determination ofits background value in various natural water. In chemical oceanography, data abouttellurium content in seawater are rather scarce. This paper will summarize and evaluate a series of our investigations on the analytical  相似文献   

银催化HDEA电化学发光法测定矿样中的痕量银     

林金明  安镜如 《岩矿测试》1991,10(1):13-16

在碱性介质中,痕量Ag(Ⅰ)对新试剂6-(2-羟基-4-二乙基氨苯偶氮)-2,3-二氢-1,4-酞嗪二酮(简称HDEA)的电化学发光具有显著的催化作用。基于此,提出了HDEA-KCI-KOH体系测定矿样中痕量Ag的新方法。方法的检测限为2.0×10~(-8)mol/L Ag,线性范围为5.0×10~(-8)—3.0×10~(-6)mol/L Ag。采用巯基棉富集分离,应用本法测定一些矿样中的Ag,结果良好。  相似文献   

海水和环境水样中超痕量碲的分析方法     

安镜如  张清 《海洋学报》1982,4(5):555-563

碲为毒性元素,有害人体健康,近年来微量碲的监测工作日益受到重视.文献报道用原子吸收光谱法测定了工业废水中ppb级的碲[1]及含量较高的人工水样[2].由于天然水中碲的含量极低,约为ppt数量级,目前尚无灵敏的方法可用于测定天然水中碲的本底值,而化学海洋学中也缺乏关于海水中碲含量的数据[3].本文目的在于研究超痕量碲测定的简便方案,即巯基棉浓缩-催化极谱法.首次测定了海水中碲的含量.  相似文献