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1.
The late Holocene is of particular interest to our understanding of the evolution of coastal sedimentary systems because this period encompasses warmer and cooler periods, and rising sea level in northern Europe. Based on an approach combining AMS 14C, sedimentological and rock magnetic analyses on sediment cores complemented with seismic data collected in the macrotidal Bay of Vilaine (south Brittany), we document the depositional history of the inner bay coeval to the mid- to late-Holocene transgression in south Brittany. Correlation between sedimentary archives revealed the main sedimentary infilling phases during the last 6000 years. Four units (U1–U4) are recognized in the coastal sediment wedge of the system, corresponding to the stepwise marine invasion of the bay. We show that (1) marine inundation, due to the steep morphology of the bedrock, is diachronous between distal and proximal records. A time lag of ~1000 years is inferred over a distance of less than 5 km; (2) in the outer areas, the sedimentation has been condensed since 3000 years; (3) proximal estuarine archives offer the best record of sedimentary processes covering the last 2000 years, including the Medieval Warm Period (MWP).Correlations in proximal records in the Bay of Vilaine assess the connection between coastal sedimentary dynamics, climatic conditions and anthropogenic activities during the MWP. We match the preservation of clay deposits to increased river-borne suspended matter transported to the estuary probably as a result of accelerated land-use development (higher soil erosion) in the catchment area between ca. 880 and 1050 AD. Because the preservation of estuarine sedimentary successions is favoured when coastal wave sediment reworking is minimal, it is proposed that the prevailing climatic regime in south Brittany during the MWP likely resembled to that of the preferred negative phase of the North Atlantic Oscillation (NAO). Our data are fairly consistent with other late Holocene records from northern Europe including the Atlantic seaboard. However, they outline the difficulty in interpreting climatic and anthropogenic signatures in coastal sedimentary records where high-resolution chronologies required to unravel their respective influences are still missing.  相似文献   
2.
Mercury speciation and its distribution in surface and deep waters of the Mediterranean Sea were studied during two oceanographic cruises on board the Italian research vessel URANIA in summer 2003 and spring 2004 as part of the Med Oceaneor and MERCYMS projects. The study included deep water profiles of dissolved gaseous Hg (DGM), reactive Hg (RHg), total Hg (THg), monomethyl Hg (MeHg) and dimethyl Hg (DMeHg) in open ocean waters. Average concentrations of measured Hg species were characterized by seasonal and spatial variations. Overall average THg concentrations ranged between 0.41 and 2.65 pM (1.32 ± 0.48 pM) and were comparable to those obtained in previous studies of the Mediterranean Sea. A significant fraction of Hg was present as “reactive” Hg (average 0.33 ± 0.32 pM). Dissolved gaseous Hg (DGM), which consists mainly of Hg0, represents a considerable proportion of THg (average 20%, 0.23 ± 0.11 pM). The portion of DGM typically increased towards the bottom, especially in areas with strong tectonic activity (Alboran Sea, Strait of Sicily, Tyrrhenian Sea), indicating its geotectonic origin. No dimethyl Hg was found in surface waters down to the depth of 40 m. Below this depth, its average concentration was 2.67 ± 2.9 fM. Dissolved fractions of total Hg and MeHg were measured in filtered water samples and were 0.68 ± 0.43 pM and 0.29 ± 0.17 pM for THg and MeHg respectively. The fraction of Hg as MeHg was in average 43%, which is relatively high compared to other ocean environments. The concentrations reported in this study are among the lowest found in marine environments and the quality of analytical methods are of key importance. Speciation of Hg in sea water is of crucial importance as THg concentrations alone do not give adequate data for understanding Hg sources and cycling in marine environments. For example, photoinduced transformations are important for the presence of reactive and elemental mercury in the surface layers, biologically mediated reactions are important for the production/degradation of MeHg and DGM in the photic zones of the water column, and the data for DGM in deep sea indicate the natural sources of Hg in geotectonicaly active areas of the Mediterranean Sea.  相似文献   
3.
Thallium diagenesis in lacustrine sediments   总被引:1,自引:0,他引:1  
Dated sediment cores and porewaters from two Canadian Shield lakes, located 40 km from Québec City (L. Tantaré) and 25 km downwind from an important smelter in northwestern Québec (L. Vose), were analyzed for thallium and other geochemical variables. Atmospheric deposition is the only source of anthropogenic Tl to these lakes. The porewater Tl concentration profiles in L. Tantaré display a peak below the sediment-water interface that suggests post-depositional Tl remobilization and transport to the overlying water and deeper sediments; such a dissolved Tl peak occurs just above the sediment-water interface in L. Vose. Modeling the porewater Tl profiles with a diagenetic reaction-transport equation reveals a zone of dissolved Tl production lying above a zone of Tl consumption in L. Tantaré sediments. In contrast, in L. Vose, Tl diffuses across the sediment-water interface from the anoxic hypolimnion and is fixed to the surficial sediments. The localization of the consumption zones, the shape of the dissolved Tl, sulfide and iron profiles, as well as calculations of saturation states are all consistent with the removal of Tl from porewater by co-precipitation with and/or adsorption to Fe sulfides. The concentrations of Tl removed from or added to sediments after their deposition (i.e., diagenetic Tl) amount to up to 36% of measured sediment Tl concentrations. Comparison of the reconstructed historical Tl records with those of polycyclic aromatic hydrocarbons (PAHs) and of Pb originating from coal burning or from smelting activities indicate that coal combustion is the major source of atmospheric Tl to L. Tantaré and that an additional important Tl source to L. Vose is the nearby smelter.  相似文献   
4.
