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1.
The H. J. Andrews Experimental Forest (HJA) encompasses the 6400 ha Lookout Creek watershed in western Oregon, USA. Hydrologic, chemistry and precipitation data have been collected, curated, and archived for up to 70 years. The HJA was established in 1948 to study the effects of harvest of old-growth conifer forest and logging-road construction on water quality, quantity and vegetation succession. Over time, research questions have expanded to include terrestrial and aquatic species, communities and ecosystem dynamics. There are nine small experimental watersheds and 10 gaging stations in the HJA, including both reference and experimentally treated watersheds. Gaged watershed areas range from 8.5 to 6242 ha. All gaging stations record stage height, water conductivity, water temperature and above-stream air temperature. At nine of the gage sites, flow-proportional water samples are collected and composited over 3-week intervals for chemical analysis. Analysis of stream and precipitation chemistry began in 1968. Analytes include dissolved and particulate species of nitrogen and phosphorus, dissolved organic carbon, pH, specific conductance, suspended sediment, alkalinity, and major cations and anions. Supporting climate measurements began in the 1950s in association with the first small watershed experiments. Over time, and following the initiation of the Long Term Ecological Research (LTER) grant in 1980, infrastructure expanded to include a set of benchmark and secondary meteorological stations located in clearings spanning the elevation range within the Lookout Creek watershed, as well as a large number of forest understory temperature stations. Extensive metadata on sensor configurations, changes in methods over time, sensor accuracy and precision, and data quality control flags are associated with the HJA data.  相似文献   
2.
The alkali element K is moderately volatile and fluid mobile; thus, it can be influenced by both primary processes (evaporation and recondensation) in the solar nebula and secondary processes (thermal and aqueous alteration) in the parent body. Since these primary and secondary processes would induce different isotopic fractionations, K isotopes could become a potential tracer to distinguish them. Using recently developed methods with improved precision (0.05‰, 95% confidence interval), we systematically measured the K isotopic compositions and major/trace elemental compositions of chondritic components (18 chondrules, 3 CAIs, 2 matrices, and 5 bulks) in the carbonaceous chondrite fall Allende. Among all the components analyzed in this study, CAIs, which formed initially under high‐temperature conditions in the solar nebula and were dominated by nominally K‐free refractory minerals, have the highest K2O content (average 0.53 wt%) and have K isotope compositions most enriched in heavy isotopes (δ41K: ?0.30 to ?0.25‰). Such an observation is consistent with previous petrologic studies that show CAIs in Allende have undergone alkali enrichment during metasomatism. In contrast, chondrules contain lower K2O content (0.003–0.17 wt%) and generally lighter K isotope compositions (δ41K: ?0.87‰ to ?0.24‰). The matrix and bulks are nearly identical in K2O content and K isotope compositions (0.02–0.05 wt%; δ41K: ?0.62 to ? 0.46‰), which are, as expected, right in the middle of CAIs and chondrules. This strongly indicates that most of the chondritic components of Allende suffered aqueous alteration and their K isotopic compositions are the ramification of Allende parent‐body processing instead of primary nebular signatures. Nevertheless, we propose the small K isotope fractionations observed (< 1‰) among Allende components are likely similar to the overall range of K isotopic fractionation that occurred in nebular environment. Furthermore, the K isotope compositions seen in the components of Allende in this study are consistent with MC‐ICP‐MS analyses of the components in ordinary chondrites, which also show an absence of large (10‰) isotope fractionations. This is not expected as evaporation experiments in nebular conditions suggest there should be large K isotopic fractionations. Nevertheless, possible nebular processes such as chondrules back exchanging with ambient gas when they formed could explain this lack of large K isotopic variation.  相似文献   
3.
Base flows are important for tropical regions with pronounced dry seasons, which are facing increasing water demands. Base flow generation, however, is one of the most challenging hydrological processes to characterize in the tropics. In many years during the May–December wet season in the Panama Canal Watershed (PCW), base flows in rivers abruptly increase. This increase persists until the start of the December–April dry season. Understanding this unusual base flow jump (BFJ) behaviour is critical to improve water provisioning in the seasonal tropics, especially during droughts and extended dry seasons. This study developed an integrated approach combining piecewise regression on cumulative average base flow and sensitivity analysis to calculate the timing and magnitude of BFJ. Rainfall, forest cover, mean land surface slope, catchment area, and estimated subsurface storage were tested as predictors for the occurrence and magnitude of the BFJs in seven subcatchments of the PCW. Sensitivity analysis on correlated predictors allowed ranking of predictor contributions due to isolated and cross-correlation effects. Correlations between observed BFJs and BFJs predicted by watershed and rainfall-related predictors were 0.92 and 0.65 for BFJ timing and magnitude, respectively. Forest cover was the second most significant predictor after cumulative rainfall for jump magnitude, owing to larger subsurface storage and groundwater recharge in forests than pastures. Catchments in the mountainous eastern PCW always generated larger jumps due to their higher rainfall and greater forest cover than the western PCW catchments. The cross-correlations between predictors contributed to more than 50% of the jump variances. The results demonstrate the importance of rainfall gradient and catchment characteristics in affecting the sudden and sustained BFJs, which can help inform land management decisions intended to enhance water supplies in the tropics. This study underscores the need for more research to further understand the hydrological processes involved in the BFJ phenomenon, including better BFJ models and field characterizations, to help improve tropical ecosystem services under a changing environment.  相似文献   
4.
The time it takes water to travel through a catchment, from when it enters as rain and snow to when it leaves as streamflow, may influence stream water quality and catchment sensitivity to environmental change. Most studies that estimate travel times do so for only a few, often rain-dominated, catchments in a region and use relatively short data records (<10 years). A better understanding of how catchment travel times vary across a landscape may help diagnose inter-catchment differences in water quality and response to environmental change. We used comprehensive and long-term observations from the Turkey Lakes Watershed Study in central Ontario to estimate water travel times for 12 snowmelt-dominated headwater catchments, three of which were impacted by forest harvesting. Chloride, a commonly used water tracer, was measured in streams, rain, snowfall and as dry atmospheric deposition over a 31 year period. These data were used with a lumped convolution integral approach to estimate mean water travel times. We explored relationships between travel times and catchment characteristics such as catchment area, slope angle, flowpath length, runoff ratio and wetland coverage, as well as the impact of harvesting. Travel time estimates were then used to compare differences in stream water quality between catchments. Our results show that mean travel times can be variable for small geographic areas and are related to catchment characteristics, in particular flowpath length and wetland cover. In addition, forest harvesting appeared to decrease mean travel times. Estimated mean travel times had complex relationships with water quality patterns. Results suggest that biogeochemical processes, particularly those present in wetlands, may have a greater influence on water quality than catchment travel times.  相似文献   
5.
High concentrations of calcite fossil granules produced by earthworms (ECG) have been identified in most of the stratigraphical units along the loess‐palaeosol reference sequence of Nussloch (Germany). They are particularly abundant in interstadial brown soils and in tundra gley horizons, the latter reflecting short‐term phases of aggradation then degradation of permafrost. These granules are characterized by a radial crystalline structure produced in the earthworms by specific bio‐mineralization processes. In our study, we used this biological indicator combined with 14C and OSL dating, and sedimentological parameters to characterize millennial‐time scale climatic variations recorded in loess sequences. The approach is based on high‐resolution counts of ECG throughout a 17‐m‐thick loess sequence (332 samples). Strong increases in granule and mollusc concentrations suggest warmer climate conditions during palaeosol formation phases, associated with increasing biodiversity, biological activity and vegetation cover. Decreased granule concentrations occur within primary loess deposits, indicating a strong correlation with palaeoenvironmental conditions and demonstrating the reliability of ECG concentration variations as a new palaeoenvironmental proxy. Finally, this pattern is also recorded in loess sequences located about 600 km westward in northern France demonstrating the large‐scale validity of this new palaeoclimatic proxy.  相似文献   
6.
Based on the high abundance of fine‐grained material and its dark appearance, NWA 11024 was recognized as a CM chondrite, which is also confirmed by oxygen isotope measurements. But contrary to known CM chondrites, the typical phases indicating aqueous alteration (e.g., phyllosilicates, carbonates) are missing. Using multiple analytical techniques, this study reveals the differences and similarities to known CM chondrites and will discuss the possibility that NWA 11024 is the first type 3 CM chondrite. During the investigation, two texturally apparent tochilinite–cronstedtite intergrowths were identified within two thin sections. However, the former phyllosilicates were recrystallized to Fe‐rich olivine during a heating event without changing the textural appearance. A peak temperature of 400–600 °C is estimated, which is not high enough to destroy or recrystallize calcite grains. Thus, calcites were never constituents of the mineral paragenesis. Another remarkable feature of NWA 11024 is the occurrence of unknown clot‐like inclusions (UCLIs) within fine‐grained rims, which are unique in this clarity. Their density and S concentration are significantly higher than of the surrounding fine‐grained rim and UCLIs can be seen as primary objects that were not formed by secondary alteration processes inside the rims. Similarities to chondritic and cometary interplanetary dust particles suggest an ice‐rich first‐generation planetesimal for their origin. In the earliest evolution, NWA 11024 experienced the lowest degree of aqueous alteration of all known CM chondrites and subsequently, a heating event dehydrated the sample. We suggest to classify the meteorite NWA 11024 as the first type 3 CM chondrite similar to the classification of CV3 chondrites (like Allende) that could also have lost their matrix phyllosilicates by thermal dehydration.  相似文献   
7.