5.
Uranium geochemistry has been investigated in three acid lakes located on the Canadian Shield and one circumneutral lake in the Appalachian Region of Eastern Canada. In all Shield lakes, dissolved U concentrations were higher in the porewater than in the overlying water. In one of them, whose hypolimnion is perennially oxic, U released to porewater at depths of Fe remobilization was removed from the porewater at depths of Fe oxyhydroxides precipitation; these similarities in the U and Fe profiles indicate that part of the U becomes associated to Fe oxyhydroxides. The dissolved U and Fe profiles in the other two Shield lakes, whose hypolimnions were anoxic when sampled, did not show any significant recycling of these elements in the vicinity of the sediment-water interface and both elements diffused from the sediment to the overlying water. In contrast, in the Appalachian Lake, dissolved U concentrations were higher in the overlying water than in porewater, strongly decreased at the vicinity of the sediment-water interface and then remained relatively constant with sediment depth. Diagenetic modeling of the porewater U profiles, assuming steady-state, reveals that authigenic U always represented ?3% of the total U concentration in the sediments of all lakes. This observation indicates that diagenetic reactions involving U are not quantitatively important and that most of the U was delivered to the sediments at our study sites as particulate U and not through diffusion across the sediment-water interface, as is seen in continental margin sediments. Comparison of the U:Corg and U:Fe molar ratios in diagenetic material collected across the sediment-water interface with Teflon sheets and in surface sediments (0-0.5 cm) of the lake having a perennially oxic hypolimnion suggest that solid phase U was mainly bound to organic matter originating from the watershed; a strong statistical correlation between sediment non-lithogenic U and Corg in the Appalachian Lake supports this contention. Thermodynamic calculations of saturation states suggest that dissolved U was not removed from porewater through precipitation of UO2(s), U3O7(s) and U3O8(s) as previously proposed in the literature.  相似文献   
6.
7.
The architecture of a tidal sand bank in the south-eastern Celtic Sea was examined using very high-resolution seismic surveys. The bank comprises four depositional units. The lowest unit 1 is characterized by gently dipping (1–8°) strata that strike parallel to the length of the bank. Unit 1 is erosionally overlain by unit 2, which forms the bulk of the bank. This unit consists of stacked sets of downcurrent-dipping (7–12°) master bedding formed by climbing, sinuous-crested tidal dunes that are up to 20 m high. These deposits are locally incised by an anastomosed channel network (unit 3) that may represent a buried swatchway system. The upper part of the bank comprises wave-related deposits that are mainly preserved on the bank flanks (unit 4). The outer bank surface is erosional. The bank is believed to have formed during the last post-glacial sea-level rise. The facies evolution from unit 1 to unit 3 indicates an upward increase in tidal energy, mainly characterized by the thickening of dune cross-bed sets in unit 2. The majority of bank growth is inferred to have occurred in water depths of the order of 60 m. This evolution was controlled by relative sea-level rise, which is likely to have caused an episode of tidal resonance with associated strong tidal currents that were responsible for the incision of the deep, cross-cutting channels of unit 3. The transition to wave-dominated sedimentation in unit 4 is related to the decay of resonance with continued sea-level rise.  相似文献   
8.
The presence of gas is a common feature in many seismic sections. However, the origin of the gas is often difficult to determine. Recently acquired very high resolution seismic profiles using an IKB Seistec boomer provide useful insight to the understanding of the gas origins in a range of environmental settings including sea lochs and coastal lagoons. The gas features are described both from a qualitative point of view through their acoustic facies, and quantitatively through the associated seismic signal (polarisation, amplitude). Acoustic facies include acoustic turbidity, gas “curtains” and “blankets” as well as “white fringes” and “black shadows”. All the features encountered have been related to specific gas nature generated by different sources (organic matter degradation in paleo-valley infillings, waste material effluent).  相似文献   
9.
Summary. A hardware configuration and program are described for interfacing a DIGICO spinner rock magnetometer to an APPLE microcomputer. This configuration provides full control of measurements and permits storage of the results on floppy or hard discs. A similar configuration can be used to operate the anisotropy unit.  相似文献   
10.
This study presents trace elements levels in surface and deep sediments of the Toulon bay (SE France) subjected to anthropogenic inputs (navy base, harbors, etc.). The studied elements (As, Cd, Cr, Cu, Hg, Ni, Pb, Zn) are defined as priority contaminants in aquatic systems. Fifty-five points scattered on the entire bay were sampled, allowing the determination of contaminants distribution with a high resolution. Several approaches were used to assess the degree of contamination and the potential toxicity of the Toulon bay sediments: comparison to the French legislation, surface-weighted average metal concentrations, enrichment factors (EF), geoaccumulation indices (Igeo), trace element stock calculation and comparison to sediment quality guidelines. A principal component analysis was performed to reveal common behavior of the studied contaminants. Results demonstrated the very high contamination of the small bay, especially in Hg (EF up to 1500), Cu, Pb and Zn, with export to the large bay further governed by hydrodynamics.  相似文献   
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