We measured the He, Ne, and Ar isotopic concentrations and the 10Be, 26Al, 36Cl, and 41Ca concentrations in 56 iron meteorites of groups IIIAB, IIAB, IVA, IC, IIA, IIB, and one ungrouped. From 41Ca and 36Cl data, we calculated terrestrial ages indistinguishable from zero for six samples, indicating recent falls, up to 562 ± 86 ka. Three of the studied meteorites are falls. The data for the other 47 irons confirm that terrestrial ages for iron meteorites can be as long as a few hundred thousand years even in relatively humid conditions. The 36Cl‐36Ar cosmic ray exposure (CRE) ages range from 4.3 ± 0.4 Ma to 652 ± 99 Ma. By including literature data, we established a consistent and reliable CRE age database for 67 iron meteorites. The high quality of the CRE ages enables us to study structures in the CRE age histogram more reliably. At first sight, the CRE age histogram shows peaks at about 400 and 630 Ma. After correction for pairing, the updated CRE age histogram comprises 41 individual samples and shows no indications of temporal periodicity, especially not if one considers each iron meteorite group separately. Our study contradicts the hypothesis of periodic GCR intensity variations (Shaviv 2002, 2003), confirming other studies indicating that there are no periodic structures in the CRE age histogram (e.g., Rahmstorf et al. 2004; Jahnke 2005). The data contradict the hypothesis that periodic GCR intensity variations might have triggered periodic Earth climate changes. The 36Cl‐36Ar CRE ages are on average 40% lower than the 41K‐K CRE ages (e.g., Voshage 1967). This offset can either be due to an offset in the 41K‐K dating system or due to a significantly lower GCR intensity in the time interval 195–656 Ma compared to the recent past. A 40% lower GCR intensity, however, would have increased the Earth temperature by up to 2 °C, which seems unrealistic and leaves an ill‐defined 41K‐K CRE age system the most likely explanation. Finally, we present new 26Al/21Ne and 10Be/21Ne production rate ratios of 0.32 ± 0.01 and 0.44 ± 0.03, respectively.  相似文献   
8.
Algae is an informal term used to describe a broad group of simple organisms from the plant kingdom. The organisms included within this grouping are aquatic photosynthetic biota with an extensive range of life habits and forms. These organisms range from micron-sized unicellular forms to giant seaweeds and kelps, which can grow to several metres long. Both benthic and planktonic modes of life are known and display a wide variety of life cycles.  相似文献   
9.
Exhumed basin margin‐scale clinothems provide important archives for understanding process interactions and reconstructing the physiography of sedimentary basins. However, studies of coeval shelf through slope to basin‐floor deposits are rarely documented, mainly due to outcrop or subsurface dataset limitations. Unit G from the Laingsburg depocentre (Karoo Basin, South Africa) is a rare example of a complete basin margin scale clinothem (>60 km long, 200 m‐high), with >10 km of depositional strike control, which allows a quasi‐3D study of a preserved shelf‐slope‐basin floor transition over a ca. 1,200 km2 area. Sand‐prone, wave‐influenced topset deposits close to the shelf‐edge rollover zone can be physically mapped down dip for ca. 10 km as they thicken and transition into heterolithic foreset/slope deposits. These deposits progressively fine and thin over tens of km farther down dip into sand‐starved bottomset/basin‐floor deposits. Only a few km along strike, the coeval foreset/slope deposits are bypass‐dominated with incisional features interpreted as minor slope conduits/gullies. The margin here is steeper, more channelized and records a stepped profile with evidence of sand‐filled intraslope topography, a preserved base‐of‐slope transition zone and sand‐rich bottomset/basin‐floor deposits. Unit G is interpreted as part of a composite depositional sequence that records a change in basin margin style from an underlying incised slope with large sand‐rich basin‐floor fans to an overlying accretion‐dominated shelf with limited sand supply to the slope and basin floor. The change in margin style is accompanied with decreased clinoform height/slope and increased shelf width. This is interpreted to reflect a transition in subsidence style from regional sag, driven by dynamic topography/inherited basement configuration, to early foreland basin flexural loading. Results of this study caution against reconstructing basin margin successions from partial datasets without accounting for temporal and spatial physiographic changes, with potential implications on predictive basin evolution models.  相似文献   
10.
With recent advances in remote sensing, location-based services and other related technologies, the production of geospatial information has exponentially increased in the last decades. Furthermore, to facilitate discovery and efficient access to such information, spatial data infrastructures were promoted and standardized, with a consideration that metadata are essential to describing data and services. Standardization bodies such as the International Organization for Standardization have defined well-known metadata models such as ISO 19115. However, current metadata assets exhibit heterogeneous quality levels because they are created by different producers with different perspectives. To address quality-related concerns, several initiatives attempted to define a common framework and test the suitability of metadata through automatic controls. Nevertheless, these controls are focused on interoperability by testing the format of metadata and a set of controlled elements. In this paper, we propose a methodology of testing the quality of metadata by considering aspects other than interoperability. The proposal adapts ISO 19157 to the metadata case and has been applied to a corpus of the Spanish Spatial Data Infrastructure. The results demonstrate that our quality check helps determine different types of errors for all metadata elements and can be almost completely automated to enhance the significance of metadata.  相似文献   
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